File name: Pandora40s1_WallopsIslandVA_20250324_L2Fit_fout2c11d20230901p1-8.txt File generation date: 20250325T051425.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c11p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 40 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora40_OF_v2d20230731.txt Instrument calibration file used: Pandora40s1_CF_v11d20230901.txt Level 1 file used: Pandora40s1_WallopsIslandVA_20250324_L1_smca1c11d20230901p1-8.txt Full location name: Wallops Island X-75 Station, Wallops Flight Facility Geophysical Observatory Short location name: WallopsIslandVA Country of location: USA Location latitude [deg]: 37.8439 Location longitude [deg]: -75.4775 Location altitude [m]: 11 Local noon date: 20250324 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 10 First and last pixel inside fitting window: 228 370 Nominal wavelengths inside fitting window [nm]: 305.0793 305.2203 305.3612 305.5021 305.6430 305.7838 305.9247 306.0656 306.2064 306.3472 306.4881 306.6289 306.7697 306.9105 307.0512 307.1920 307.3328 307.4735 307.6142 307.7550 307.8957 308.0364 308.1771 308.3177 308.4584 308.5990 308.7397 308.8803 309.0209 309.1615 309.3021 309.4427 309.5833 309.7239 309.8644 310.0050 310.1455 310.2860 310.4265 310.5670 310.7075 310.8479 310.9884 311.1289 311.2693 311.4097 311.5501 311.6905 311.8309 311.9713 312.1117 312.2520 312.3924 312.5327 312.6730 312.8133 312.9536 313.0939 313.2342 313.3745 313.5147 313.6550 313.7952 313.9354 314.0756 314.2158 314.3560 314.4962 314.6363 314.7765 314.9166 315.0568 315.1969 315.3370 315.4771 315.6171 315.7572 315.8973 316.0373 316.1773 316.3174 316.4574 316.5974 316.7374 316.8773 317.0173 317.1573 317.2972 317.4371 317.5770 317.7170 317.8568 317.9967 318.1366 318.2765 318.4163 318.5561 318.6960 318.8358 318.9756 319.1154 319.2551 319.3949 319.5347 319.6744 319.8141 319.9539 320.0936 320.2333 320.3729 320.5126 320.6523 320.7919 320.9316 321.0712 321.2108 321.3504 321.4900 321.6296 321.7691 321.9087 322.0482 322.1878 322.3273 322.4668 322.6063 322.7458 322.8852 323.0247 323.1641 323.3036 323.4430 323.5824 323.7218 323.8612 324.0006 324.1399 324.2793 324.4186 324.5580 324.6973 324.8366 324.9759 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250324T125853.5Z 9214.540897 170 1 24.96 2 67.39 106.51 63.56 179.72 0.00 1 0.00 1 0 33 3.702e-02 1.851e-02 2.610e-02 2.550e-03 3.551960e-01 1.330388e-03 4.219946e-03 -6.000000e+00 2.183552e-02 227.22 -2.00 3.45 -2.00 319.27 0.00e+00 9.915817e-05 3.330739e-04 8.505076e-04 -6.000000e+00 9.522899e-04 280.26 -2.00 20.00 -2.00 318.63 0.00e+00 2.580 0.000 302.00 328.00 3 3.3944e+00 3.6860e-03 3.1747e-02 -6.0000e+00 5.4216e-02 -1.0670e-01 4.2572e-03 1.9218e-02 -6.0000e+00 5.8664e-02 3.8272e-02 