File name: Pandora40s1_WallopsIslandVA_20250319_L2Fit_fwvt1c11d20230901p1-8.txt File generation date: 20250320T052341.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c11p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 40 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora40_OF_v2d20230731.txt Instrument calibration file used: Pandora40s1_CF_v11d20230901.txt Level 1 file used: Pandora40s1_WallopsIslandVA_20250319_L1_smca1c11d20230901p1-8.txt Full location name: Wallops Island X-75 Station, Wallops Flight Facility Geophysical Observatory Short location name: WallopsIslandVA Country of location: USA Location latitude [deg]: 37.8439 Location longitude [deg]: -75.4775 Location altitude [m]: 11 Local noon date: 20250319 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 10 First and last pixel inside fitting window: 1649 1798 Nominal wavelengths inside fitting window [nm]: 492.0737 492.1948 492.3159 492.4369 492.5579 492.6790 492.8000 492.9209 493.0419 493.1628 493.2838 493.4047 493.5256 493.6465 493.7673 493.8882 494.0090 494.1298 494.2506 494.3714 494.4922 494.6129 494.7337 494.8544 494.9751 495.0958 495.2165 495.3371 495.4577 495.5784 495.6990 495.8196 495.9401 496.0607 496.1812 496.3017 496.4222 496.5427 496.6632 496.7837 496.9041 497.0245 497.1449 497.2653 497.3857 497.5061 497.6264 497.7467 497.8670 497.9873 498.1076 498.2279 498.3481 498.4683 498.5885 498.7087 498.8289 498.9491 499.0692 499.1893 499.3094 499.4295 499.5496 499.6697 499.7897 499.9098 500.0298 500.1498 500.2697 500.3897 500.5096 500.6296 500.7495 500.8694 500.9893 501.1091 501.2290 501.3488 501.4686 501.5884 501.7082 501.8279 501.9477 502.0674 502.1871 502.3068 502.4265 502.5462 502.6658 502.7855 502.9051 503.0247 503.1442 503.2638 503.3834 503.5029 503.6224 503.7419 503.8614 503.9808 504.1003 504.2197 504.3391 504.4585 504.5779 504.6973 504.8166 504.9360 505.0553 505.1746 505.2939 505.4131 505.5324 505.6516 505.7708 505.8900 506.0092 506.1283 506.2475 506.3666 506.4857 506.6048 506.7239 506.8430 506.9620 507.0811 507.2001 507.3191 507.4380 507.5570 507.6759 507.7949 507.9138 508.0327 508.1516 508.2704 508.3893 508.5081 508.6269 508.7457 508.8645 508.9832 509.1020 509.2207 509.3394 509.4581 509.5768 509.6955 509.8141 509.9327 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250319T111143.5Z 9209.466476 211 1 41.39 2 89.80 90.60 71.69 216.44 0.00 1 0.00 1 0 50 1.368e-02 1.326e-02 3.928e-04 3.886e-04 9.249874e+03 2.542812e+01 5.507943e+02 -6.000000e+00 7.585279e+02 279.77 -2.00 20.00 -2.00 505.48 0.00e+00 3.832411e-03 1.086520e-05 2.355614e-04 -6.000000e+00 3.833710e-04 279.77 -2.00 20.00 -2.00 501.37 0.00e+00 1.209704e+00 7.494763e-03 8.943610e-02 -6.000000e+00 2.753977e-01 226.82 -2.00 3.45 -2.00 502.81 0.00e+00 20.283 0.142 489.00 513.00 1 2.9085e+00 5.6802e-04 3.6729e-02 -6.0000e+00 2.1052e-02 -5.6141e-02 1.4710e-04 2.6827e-03 -6.0000e+00 5.5414e-03 5.0793e-03 -1.3728e-02 3.8811e-05 1.0882e-04 -6.0000e+00 1.4374e-03 2.3536e-02 -7.6923e-04 12 9 9 12 1 1 67.38 19.63 6.54 0.02354 -0.07169 120 33 1 4 0 341.790 24.65 19.99 19.63 10.41 6.6 1002.66 900000 -3843 -3263 -1695 -151 793 1552 1985 2443 2308 1741 816 122 -389 -941 -1447 -1689 -1342 -453 751 1131 1117 506 450 587 1030 1277 1326 1103 262 -1169 -2736 -3079 -2241 -409 1130 1603 1069 303 -211 -703 -616 -372 245 778 1348 1632 1646 1258 872 85 -950 -2099 -2908 -2731 -1667 -38 1104 1497 1212 921 729 998 1357 1513 1393 831 223 -314 -551 -998 -1437 -1659 -1229 -403 320 355 -484 -1439 -2040 -2000 -1855 -1584 -1460 -1120 -794 -461 -318 -548 -792 -955 -572 213 1559 2303 2316 1577 667 -79 -821 -1705 -2717 -2844 -1931 -115 1158 1329 