File name: Pandora159s1_Wakkerstroom_20231114_L2Fit_fwvt1c7d20231113p1-8.txt
File generation date: 20250129T111747.1Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c7p1-8
Local principal investigator: Refilwe Kai
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 159
Spectrometer number: 1
Processing software version used: BlickP v1.8.70
Instrument operation file used: Pandora159_OF_v6d20191004.txt
Instrument calibration file used: Pandora159s1_CF_v7d20231113.txt
Level 1 file used: Pandora159s1_Wakkerstroom_20231114_L1_smca1c7d20231113p1-8.txt
Full location name: Global Change Institute, University of Witwatersrand field site in Wakkerstroom
Short location name: Wakkerstroom
Country of location: South Africa
Location latitude [deg]: -27.3493
Location longitude [deg]: 30.1438
Location altitude [m]: 1760
Local noon date: 20231114
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: new FC bc  steadily increasing wrms
First and last pixel inside fitting window: 1644 1794
Nominal wavelengths inside fitting window [nm]: 492.0151 492.1360 492.2568 492.3777 492.4985 492.6193 492.7401 492.8609 492.9817 493.1024 493.2231 493.3438 493.4645 493.5852 493.7059 493.8265 493.9471 494.0677 494.1883 494.3089 494.4295 494.5500 494.6705 494.7910 494.9115 495.0320 495.1525 495.2729 495.3933 495.5137 495.6341 495.7545 495.8748 495.9952 496.1155 496.2358 496.3561 496.4764 496.5966 496.7169 496.8371 496.9573 497.0775 497.1976 497.3178 497.4379 497.5580 497.6781 497.7982 497.9183 498.0383 498.1584 498.2784 498.3984 498.5184 498.6383 498.7583 498.8782 498.9981 499.1180 499.2379 499.3578 499.4776 499.5974 499.7172 499.8370 499.9568 500.0766 500.1963 500.3160 500.4357 500.5554 500.6751 500.7948 500.9144 501.0340 501.1536 501.2732 501.3928 501.5123 501.6319 501.7514 501.8709 501.9904 502.1098 502.2293 502.3487 502.4681 502.5875 502.7069 502.8263 502.9456 503.0649 503.1842 503.3035 503.4228 503.5421 503.6613 503.7805 503.8997 504.0189 504.1381 504.2572 504.3764 504.4955 504.6146 504.7337 504.8527 504.9718 505.0908 505.2098 505.3288 505.4478 505.5667 505.6857 505.8046 505.9235 506.0424 506.1613 506.2801 506.3990 506.5178 506.6366 506.7554 506.8741 506.9929 507.1116 507.2303 507.3490 507.4677 507.5863 507.7050 507.8236 507.9422 508.0608 508.1794 508.2979 508.4164 508.5350 508.6535 508.7719 508.8904 509.0088 509.1273 509.2457 509.3641 509.4824 509.6008 509.7191 509.8375 509.9558
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal
Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal
Column 100: Humidity in head sensor [%], -9=no humidity signal
Column 101: Pressure in head sensor [hPa], -9=no pressure signal
Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20231114T055619.2Z 8718.247444 115 1 50.75 2 52.81 92.75 60.59 102.80 0.00 1 0.00 1 0 15 4.896e-03 4.837e-03 3.385e-03 3.361e-03 2.844966e+03 1.966677e+02 2.259357e+02 -6.000000e+00 2.529796e+02 279.82 -2.00 20.00 -2.00 505.30 0.00e+00 2.979990e-04 8.976554e-05 2.197478e-05 -6.000000e+00 1.332218e-04 279.82 -2.00 20.00 -2.00 500.20 0.00e+00 1.086173e-01 6.532767e-02 1.684242e-02 -6.000000e+00 9.431682e-02 228.24 -2.00 3.06 -2.00 501.87 0.00e+00 1.650 0.000 489.00 513.00 1 8.6187e+00 4.9861e-03 2.4837e-03 -6.0000e+00 7.2018e-03 8.8345e-03 1.3044e-03 4.6476e-04 -6.0000e+00 1.8994e-03 2.8771e-04 1.8361e-04 2.6145e-04 2.7695e-05 -6.0000e+00 3.9297e-04 -1.4810e-02 2.2892e-05 12 8 8 10 0 0 -6.43 19.34 2.22 -0.01481 -0.01354 13 3 1 2 0 3903.200 14.99 19.34 16.14 21.58 21.48 25.6 842.90 -858 -166 -32 -425 