File name: Pandora40s1_WallopsIslandVA_20250307_L2Fit_fout2c11d20230901p1-8.txt File generation date: 20250308T051712.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c11p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 40 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora40_OF_v2d20230731.txt Instrument calibration file used: Pandora40s1_CF_v11d20230901.txt Level 1 file used: Pandora40s1_WallopsIslandVA_20250307_L1_smca1c11d20230901p1-8.txt Full location name: Wallops Island X-75 Station, Wallops Flight Facility Geophysical Observatory Short location name: WallopsIslandVA Country of location: USA Location latitude [deg]: 37.8439 Location longitude [deg]: -75.4775 Location altitude [m]: 11 Local noon date: 20250307 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 10 First and last pixel inside fitting window: 228 370 Nominal wavelengths inside fitting window [nm]: 305.0793 305.2203 305.3612 305.5021 305.6430 305.7838 305.9247 306.0656 306.2064 306.3472 306.4881 306.6289 306.7697 306.9105 307.0512 307.1920 307.3328 307.4735 307.6142 307.7550 307.8957 308.0364 308.1771 308.3177 308.4584 308.5990 308.7397 308.8803 309.0209 309.1615 309.3021 309.4427 309.5833 309.7239 309.8644 310.0050 310.1455 310.2860 310.4265 310.5670 310.7075 310.8479 310.9884 311.1289 311.2693 311.4097 311.5501 311.6905 311.8309 311.9713 312.1117 312.2520 312.3924 312.5327 312.6730 312.8133 312.9536 313.0939 313.2342 313.3745 313.5147 313.6550 313.7952 313.9354 314.0756 314.2158 314.3560 314.4962 314.6363 314.7765 314.9166 315.0568 315.1969 315.3370 315.4771 315.6171 315.7572 315.8973 316.0373 316.1773 316.3174 316.4574 316.5974 316.7374 316.8773 317.0173 317.1573 317.2972 317.4371 317.5770 317.7170 317.8568 317.9967 318.1366 318.2765 318.4163 318.5561 318.6960 318.8358 318.9756 319.1154 319.2551 319.3949 319.5347 319.6744 319.8141 319.9539 320.0936 320.2333 320.3729 320.5126 320.6523 320.7919 320.9316 321.0712 321.2108 321.3504 321.4900 321.6296 321.7691 321.9087 322.0482 322.1878 322.3273 322.4668 322.6063 322.7458 322.8852 323.0247 323.1641 323.3036 323.4430 323.5824 323.7218 323.8612 324.0006 324.1399 324.2793 324.4186 324.5580 324.6973 324.8366 324.9759 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250307T123845.0Z 9197.526910 135 1 26.82 2 76.48 107.56 113.38 11.53 0.00 1 0.00 1 0 41 2.042e-01 1.784e-02 2.125e-01 4.530e-03 5.131528e-01 2.445014e-03 5.901182e-03 -6.000000e+00 1.198218e-01 226.12 -2.00 3.45 -2.00 320.68 0.00e+00 -4.172463e-04 9.727478e-04 5.295083e-04 -6.000000e+00 5.223544e-03 278.96 -2.00 20.00 -2.00 320.14 0.00e+00 4.175 0.001 302.00 328.00 3 2.6307e+00 7.5974e-03 4.9459e-02 -6.0000e+00 2.9688e-01 -1.0923e-01 9.7491e-03 2.7682e-02 -6.0000e+00 3.2168e-01 3.2513e-02 9.5569e-03 1.4229e-02 -6.0000e+00 1.9139e-01 -5.4722e-03 4.7759e-03 5.9662e-03 -6.0000e+00 8.2104e-02 3.5849e-04 -5.7406e-03 1.3977e-04 6.1287e-05 -6.0000e+00 5.8774e-03 -1.0547e-01 -6.5648e-05 12 9 9 12 1 1 94.03 19.41 0.21 -0.10547 -0.14861 24 11 1 5 0 1072.800 24.56 20.00 19.41 8.93 6.5 1029.61 900000 42040 -48494 100122 -88851 -67021 5448 -78544 -61119 -29961 67638 160 -16168 -61022 26890 -33486 15740 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221 -1175 -2158 -2643 -2122 -1404 -396 -124 -39 -1341 -96 801 1687 3306 2387 1888 920 -1465 -2142 -3184 -1724 -991 633 2175 3015 2074 -677 -4493 -5667 -3461 296 1364 -441 -1029 -155 2291 4359 4525 2547 -55 -3374 -4592 -4603 -2613 1401 3062 3857 561 1576 503 1367 -936 -3846 -4366 -444 2265 756 -1365 -3657 -1517 -51 2566 1079 2280 2265 2202 -1163 -4111 SS 20250307T124924.0Z 9197.534306 138 1 48.67 2 74.48 109.36 112.94 13.90 