File name: Pandora40s1_WallopsIslandVA_20241218_L2Fit_fout2c11d20230901p1-8.txt File generation date: 20241219T050558.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c11p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 40 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora40_OF_v2d20230731.txt Instrument calibration file used: Pandora40s1_CF_v11d20230901.txt Level 1 file used: Pandora40s1_WallopsIslandVA_20241218_L1_smca1c11d20230901p1-8.txt Full location name: Wallops Island X-75 Station, Wallops Flight Facility Geophysical Observatory Short location name: WallopsIslandVA Country of location: USA Location latitude [deg]: 37.8439 Location longitude [deg]: -75.4775 Location altitude [m]: 11 Local noon date: 20241218 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 10 First and last pixel inside fitting window: 228 370 Nominal wavelengths inside fitting window [nm]: 305.0793 305.2203 305.3612 305.5021 305.6430 305.7838 305.9247 306.0656 306.2064 306.3472 306.4881 306.6289 306.7697 306.9105 307.0512 307.1920 307.3328 307.4735 307.6142 307.7550 307.8957 308.0364 308.1771 308.3177 308.4584 308.5990 308.7397 308.8803 309.0209 309.1615 309.3021 309.4427 309.5833 309.7239 309.8644 310.0050 310.1455 310.2860 310.4265 310.5670 310.7075 310.8479 310.9884 311.1289 311.2693 311.4097 311.5501 311.6905 311.8309 311.9713 312.1117 312.2520 312.3924 312.5327 312.6730 312.8133 312.9536 313.0939 313.2342 313.3745 313.5147 313.6550 313.7952 313.9354 314.0756 314.2158 314.3560 314.4962 314.6363 314.7765 314.9166 315.0568 315.1969 315.3370 315.4771 315.6171 315.7572 315.8973 316.0373 316.1773 316.3174 316.4574 316.5974 316.7374 316.8773 317.0173 317.1573 317.2972 317.4371 317.5770 317.7170 317.8568 317.9967 318.1366 318.2765 318.4163 318.5561 318.6960 318.8358 318.9756 319.1154 319.2551 319.3949 319.5347 319.6744 319.8141 319.9539 320.0936 320.2333 320.3729 320.5126 320.6523 320.7919 320.9316 321.0712 321.2108 321.3504 321.4900 321.6296 321.7691 321.9087 322.0482 322.1878 322.3273 322.4668 322.6063 322.7458 322.8852 323.0247 323.1641 323.3036 323.4430 323.5824 323.7218 323.8612 324.0006 324.1399 324.2793 324.4186 324.5580 324.6973 324.8366 324.9759 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20241218T125019.1Z 9118.534943 78 1 49.37 2 84.54 125.43 64.98 279.21 0.00 1 0.00 1 0 41 6.074e-01 7.394e-02 5.058e-01 7.074e-02 7.896870e-01 4.187435e-02 9.836664e-03 -6.000000e+00 3.570723e-01 223.45 -2.00 3.45 -2.00 321.61 0.00e+00 -3.573896e-04 1.267970e-02 4.652238e-03 -6.000000e+00 1.616046e-02 279.52 -2.00 20.00 -2.00 321.00 0.00e+00 9.194 0.013 302.00 328.00 3 7.6567e-01 1.2679e-01 1.0133e-01 -6.0000e+00 8.7761e-01 1.6440e+00 1.4440e-01 4.3691e-02 -6.0000e+00 9.5074e-01 -2.0224e+00 8.9523e-02 2.2651e-02 -6.0000e+00 5.7032e-01 7.7086e-01 5.0466e-02 7.7310e-03 -6.0000e+00 2.5040e-01 1.1636e-05 -7.7045e-03 2.1475e-03 1.7450e-04 -6.0000e+00 1.8021e-02 -1.1557e-01 1.9813e-04 12 8 8 10 0 0 99.69 20.23 0.89 -0.11557 -0.17347 18 4 1 5 0 2742.740 25.17 20.00 20.23 15.62 6.4 1078.27 900000 115969 900000 90132 900000 147872 35639 -51084 23775 148183 21510 67993 -26643 80288 91356 900000 5172 45208 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900000 -3811 13905 -8798 1733 -10687 2522 6236 7124 5889 -83 9084 6117 984 3600 16854 -1590 5294 8830 3952 2238 2188 4861 1643 9134 -5032 7740 -11616 8104 -10136 425 2401 -2799 -2531 8400 7632 580 -588 -989 932 5790 3024 -3336 10268 -850 6632 -1890 -1487 11419 -7879 -6891 -10713 7211 -9116 4153 -1262 5270 -10232 15009 -3046 -7808 4304 -2422 7774 3535 11067 4468 10125 2637 -9358 -1715 -1549 2900 -21359 2584 1825 6140 5323 -5755 -8255 5188 -810 -10693 1549 2080 5471 -6444 9452 5745 595 -10478 995 -3273 4128 10060 3615 -10800 SU 20241218T152406.2Z 9118.641739 1092 1 10.03 2 65.17 156.04 92.83 300.00 0.00 1 0.00 1 0 41 2.832e-02 1.992e-02 1.423e-02 3.230e-03 2.790522e-01 1.660899e-03 3.408332e-03 -6.000000e+00 1.646779e-02 223.45 -2.00 3.45 -2.00 317.90 0.00e+00 9.419737e-04 2.802417e-04 5.740903e-04 -6.000000e+00 7.261302e-04 279.51 -2.00 20.00 -2.00 317.26 0.00e+00 2.366 0.000 302.00 328.00 3 3.5608e+00 4.3835e-03 2.7339e-02 -6.0000e+00 4.0549e-02 -3.4429e-02 4.9343e-03 1.4226e-02 -6.0000e+00 4.3994e-02 3.2012e-02 3.1653e-03 6.9512e-03 -6.0000e+00 2.6237e-02 -1.3220e-02 1.6458e-03 2.0449e-03 -6.0000e+00 1.1341e-02 1.0300e-03 -7.2124e-03 9.7642e-05 2.4754e-05 -6.0000e+00 8.1414e-04 -1.1429e-01 -6.8837e-05 12 9 9 12 1 1 99.97 20.43 0.29 -0.11429 -0.16849 9 11 1 5 0 1002.340 25.39 19.99 20.43 17.01 6.4 1091.45 900000 8048 4707 3815 4180 -5271 -4567 -2522 289 -3572 6962 -6009 -8008 -2730 -690 1274 922 1534 -623 2260 791 5092 1698 569 -1303 3580 1948 1434 919 -2542 -822 -3342 -245 1252 2484 -6692 -6727 -9124 -3586 -971 1438 612 202 2454 -280 626 753 208 -1773 -1558 -2971 -721 1650 1625 1435 201 1638 880 855 -632 -995 -1286 1241 2940 4543 3727 351 -3423 -5173 -3538 64 2626 2103 1622 814 280 -2115 -4151 -6136 -5616 -2234 -949 403 -618 -1048 -472 1490 1998 2854 2004 2332 1771 -1037 -2283 -4753 -2264 -1007 -13 1807 3157 2701 -190 -3541 -4684 -2889 -382 260 -284 -531 -169 1309 2843 3518 1766 34 -2039 -3112 -2794 -1584 -235 1499 2386 1235 815 780 430 -259 -2894 -2875 -984 687 730 -320 -1666 -1048 45 1314 655 785 1003 776 -310 -1609 900000 531 353 297 310 -393 -324 -184 23 -327 608 -599 -849 -307 -88 182 146 256 -111 408 151 955 329 114 -278 777 445 328 203 -556 -175 -768 -60 325 654 -1854 -1838 -2724 -1181 -366 606 281 98 1202 -142 316 381 105 -898 -782 -1524 -381 908 947 872 127 1045 575 558 -413 -653 -865 871 2174 3495 2889 268 -2539 -3833 -2731 53 2264 1885 1464 720 236 -1684 -3130 -4546 -4305 -1823 -841 381 -620 -1100 -516 1694 2354 3421 2406 2738 1993 -1119 -2346 -4899 -2384 -1129 -15 2292 4146 3541 -244 -4391 -5682 -3529 -482 342 -387 -748 -246 1980 4404 5485 2728 51 -2935 -4353 -3886 -2252 -345 2271 3655 1894 1232 1149 618 -361 -3993 -3981 -1405 1021 1123 -504 -2692 -1739 78 2301 1173 1422 1818 1397 -549 -2800 SU 20241218T153733.9Z 9118.651087 1140 1 48.25 2 64.16 159.27 95.06 302.04 0.00 1 0.00 1 0 41 2.649e-02 1.877e-02 7.788e-03 1.562e-03 2.692467e-01 8.025808e-04 3.263640e-03 -6.000000e+00 1.540789e-02 223.45 -2.00 3.45 -2.00 318.32 0.00e+00 7.503554e-04 1.499606e-04 5.109020e-04 -6.000000e+00 6.793965e-04 279.51 -2.00 20.00 -2.00 317.66 0.00e+00 2.280 0.000 302.00 328.00 3 3.3214e+00 2.1389e-03 2.6376e-02 -6.0000e+00 3.7939e-02 -3.0273e-02 2.4198e-03 1.3796e-02 -6.0000e+00 4.1163e-02 3.0899e-02 1.5936e-03 6.7170e-03 -6.0000e+00 2.4548e-02 -1.2601e-02 8.3367e-04 2.0329e-03 -6.0000e+00 1.0611e-02 1.4418e-03 -7.3462e-03 4.8091e-05 2.4213e-05 -6.0000e+00 7.6175e-04 -1.1463e-01 -8.1541e-05 12 9 9 12 1 1 99.98 20.49 0.22 -0.11463 -0.16983 80 19 1 5 0 595.630 25.39 20.02 20.49 17.36 6.4 1094.42 900000 2606 2085 3994 3561 -6096 -5707 -8666 -835 -2448 3620 -4708 -3714 -4521 712 826 2294 2979 -624 2775 368 3578 -1131 -432 -2401 1779 3094 1842 -1060 -2745 -3099 -3390 1508 1032 3410 -4290 -7793 -7333 -3481 -139 2054 1492 985 959 -349 312 526 1174 -1274 -1177 -2610 -990 565 945 1393 826 1131 1369 786 -621 -935 -1137 752 2200 3927 3686 155 -3068 -5482 -3224 707 2215 1901 2027 1037 837 -1719 -4477 -6056 -5821 -2404 -1142 44 -732 -1296 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