3.2089e-03 8.9956e-03 -6.0000e+00 3.4899e-02 -1.2871e-02 1.7020e-03 3.1754e-03 -6.0000e+00 1.4972e-02 9.0789e-04 -6.2373e-03 7.8935e-05 3.2055e-05 -6.0000e+00 1.0654e-03 -1.1119e-01 2.0302e-05 12 9 9 12 9 1 99.95 20.40 0.23 -0.11119 -0.15806 32 15 1 5 0 756.340 25.39 20.00 20.40 15.88 6.6 1034.58 900000 -3676 -7536 343 -5146 -18863 5268 -19388 -3486 -6436 -5778 -6948 -4780 -4641 7302 5558 2297 -2277 1621 -238 -499 869 -159 1356 1103 1386 3619 3707 -1992 -5029 -3549 -2283 -2484 316 -315 -4181 -7540 -8726 -2406 182 3069 2095 656 941 817 1311 318 145 -1501 -964 -2826 -430 299 1699 1113 1071 806 1511 604 -76 -1002 -1261 710 2175 4525 3490 352 -3849 -5015 -2899 1081 2773 2534 1883 1102 725 -2809 -4672 -6786 -5262 -2719 -1299 -657 -266 -1863 -418 1221 2365 2996 2567 2288 1233 -1048 -3469 -4498 -2554 -749 217 1417 3263 1918 -93 -3901 -4640 -2751 -134 619 23 -333 -340 1525 2519 2852 1717 196 -1917 -3296 -2614 -1634 273 1583 2051 998 738 835 611 -396 -2520 -2773 -586 610 710 -413 -1424 -1025 246 960 735 875 976 857 -487 -1689 900000 -98 -235 10 -155 -602 128 -645 -113 -242 -230 -287 -206 -229 380 344 165 -185 134 -21 -47 82 -15 133 116 157 421 430 -235 -587 -410 -282 -345 47 -49 -650 -1203 -1537 -473 42 807 573 193 286 253 438 108 49 -513 -329 -1010 -160 112 674 471 473 369 702 283 -35 -468 -612 365 1211 2638 2082 206 -2212 -2905 -1785 722 1991 1905 1422 806 495 -1797 -2791 -4031 -3283 -1878 -1005 -561 -243 -1839 -405 1247 2527 3275 2808 2423 1233 -1056 -3335 -4340 -2591 -778 250 1787 4295 2546 -118 -4708 -5388 -3228 -164 801 31 -480 -491 2328 4041 4655 2763 301 -2796 -4943 -3892 -2521 413 2492 3270 1583 1136 1321 928 -579 -3621 -4064 -905 949 1172 -712 -2559 -1926 484 1852 1465 1769 1976 1699 -939 -3349 SS 20250324T132037.5Z 9214.555989 182 1 48.98 2 63.31 110.46 63.69 185.06 0.00 1 0.00 1 0 33 3.392e-02 1.873e-02 1.874e-02 2.373e-03 3.105064e-01 1.240205e-03 3.688206e-03 -6.000000e+00 2.000282e-02 227.22 -2.00 3.45 -2.00 319.09 0.00e+00 6.352951e-05 2.863428e-04 6.083296e-04 -6.000000e+00 8.724781e-04 280.26 -2.00 20.00 -2.00 318.43 0.00e+00 2.214 0.000 302.00 328.00 3 3.6821e+00 3.4127e-03 2.7342e-02 -6.0000e+00 4.9665e-02 -8.2598e-02 3.9094e-03 1.6528e-02 -6.0000e+00 5.3743e-02 3.6459e-02 2.7957e-03 7.8373e-03 -6.0000e+00 3.1971e-02 -1.3616e-02 1.4721e-03 2.7238e-03 -6.0000e+00 1.3714e-02 1.0180e-03 -6.5273e-03 7.4342e-05 2.8854e-05 -6.0000e+00 9.7616e-04 -1.1060e-01 4.5740e-06 12 8 8 10 0 0 99.99 20.45 0.16 -0.11060 -0.15965 135 31 1 5 0 362.790 25.39 20.00 20.45 16.32 6.6 1039.15 900000 -3648 15538 -6357 8222 -7221 -4934 2416 -6321 14380 -2278 7519 -5511 1900 -5415 2656 1384 2766 -584 -1174 4134 -28 3078 -2067 4457 1622 2891 905 3527 -2166 -2061 -1834 -2381 3438 -485 -1190 -10126 -4482 -3934 566 1514 2296 1228 164 284 -665 1658 -1752 -853 -3199 -2193 -609 110 1268 890 725 -65 1608 139 274 -1957 -418 109 2719 4144 3719 201 -4190 -4307 -3567 1671 1582 2450 1154 1781 122 -1467 -4549 -7097 -5154 -2797 -1233 -1001 -356 -1802 -262 822 2290 2729 2772 2981 845 -150 -3579 -4206 -2996 -384 80 1674 3086 2360 -350 -3311 -4411 -2958 358 137 -59 -662 63 1288 2662 2931 1492 108 -2225 -3280 -3195 -1331 -213 1706 1431 1273 913 533 184 -619 -2675 -3268 -498 565 1024 -563 -1379 -1082 136 1040 409 1022 1281 1029 -572 -1830 900000 -142 559 -289 313 -294 -189 92 -295 617 -121 369 -322 116 -413 215 126 264 -61 -128 449 -3 350 -253 545 219 401 128 465 -290 -273 -260 -374 555 -84 -200 -1840 -835 -861 142 435 718 412 57 101 -239 586 -635 -303 -1158 -801 -233 45 550 407 346 -32 799 70 136 -992 -215 60 1590 2548 2306 122 -2495 -2550 -2251 1123 1157 1852 885 1311 85 -951 -2795 -4325 -3257 -1931 -943 -838 -317 -1717 -261 867 2507 3063 3090 3225 879 -146 -3347 -3911 -2915 -401 92 2071 3985 3046 -438 -3941 -5122 -3485 438 177 -80 -938 93 2015 4317 4823 2421 167 -3297 -4701 -4566 -1948 -327 2709 2322 2046 1436 813 271 -881 -3746 -4644 -736 884 1676 -957 -2422 -1975 257 2045 828 2093 2622 2083 -1133 -3546 SS 20250324T135358.0Z 9214.579144 206 1 48.80 2 57.28 117.09 64.62 193.16 0.00 1 0.00 1 0 33 2.819e-02 1.875e-02 1.141e-02 2.355e-03 2.635164e-01 1.224221e-03 3.172540e-03 -6.000000e+00 1.662305e-02 227.22 -2.00 3.45 -2.00 318.36 0.00e+00 6.009241e-04 2.268241e-04 5.704878e-04 -6.000000e+00 7.252099e-04 280.27 -2.00 20.00 -2.00 317.68 0.00e+00 1.844 0.000 302.00 328.00 3 4.2340e+00 3.2838e-03 2.2839e-02 -6.0000e+00 4.1274e-02 -4.9177e-02 3.7062e-03 1.3726e-02 -6.0000e+00 4.4665e-02 2.2361e-02 2.4138e-03 6.5897e-03 -6.0000e+00 2.6571e-02 -8.9781e-03 1.2502e-03 1.9903e-03 -6.0000e+00 1.1396e-02 8.8980e-04 -7.1128e-03 7.2949e-05 2.3073e-05 -6.0000e+00 8.1146e-04 -1.1147e-01 -9.2430e-05 12 9 9 12 1 1 99.98 20.57 0.15 -0.11147 -0.16492 76 18 1 5 0 633.640 25.47 20.03 20.57 17.07 6.7 1045.90 900000 7669 4185 1895 -94 417 -8884 -4596 -3757 7375 2817 -4771 -6965 -5909 1231 974 3930 493 828 2156 1217 4018 1823 -2403 966 2760 1406 1971 -286 -2286 -5758 -1214 -949 2203 2392 -3042 -6758 -8036 -4985 440 2935 412 1172 564 907 -533 571 -377 -2065 -2048 -2532 -1290 715 952 1102 1090 962 1882 365 -749 -883 -703 501 2232 4341 3602 868 -3774 -4782 -3796 1402 1921 2199 1727 1262 967 -2228 -4062 -6731 -5299 -2426 -781 -299 -872 -1379 -782 944 1888 2968 2060 2581 1257 -894 -3592 -4044 -2841 -787 125 1791 3188 2113 -55 -3311 -4281 -2651 -101 185 -191 -538 -310 1325 2466 3048 1550 121 -2329 -2929 -2993 -1644 49 1660 2133 994 823 337 527 -496 -2443 -3017 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