File name: Pandora40s1_WallopsIslandVA_20250131_L2Fit_fout2c11d20230901p1-8.txt File generation date: 20250201T052215.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c11p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 40 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora40_OF_v2d20230731.txt Instrument calibration file used: Pandora40s1_CF_v11d20230901.txt Level 1 file used: Pandora40s1_WallopsIslandVA_20250131_L1_smca1c11d20230901p1-8.txt Full location name: Wallops Island X-75 Station, Wallops Flight Facility Geophysical Observatory Short location name: WallopsIslandVA Country of location: USA Location latitude [deg]: 37.8439 Location longitude [deg]: -75.4775 Location altitude [m]: 11 Local noon date: 20250131 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 10 First and last pixel inside fitting window: 228 370 Nominal wavelengths inside fitting window [nm]: 305.0793 305.2203 305.3612 305.5021 305.6430 305.7838 305.9247 306.0656 306.2064 306.3472 306.4881 306.6289 306.7697 306.9105 307.0512 307.1920 307.3328 307.4735 307.6142 307.7550 307.8957 308.0364 308.1771 308.3177 308.4584 308.5990 308.7397 308.8803 309.0209 309.1615 309.3021 309.4427 309.5833 309.7239 309.8644 310.0050 310.1455 310.2860 310.4265 310.5670 310.7075 310.8479 310.9884 311.1289 311.2693 311.4097 311.5501 311.6905 311.8309 311.9713 312.1117 312.2520 312.3924 312.5327 312.6730 312.8133 312.9536 313.0939 313.2342 313.3745 313.5147 313.6550 313.7952 313.9354 314.0756 314.2158 314.3560 314.4962 314.6363 314.7765 314.9166 315.0568 315.1969 315.3370 315.4771 315.6171 315.7572 315.8973 316.0373 316.1773 316.3174 316.4574 316.5974 316.7374 316.8773 317.0173 317.1573 317.2972 317.4371 317.5770 317.7170 317.8568 317.9967 318.1366 318.2765 318.4163 318.5561 318.6960 318.8358 318.9756 319.1154 319.2551 319.3949 319.5347 319.6744 319.8141 319.9539 320.0936 320.2333 320.3729 320.5126 320.6523 320.7919 320.9316 321.0712 321.2108 321.3504 321.4900 321.6296 321.7691 321.9087 322.0482 322.1878 322.3273 322.4668 322.6063 322.7458 322.8852 323.0247 323.1641 323.3036 323.4430 323.5824 323.7218 323.8612 324.0006 324.1399 324.2793 324.4186 324.5580 324.6973 324.8366 324.9759 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250131T195852.8Z 9162.832556 308 1 49.84 2 67.05 222.76 47.84 195.04 0.00 1 0.00 1 0 33 2.083e-01 2.381e-02 1.648e-01 1.315e-02 3.131437e-01 6.822973e-03 3.818151e-03 -6.000000e+00 1.218421e-01 224.59 -2.00 3.45 -2.00 319.10 0.00e+00 -8.210778e-05 1.555263e-03 1.011700e-03 -6.000000e+00 5.303101e-03 277.89 -2.00 20.00 -2.00 318.48 0.00e+00 2.544 0.000 302.00 328.00 3 5.7346e+00 1.8630e-02 3.0102e-02 -6.0000e+00 3.0097e-01 4.7093e-03 2.1366e-02 1.7314e-02 -6.0000e+00 3.2622e-01 1.4792e-02 1.5456e-02 7.9431e-03 -6.0000e+00 1.9420e-01 -3.2571e-03 8.1854e-03 2.7545e-03 -6.0000e+00 8.3730e-02 9.2171e-05 -6.5548e-03 4.1219e-04 2.9377e-05 -6.0000e+00 5.9856e-03 -1.1689e-01 2.4730e-04 12 8 8 10 0 0 99.95 20.03 0.99 -0.11689 -0.16615 23 5 1 5 0 2166.620 25.07 20.00 20.03 12.65 6.4 1052.74 900000 134357 13031 -5737 78875 -8431 98759 -6848 28376 8794 131960 -39162 3728 16873 12072 17252 -2425 11075 -14650 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268 701 2223 982 1981 -604 -289 -3361 -3515 -4085 -799 -1794 1555 33 1075 -2386 1076 3212 -233 3314 1345 3799 -1801 -2798 -6009 -657 -923 -475 1966 3366 1858 -898 -2360 -6718 -2993 -1955 2570 269 -1111 174 3931 5062 4244 4649 -91 -739 -6292 -5231 -5638 -610 2926 2494 3671 1728 2689 -2262 639 -5403 -3423 -4344 824 1872 685 -2662 -3035 391 805 3557 2426 2967 253 152 -4300 SS 20250131T200840.4Z 9162.839357 311 1 5.29 2 68.39 