File name: Pandora40s1_WallopsIslandVA_20250104_L2Fit_fwvt1c11d20230901p1-8.txt File generation date: 20250105T051509.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c11p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 40 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora40_OF_v2d20230731.txt Instrument calibration file used: Pandora40s1_CF_v11d20230901.txt Level 1 file used: Pandora40s1_WallopsIslandVA_20250104_L1_smca1c11d20230901p1-8.txt Full location name: Wallops Island X-75 Station, Wallops Flight Facility Geophysical Observatory Short location name: WallopsIslandVA Country of location: USA Location latitude [deg]: 37.8439 Location longitude [deg]: -75.4775 Location altitude [m]: 11 Local noon date: 20250104 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 10 First and last pixel inside fitting window: 1649 1798 Nominal wavelengths inside fitting window [nm]: 492.0737 492.1948 492.3159 492.4369 492.5579 492.6790 492.8000 492.9209 493.0419 493.1628 493.2838 493.4047 493.5256 493.6465 493.7673 493.8882 494.0090 494.1298 494.2506 494.3714 494.4922 494.6129 494.7337 494.8544 494.9751 495.0958 495.2165 495.3371 495.4577 495.5784 495.6990 495.8196 495.9401 496.0607 496.1812 496.3017 496.4222 496.5427 496.6632 496.7837 496.9041 497.0245 497.1449 497.2653 497.3857 497.5061 497.6264 497.7467 497.8670 497.9873 498.1076 498.2279 498.3481 498.4683 498.5885 498.7087 498.8289 498.9491 499.0692 499.1893 499.3094 499.4295 499.5496 499.6697 499.7897 499.9098 500.0298 500.1498 500.2697 500.3897 500.5096 500.6296 500.7495 500.8694 500.9893 501.1091 501.2290 501.3488 501.4686 501.5884 501.7082 501.8279 501.9477 502.0674 502.1871 502.3068 502.4265 502.5462 502.6658 502.7855 502.9051 503.0247 503.1442 503.2638 503.3834 503.5029 503.6224 503.7419 503.8614 503.9808 504.1003 504.2197 504.3391 504.4585 504.5779 504.6973 504.8166 504.9360 505.0553 505.1746 505.2939 505.4131 505.5324 505.6516 505.7708 505.8900 506.0092 506.1283 506.2475 506.3666 506.4857 506.6048 506.7239 506.8430 506.9620 507.0811 507.2001 507.3191 507.4380 507.5570 507.6759 507.7949 507.9138 508.0327 508.1516 508.2704 508.3893 508.5081 508.6269 508.7457 508.8645 508.9832 509.1020 509.2207 509.3394 509.4581 509.5768 509.6955 509.8141 509.9327 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20250104T123531.6Z 9135.524671 74 1 31.00 2 87.81 121.19 124.47 72.80 0.00 1 0.00 1 0 36 9.571e-03 9.409e-03 1.453e-03 1.450e-03 2.714791e+03 8.604536e+01 1.847221e+02 -6.000000e+00 5.282929e+02 278.63 -2.00 20.00 -2.00 505.30 0.00e+00 1.882795e-03 4.013823e-05 1.124316e-04 -6.000000e+00 2.679677e-04 278.63 -2.00 20.00 -2.00 500.77 0.00e+00 1.804546e+00 2.865785e-02 2.791557e-02 -6.000000e+00 1.925887e-01 223.81 -2.00 3.45 -2.00 502.29 0.00e+00 15.605 0.065 489.00 513.00 1 5.7149e+00 2.1898e-03 2.4456e-02 -6.0000e+00 1.4713e-02 1.4861e-02 5.6975e-04 1.4239e-03 -6.0000e+00 3.8848e-03 5.9357e-04 -1.0681e-02 1.4860e-04 5.0234e-05 -6.0000e+00 1.0060e-03 -5.7585e-02 -4.9984e-04 12 8 8 10 0 0 97.21 18.62 1.61 -0.05758 -0.13167 8 2 1 4 0 3874.250 23.83 20.00 18.62 3.53 6.3 975.86 900000 -2792 -2434 -1404 -207 174 890 1191 1440 1261 1111 554 157 -280 -480 -650 -1451 -854 -624 680 686 879 -8 160 319 449 859 1036 926 637 -451 -1993 -2276 -1980 -254 870 1599 988 232 -289 -448 -745 -501 -158 618 640 844 960 831 693 355 -96 -1024 -2118 -2129 -1301 -199 685 1062 670 565 24 604 725 1070 1068 638 277 -219 -179 -465 -789 -1179 -999 106 682 1082 531 -598 -938 -1030 -1316 -798 -783 -493 -562 -184 258 -320 -509 -862 -381 -50 1130 1479 1796 1335 692 161 -548 -925 -1811 -1855 -1058 297 1365 1322 815 -558 -1145 -1360 -703 -210 