379 176 539 185 778 626 927 -9 -107 -362 -390 -115 -142 -22 -192 940 -479 -277 391 467 -161 908 37 -71 33 -79 13 -1108 -41 -297 182 -55 -205 -357 46 -35 -96 174 -65 44 -269 626 -741 469 471 339 -734 -536 -740 -411 -475 -237 122 579 387 334 132 -191 207 247 330 -351 345 -1135 -72 -604 -104 -350 -143 658 -494 596 -591 204 -239 -440 -776 -235 691 116 -287 -170 98 -348 -169 -338 443 -462 1033 134 438 315 -481 810 160 -773 -1007 -292 -854 -435 287 874 -287 -234 -524 -501 -820 234 795 -843 226 198 422 -175 1085 318 162 391 -531 -80 74 474 436 380 -504 555 -159 858 -697 673 -775 -821 -272 -176 386 506 453 233 -99 72 741 445 332 -445 -729 -265 -269 -811 -156 -31 -433 396 187 584 205 859 685 991 -10 -113 -374 -398 -117 -146 -23 -209 1034 -534 -309 432 515 -180 1008 42 -78 36 -82 13 -1129 -42 -313 200 -62 -229 -394 50 -37 -103 186 -70 48 -280 650 -778 481 476 358 -759 -533 -722 -398 -470 -243 121 580 389 334 132 -192 209 250 332 -351 336 -1105 -68 -571 -96 -324 -133 617 -477 573 -565 189 -218 -400 -708 -215 635 108 -271 -163 94 -335 -162 -325 423 -449 1012 134 435 307 -464 752 145 -689 -886 -256 -772 -410 281 865 -285 -228 -501 -475 -793 228 782 -853 228 200 428 -180 1102 321 160 380 -511 -76 72 458 422 367 -489 532 -154 811 -653 614 -709 -752 -254 -169 374 496 449 232 -99 72 746 449 332 -436 -693 -247 -251
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SQ 20231114T062715.7Z 8718.268932 127 1 44.04 2 45.94 89.31 54.02 100.34 0.00 1 0.00 1 0 15 3.656e-03 3.610e-03 2.345e-03 2.334e-03 2.321114e+03 1.324369e+02 1.800345e+02 -6.000000e+00 1.889234e+02 279.82 -2.00 20.00 -2.00 505.25 0.00e+00 2.584800e-04 6.207597e-05 1.791177e-05 -6.000000e+00 9.948528e-05 279.82 -2.00 20.00 -2.00 500.25 0.00e+00 1.030702e-02 4.520978e-02 1.479854e-02 -6.000000e+00 7.044631e-02 228.24 -2.00 3.06 -2.00 501.87 0.00e+00 1.436 0.000 489.00 513.00 1 8.1128e+00 3.4497e-03 2.1529e-03 -6.0000e+00 5.3788e-03 6.1239e-03 9.0907e-04 3.9073e-04 -6.0000e+00 1.4191e-03 4.9354e-04 -7.3373e-05 1.8301e-04 2.3277e-05 -6.0000e+00 2.9345e-04 -7.9895e-03 -3.8106e-05 11 1 0 11 8 0 77.38 19.32 1.97 -0.00799 -0.00850 13 3 1 2 0 3386.700 14.99 19.32 16.22 21.58 21.48 26.0 844.31 -686 -1233 -417 278 90 322 401 226 354 528 -38 456 -84 324 -58 -151 -187 -26 20 -184 418 -196 -53 186 -39 229 302 193 -43 -332 26 -338 -346 -201 144 678 325 -357 -336 130 77 60 -8 -19 552 -96 -157 155 165 -72 34 -550 -781 -560 -396 38 -320 254 109 124 685 541 406 817 -545 213 -343 44 97 -533 216 -773 50 -418 18 39 -199 -528 -193 -525 -91 -260 221 -127 -503 120 -65 16 -456 -222 -234 41 5 552 446 341 370 361 -503 -853 -261 -446 -710 -378 -4 249 233 174 -207 -379 -614 634 288 166 90 380 274 406 55 526 -412 416 -37 151 317 -130 340 148 485 -445 581 -138 87 -73 159 -363 -359 115 372 361 215 -147 -228 205 302 320 -222 -510 -576 -352 -148 -662 -1196 -411 282 94 341 432 247 388 571 -40 481 -88 333 -59 -153 -191 -27 21 -200 453 -213 -58 201 -43 250 328 208 -46 -343 26 -337 -349 -207 154 735 350 -382 -355 135 80 62 -9 -20 585 -103 -168 164 173 -74 34 -536 -747 -532 -382 38 -328 262 113 128 699 554 419 842 -566 217 -346 43 95 -519 206 -741 48 -407 18 38 -194 -506 -182 -493 -85 -245 209 -121 -485 117 -64 15 -445 -216 -228 40 5 557 447 337 360 344 -470 -783 -235 -402 -655 -360 -4 248 230 170 -199 -363 -594 618 285 166 90 381 276 411 56 526 -408 403 -35 144 306 -126 329 142 464 -430 557 -131 81 -68 145 -330 -334 109 357 349 210 -144 -224 202 298 316 -218 -491 -540 -324 -137
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