0.00 1 0.00 1 0 25 1.048e-01 1.765e-02 5.932e-02 2.238e-03 4.616913e-01 1.196674e-03 5.369164e-03 -6.000000e+00 6.153327e-02 226.12 -2.00 3.45 -2.00 320.40 0.00e+00 -8.703393e-04 4.296557e-04 1.034754e-03 -6.000000e+00 2.682006e-03 278.96 -2.00 20.00 -2.00 319.83 0.00e+00 3.670 0.001 302.00 328.00 3 2.1707e+00 3.5936e-03 4.4089e-02 -6.0000e+00 1.5246e-01 -1.0024e-01 4.4549e-03 2.6034e-02 -6.0000e+00 1.6518e-01 4.7047e-02 4.1070e-03 1.2346e-02 -6.0000e+00 9.8271e-02 -1.5418e-02 2.0918e-03 5.6439e-03 -6.0000e+00 4.2174e-02 9.6070e-04 -5.7384e-03 6.9996e-05 5.1593e-05 -6.0000e+00 3.0166e-03 -1.0703e-01 -2.9119e-05 12 8 8 10 0 0 99.92 19.45 0.17 -0.10703 -0.15015 122 28 1 5 0 398.870 24.56 20.00 19.45 9.26 6.5 1032.42 900000 -17352 -29905 -47298 -24686 -12816 9156 -42701 -42778 -36276 -32579 -43161 -26320 -30419 -183 3210 -1701 -4376 -7437 -283 -2738 -3722 -9126 -561 2701 4695 6850 4054 -2536 -597 -3328 -2781 2462 1973 4019 -7378 -8373 -7655 -3195 1080 2773 2134 2890 3277 1387 1747 1579 94 -1987 -1727 -3611 -375 -36 2036 1160 1102 1867 1956 1716 -9 232 -1468 1288 2361 4218 3240 -905 -4283 -5339 -2087 1050 2330 1605 1591 754 561 -2243 -5055 -6567 -5324 -2520 -1097 -557 -432 -1626 -752 1449 2137 3118 2949 2588 1178 -1120 -3790 -3855 -2304 -838 -20 1463 3012 1560 -834 -3717 -4940 -2544 44 336 -476 -452 157 1672 2682 2880 1620 -203 -2294 -3204 -2554 -1384 491 1957 1805 582 719 814 753 -501 -2850 -3051 -592 1037 760 -704 -1655 -865 205 903 403 861 1338 887 -561 -1889 900000 -159 -344 -669 -276 -121 70 -576 -665 -602 -563 -861 -495 -700 -4 77 -49 -140 -264 -10 -105 -149 -392 -23 119 222 334 204 -132 -30 -176 -164 157 141 293 -590 -680 -685 -326 129 379 328 473 555 244 310 283 17 -376 -338 -748 -83 -9 521 321 321 564 607 534 -3 72 -479 447 900 1713 1359 -381 -1794 -2305 -962 532 1261 912 908 414 285 -1074 -2311 -3040 -2659 -1396 -688 -384 -322 -1307 -633 1275 1973 2926 2753 2335 1020 -930 -3065 -3171 -2040 -818 -22 1721 3717 1941 -991 -4192 -5431 -2808 50 405 -603 -606 223 2534 4319 4764 2665 -323 -3523 -4760 -3835 -2128 787 3194 3002 956 1140 1260 1120 -730 -4123 -4572 -937 1758 1367 -1325 -3274 -1774 438 2005 915 1972 3040 1990 -1228 -3994 SS 20250307T125921.7Z 9197.541224 141 1 48.88 2 72.63 111.09 112.45 16.10 0.00 1 0.00 1 0 33 5.122e-02 1.805e-02 4.581e-02 2.205e-03 4.188069e-01 1.172137e-03 4.986609e-03 -6.000000e+00 3.005822e-02 226.12 -2.00 3.45 -2.00 319.99 0.00e+00 -4.874344e-04 3.699470e-04 1.372440e-03 -6.000000e+00 1.310204e-03 278.96 -2.00 20.00 -2.00 319.40 0.00e+00 3.302 0.001 302.00 328.00 3 2.6709e+00 3.4077e-03 4.0003e-02 -6.0000e+00 7.4474e-02 -8.5800e-02 4.0892e-03 2.4426e-02 -6.0000e+00 8.0688e-02 4.7753e-02 3.5201e-03 1.0900e-02 -6.0000e+00 4.8006e-02 -1.6312e-02 1.8282e-03 4.6808e-03 -6.0000e+00 2.0601e-02 8.6039e-04 -5.7966e-03 6.9054e-05 4.2640e-05 -6.0000e+00 1.4738e-03 -1.0688e-01 -4.4658e-05 12 8 8 10 0 0 99.76 19.49 0.16 -0.10688 -0.15044 77 18 1 5 0 634.730 24.56 20.00 19.49 9.49 6.5 1035.10 900000 8305 12758 19619 -11538 -1481 -22590 -22358 4325 -1140 6666 -23438 6610 -14093 -5295 -1282 -503 -313 -2367 2827 -1102 3780 -3033 419 -3480 6119 2011 4600 677 -7339 -6387 -3892 1569 1549 -1807 -3503 -9008 -9125 -4092 1141 622 2261 1518 974 1122 1371 1350 -793 -2437 -1379 -3143 -2516 435 1112 1295 1299 550 672 969 4 -400 -733 494 2999 4101 3659 -559 -3690 -5024 -2679 1233 2414 2162 2434 985 736 -2226 -5329 -6094 -5070 -2300 -893 -296 -395 -1271 -383 941 1849 2917 2472 2350 1227 -908 -3216 -4449 -1912 -940 351 1351 3083 1649 -643 -3792 -4980 -2686 -243 439 -444 -375 -103 1768 2689 2938 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