447 -829 -1572 -1455 -626 309 881 1172 1299 1389 1731 2148 2196 1583 681 -192 -516 -95 552 913 791 720 645 874 808 306 -813 -1540 -1785 -1448 -686 -98 127 372 392 396 381 527 654 526 -46 -1040 -2333 900000 -3139 -2679 -1411 -129 690 1378 1793 2229 2119 1599 748 111 -352 -847 -1302 -1527 -1225 -419 706 1015 1012 463 414 543 957 1191 1237 1025 242 -1067 -2485 -2797 -2056 -381 1069 1538 1033 294 -203 -680 -597 -362 241 773 1353 1649 1665 1270 872 84 -928 -2028 -2797 -2634 -1628 -38 1115 1534 1184 905 720 990 1351 1510 1388 825 220 -307 -535 -965 -1467 -1602 -1192 -393 313 348 -474 -1401 -1975 -1927 -1788 -1531 -1422 -1099 -786 -459 -318 -550 -796 -961 -577 216 1586 2341 2337 1571 653 -76 -778 -1696 -2560 -2712 -1883 -114 1186 1386 471 -881 -1674 -1557 -674 318 917 1231 1374 1483 1862 2327 2386 1721 736 -207 -552 -101 590 981 856 783 703 952 879 332 -880 -1664 -1936 -1586 -761 -111 146 411 438 447 434 603 749 602 -53 -1174 -2627 SQ 20250319T111500.0Z 9209.468750 215 1 48.82 2 89.16 91.10 72.07 217.09 0.00 1 0.00 1 0 50 1.166e-02 1.136e-02 1.982e-04 1.966e-04 7.348282e+03 1.260765e+01 4.557661e+02 -6.000000e+00 6.469732e+02 279.77 -2.00 20.00 -2.00 505.44 0.00e+00 3.063955e-03 5.495624e-06 1.921457e-04 -6.000000e+00 3.270455e-04 279.77 -2.00 20.00 -2.00 501.26 0.00e+00 1.242351e+00 3.828165e-03 6.883670e-02 -6.000000e+00 2.350313e-01 226.82 -2.00 3.45 -2.00 502.72 0.00e+00 19.087 0.119 489.00 513.00 1 1.9616e+00 2.9151e-04 3.3051e-02 -6.0000e+00 1.7964e-02 -3.8749e-02 7.5271e-05 2.2667e-03 -6.0000e+00 4.7327e-03 1.5686e-02 -1.2916e-02 1.9811e-05 9.4070e-05 -6.0000e+00 1.2257e-03 1.2147e-02 -7.5438e-04 12 8 8 10 0 0 36.85 19.63 3.99 0.01215 -0.07744 378 86 1 4 0 129.140 24.65 19.99 19.63 10.48 6.6 1003.73 900000 -3290 -2617 -1234 68 835 1351 1773 2079 2047 1529 796 193 -229 -661 -1147 -1432 -1166 -315 679 1108 873 462 265 428 781 1093 1081 1058 415 -886 -2384 -2778 -1978 -334 1067 1487 986 192 -356 -698 -731 -458 -13 504 1044 1366 1305 1049 688 103 -757 -1768 -2564 -2558 -1527 3 1044 1307 989 594 450 712 1027 1288 1191 753 183 -248 -450 -735 -1199 -1422 -1095 -259 552 564 -183 -1141 -1603 -1575 -1450 -1287 -1120 -881 -619 -279 -215 -419 -701 -830 -622 89 1179 1931 1928 1372 650 42 -622 -1475 -2371 -2560 -1667 -73 1127 1309 425 -705 -1469 -1385 -695 135 710 967 945 983 1305 1684 1791 1240 464 -304 -590 -224 419 715 657 562 579 755 844 452 -530 -1253 -1607 -1236 -547 19 263 368 302 293 296 415 621 606 112 -866 -2015 900000 -2785 -2221 -1063 60 754 1248 1574 1867 1847 1380 715 172 -203 -582 -1008 -1264 -1040 -285 624 1034 824 440 253 411 754 1059 1047 1018 396 -835 -2231 -2599 -1867 -320 1042 1472 984 192 -355 -694 -728 -435 -13 488 1018 1339 1282 1026 666 99 -752 -1734 -2499 -2502 -1511 3 1013 1287 984 595 452 718 1039 1305 1205 758 183 -246 -442 -716 -1165 -1383 -1071 -255 545 557 -180 -1118 -1559 -1525 -1403 -1251 -1097 -870 -617 -280 -217 -424 -711 -843 -635 91 1215 1991 1977 1389 647 41 -598 -1405 -2260 -2469 -1641 -74 1165 1307 429 -714 -1489 -1408 -712 140 743 1021 1007 1056 1412 1832 1951 1349 502 -327 -630 -239 447 767 709 608 627 818 911 486 -567 -1339 -1723 -1337 -599 20 283 402 334 328 334 470 703 685 126 -964 -2233 SQ 20250319T111816.6Z 9209.471026 219 1 48.82 2 88.51 91.61 72.46 217.74 0.00 1 0.00 1 0 50 1.064e-02 1.043e-02 1.282e-04 1.277e-04 5.894845e+03 7.968591e+00 3.818166e+02 -6.000000e+00 5.902459e+02 279.77 -2.00 20.00 -2.00 505.38 0.00e+00 2.680783e-03 3.550886e-06 1.668361e-04 -6.000000e+00 2.984647e-04 279.77 -2.00 20.00 -2.00 501.06 0.00e+00 1.150769e+00 2.489389e-03 5.339667e-02 -6.000000e+00 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