404 591 852 364 737 1229 1051 904 337 -335 -778 -365 -59 522 465 448 122 354 488 597 -581 -1461 -1626 -1256 -630 -34 357 330 196 240 63 366 709 545 87 -502 -1799 900000 -2576 -2248 -1315 -198 160 834 1136 1391 1227 1078 533 150 -264 -450 -604 -1358 -803 -598 659 678 875 -8 161 323 456 872 1049 932 633 -441 -1933 -2194 -1927 -251 874 1626 1014 238 -295 -454 -755 -509 -162 635 666 883 1003 863 710 358 -94 -994 -2042 -2049 -1264 -197 690 1086 692 585 25 626 755 1113 1107 657 283 -221 -178 -459 -775 -1157 -984 105 677 1072 523 -586 -910 -995 -1275 -773 -764 -484 -557 -183 258 -322 -513 -874 -387 -51 1160 1527 1846 1361 696 159 -533 -886 -1728 -1779 -1030 296 1385 1276 789 -542 -1107 -1318 -684 -207 402 596 865 374 760 1267 1085 926 342 -338 -782 -365 -59 524 469 452 124 357 491 594 -577 -1446 -1604 -1245 -632 -35 369 346 208 257 68 395 765 588 94 -531 -1887 SO 20250104T123959.1Z 9135.527767 104 1 31.35 2 87.06 121.89 123.65 73.61 0.00 1 0.00 1 0 36 9.642e-03 9.481e-03 1.273e-03 1.271e-03 2.334494e+03 7.461789e+01 1.498267e+02 -6.000000e+00 5.322358e+02 278.63 -2.00 20.00 -2.00 505.29 0.00e+00 1.701830e-03 3.491673e-05 1.035278e-04 -6.000000e+00 2.699842e-04 278.63 -2.00 20.00 -2.00 500.70 0.00e+00 1.567019e+00 2.496388e-02 2.537971e-02 -6.000000e+00 1.940451e-01 223.81 -2.00 3.45 -2.00 502.24 0.00e+00 13.714 0.044 489.00 513.00 1 5.7421e+00 1.9005e-03 2.0872e-02 -6.0000e+00 1.4824e-02 1.6868e-02 5.0061e-04 1.2205e-03 -6.0000e+00 3.9145e-03 7.7214e-04 -1.0421e-02 1.3035e-04 4.4822e-05 -6.0000e+00 1.0136e-03 -6.7839e-02 -4.4683e-04 12 9 9 12 1 1 99.30 18.63 1.44 -0.06784 -0.14013 7 2 1 4 0 3918.040 23.83 20.00 18.63 3.63 6.3 976.89 900000 -2866 -2419 -1463 144 -24 912 956 1365 1490 1076 545 37 -204 -556 -996 -1443 -1121 -526 365 1137 1025 421 210 142 628 835 1024 1288 664 -647 -2144 -2349 -1898 -536 793 1538 916 386 36 -398 -461 -699 -114 388 789 1208 1136 1002 630 380 -447 -1088 -2187 -2209 -1565 -98 845 1300 611 388 93 212 742 1079 981 704 344 -326 14 -529 -613 -1211 -956 74 591 971 666 -895 -982 -858 -979 -841 -609 -541 -181 -105 160 -251 -333 -772 -332 -141 632 1306 1468 928 785 305 -415 -814 -1877 -1891 -1400 247 1328 1432 810 -365 -1321 -1230 -776 26 529 849 789 594 988 1066 1153 660 -30 -395 -690 -134 92 514 315 324 93 617 740 320 -246 -1078 -1661 -1390 -334 -274 260 566 59 -2 4 291 491 491 272 -720 -1678 900000 -2647 -2233 -1370 137 -24 914 920 1327 1455 1050 528 35 -206 -556 -991 -1441 -1126 -505 356 1123 1022 423 212 144 637 850 1038 1293 659 -635 -2083 -2266 -1845 -529 797 1563 939 395 37 -402 -465 -710 -116 399 817 1254 1180 1034 643 381 -440 -1051 -2097 -2115 -1515 -96 845 1317 627 399 96 219 767 1113 1009 719 347 -326 14 -518 -595 -1178 -934 73 582 954 649 -871 -944 -820 -936 -808 -587 -526 -177 -104 158 -251 -332 -775 -333 -143 645 1338 1500 942 783 299 -400 -771 -1776 -1798 -1355 243 1334 1457 827 -373 -1348 -1253 -796 26 554 849 797 606 1009 1093 1179 672 -30 -395 -687 -132 92 511 314 324 93 615 734 316 -240 -1111 -1617 -1360 -329 -276 265 583 61 -2 5 310 522 522 285 -749 -1726 SO 20250104T124119.9Z 9135.528703 107 1 33.06 2 86.84 122.11 123.40 73.85 0.00 1 0.00 1 0 36 9.643e-03 9.473e-03 9.029e-04 9.013e-04 2.407595e+03 5.291369e+01 1.561268e+02 -6.000000e+00 5.322977e+02 278.63 -2.00 20.00 -2.00 505.30 0.00e+00 1.708419e-03 2.476828e-05 1.073767e-04 -6.000000e+00 2.699146e-04 278.63 -2.00 20.00 -2.00 500.74 0.00e+00 1.555431e+00 1.768594e-02 2.564479e-02 -6.000000e+00 1.939379e-01 223.81 -2.00 3.45 -2.00 502.28 0.00e+00 13.193 0.039 489.00 513.00 1 5.3314e+00 1.3466e-03 1.9982e-02 -6.0000e+00 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