224.84 48.34 198.16 0.00 1 0.00 1 0 41 5.541e-02 2.081e-02 3.324e-02 5.727e-03 3.101336e-01 2.956871e-03 3.737582e-03 -6.000000e+00 3.235111e-02 224.59 -2.00 3.45 -2.00 318.35 0.00e+00 2.766109e-04 5.594004e-04 5.398773e-04 -6.000000e+00 1.411315e-03 277.89 -2.00 20.00 -2.00 317.73 0.00e+00 2.690 0.000 302.00 328.00 3 3.5952e+00 7.9014e-03 3.0971e-02 -6.0000e+00 7.9908e-02 -6.8900e-02 8.9311e-03 1.6104e-02 -6.0000e+00 8.6664e-02 2.9465e-02 6.0211e-03 7.7586e-03 -6.0000e+00 5.1588e-02 -8.1189e-03 3.1733e-03 2.5458e-03 -6.0000e+00 2.2206e-02 7.1177e-04 -7.4127e-03 1.7367e-04 2.8394e-05 -6.0000e+00 1.5935e-03 -1.1281e-01 -8.8291e-05 12 9 9 12 9 1 99.79 20.06 0.21 -0.11281 -0.16851 3 8 1 5 0 1317.810 25.07 19.98 20.06 12.77 6.4 1052.40 900000 -8113 12465 15193 -9883 -6039 -18168 3373 -14321 25572 -18424 19815 -21664 5268 -3794 -70 1076 8351 7837 -3679 4618 -482 6952 -3401 1202 -211 3214 1156 -2966 2012 -5534 6974 -3352 5237 -1064 -3918 -13736 -3150 -3347 -476 2291 3010 2073 -493 3983 -853 680 -579 149 -1574 -2529 -786 -718 2046 286 1506 -210 2981 -1406 -76 -134 -1305 398 2120 4666 2691 1858 -4282 -4733 -3488 552 1442 2253 1396 1488 843 -2178 -3345 -8084 -4268 -4148 713 -773 143 -1265 231 735 1489 3118 2459 2971 1201 -593 -3012 -3902 -3051 -815 -613 1849 3756 1898 905 -3479 -4840 -3093 373 -46 743 -993 -523 2067 2702 3453 1066 116 -2902 -2666 -3212 -1366 -290 1650 2452 1013 1005 433 667 -770 -1464 -3762 -816 356 1163 -687 -1254 -898 796 817 385 1228 757 1671 -1191 -1812 900000 -448 627 771 -607 -331 -1073 172 -976 1337 -1537 1176 -1993 422 -386 -8 133 1028 1020 -558 676 -76 1030 -569 204 -39 596 218 -559 349 -1021 1220 -708 1111 -246 -902 -3420 -766 -949 -155 835 1186 870 -218 1720 -385 304 -261 66 -706 -1160 -375 -365 1081 160 864 -125 1762 -862 -45 -81 -811 260 1463 3335 1965 1312 -3007 -3311 -2555 430 1197 1924 1203 1248 675 -1656 -2397 -5844 -3128 -3323 605 -717 139 -1297 245 819 1718 3639 2873 3391 1327 -625 -3059 -3947 -3203 -907 -736 2339 4900 2498 1153 -4309 -5877 -3780 468 -61 1004 -1401 -764 3121 4212 5433 1674 176 -4273 -3791 -4570 -1978 -436 2541 3815 1579 1538 649 973 -1097 -2044 -5359 -1194 544 1837 -1119 -2087 -1537 1397 1482 713 2289 1420 3082 -2184 -3253 SS 20250131T201817.5Z 9162.846036 314 1 24.38 2 69.75 226.82 48.92 201.17 0.00 1 0.00 1 0 41 3.368e-02 1.873e-02 1.549e-02 1.872e-03 3.309848e-01 9.690964e-04 3.994181e-03 -6.000000e+00 1.967747e-02 224.59 -2.00 3.45 -2.00 318.95 0.00e+00 5.373783e-04 2.189412e-04 7.170712e-04 -6.000000e+00 8.579909e-04 277.89 -2.00 20.00 -2.00 318.34 0.00e+00 2.859 0.000 302.00 328.00 3 2.6990e+00 2.6405e-03 3.3064e-02 -6.0000e+00 4.8604e-02 -7.4979e-02 3.0207e-03 1.7541e-02 -6.0000e+00 5.2703e-02 3.3853e-02 2.1986e-03 8.3817e-03 -6.0000e+00 3.1373e-02 -1.2735e-02 1.1697e-03 2.7467e-03 -6.0000e+00 1.3511e-02 1.4444e-03 -6.8840e-03 5.7495e-05 3.0229e-05 -6.0000e+00 9.6854e-04 -1.1456e-01 -8.4391e-06 12 9 9 12 1 1 99.26 20.08 0.13 -0.11456 -0.16629 42 20 1 5 0 566.750 25.07 20.00 20.08 12.65 6.4 1052.56 900000 -327 4683 2839 -351 2425 -19479 -2548 -10983 4902 -5845 705 -8713 -2970 4298 -226 2212 -2673 4027 -2246 6950 -396 2963 -3538 2653 3073 2584 1963 -2515 -788 -6240 218 -2618 2085 -898 -2723 -10290 -7130 -3231 -305 2867 779 1866 251 1131 -151 1577 -88 30 -1298 -2854 -848 -99 1324 599 2125 299 1811 1005 56 -1592 -1409 543 2116 4822 3388 819 -4030 -4441 -3504 1441 1850 1899 1815 1203 1064 -2563 -4138 -7048 -5139 -2982 -870 -598 -731 -1244 -647 1026 1620 3019 2316 3040 1034 -284 -3492 -4082 -2800 -507 110 1601 3107 2185 -80 -3375 -4448 -3200 0 274 90 -511 -18 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