File name: Pandora40s1_WallopsIslandVA_20250717_L2Fit_fout2c11d20230901p1-8.txt File generation date: 20250718T052522.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c11p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 40 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora40_OF_v2d20230731.txt Instrument calibration file used: Pandora40s1_CF_v11d20230901.txt Level 1 file used: Pandora40s1_WallopsIslandVA_20250717_L1_smca1c11d20230901p1-8.txt Full location name: Wallops Island X-75 Station, Wallops Flight Facility Geophysical Observatory Short location name: WallopsIslandVA Country of location: USA Location latitude [deg]: 37.8439 Location longitude [deg]: -75.4775 Location altitude [m]: 11 Local noon date: 20250717 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 10 First and last pixel inside fitting window: 228 370 Nominal wavelengths inside fitting window [nm]: 305.0793 305.2203 305.3612 305.5021 305.6430 305.7838 305.9247 306.0656 306.2064 306.3472 306.4881 306.6289 306.7697 306.9105 307.0512 307.1920 307.3328 307.4735 307.6142 307.7550 307.8957 308.0364 308.1771 308.3177 308.4584 308.5990 308.7397 308.8803 309.0209 309.1615 309.3021 309.4427 309.5833 309.7239 309.8644 310.0050 310.1455 310.2860 310.4265 310.5670 310.7075 310.8479 310.9884 311.1289 311.2693 311.4097 311.5501 311.6905 311.8309 311.9713 312.1117 312.2520 312.3924 312.5327 312.6730 312.8133 312.9536 313.0939 313.2342 313.3745 313.5147 313.6550 313.7952 313.9354 314.0756 314.2158 314.3560 314.4962 314.6363 314.7765 314.9166 315.0568 315.1969 315.3370 315.4771 315.6171 315.7572 315.8973 316.0373 316.1773 316.3174 316.4574 316.5974 316.7374 316.8773 317.0173 317.1573 317.2972 317.4371 317.5770 317.7170 317.8568 317.9967 318.1366 318.2765 318.4163 318.5561 318.6960 318.8358 318.9756 319.1154 319.2551 319.3949 319.5347 319.6744 319.8141 319.9539 320.0936 320.2333 320.3729 320.5126 320.6523 320.7919 320.9316 321.0712 321.2108 321.3504 321.4900 321.6296 321.7691 321.9087 322.0482 322.1878 322.3273 322.4668 322.6063 322.7458 322.8852 323.0247 323.1641 323.3036 323.4430 323.5824 323.7218 323.8612 324.0006 324.1399 324.2793 324.4186 324.5580 324.6973 324.8366 324.9759 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250717T110304.4Z 9329.460468 220 1 48.83 2 78.20 72.34 30.67 200.81 0.00 1 0.00 1 0 25 3.430e-01 9.509e-03 2.736e-01 5.986e-03 5.796492e-01 3.291874e-03 7.203982e-03 -6.000000e+00 2.035799e-01 232.58 -2.00 3.45 -2.00 321.31 0.00e+00 5.265316e-03 1.711417e-03 6.779254e-03 -6.000000e+00 9.640923e-03 291.23 -2.00 20.00 -2.00 320.62 0.00e+00 4.732 0.002 302.00 328.00 3 2.4017e+00 1.2098e-02 6.4537e-02 -6.0000e+00 5.1100e-01 1.7661e-04 1.6393e-02 5.1601e-02 -6.0000e+00 5.5349e-01 -6.1839e-02 1.5111e-02 2.3199e-02 -6.0000e+00 3.2877e-01 2.1835e-02 7.1133e-03 4.8795e-03 -6.0000e+00 1.3841e-01 2.3942e-04 4.1007e-03 1.8416e-04 1.3672e-04 -6.0000e+00 1.0071e-02 1.4860e-01 -1.7550e-04 12 8 8 10 0 0 95.64 22.95 0.29 0.14860 0.17941 53 12 1 5 0 921.190 27.35 20.00 22.95 32.08 7.7 1031.75 65913 -177360 900000 -176145 -47734 -40677 -82396 900000 -115245 52716 116982 900000 -86089 24607 -44063 73845 8814 46163 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-904 -1103 14 289 -1504 1254 481 1444 508 1118 442 904 -37 -813 -842 -379 650 -732 1472 -1242 4 -1543 -1953 -2424 -915 -377 -1035 244 251 1039 853 2397 816 141 -795 -842 -1667 -344 -505 10 942 531 1223 250 702 -552 263 -1198 -260 981 -501 596 -1206 -171 -1093 12 341 1765 1028 1176 460 -520 -1190 -1687 900000 SS 20250717T111405.4Z 9329.468119 223 1 48.69 2 76.12 73.88 31.47 205.75 0.00 1 0.00 1 0 25 1.385e-01 7.249e-03 8.331e-02 2.386e-03 5.060727e-01 1.273406e-03 6.018682e-03 -6.000000e+00 8.205214e-02 232.58 -2.00 3.45 -2.00 320.79 0.00e+00 2.768597e-03 5.524580e-04 4.133324e-03 -6.000000e+00 3.730087e-03 291.23 -2.00 20.00 -2.00 320.03 0.00e+00 4.071 0.001 302.00 328.00 3 1.7968e+00 4.2485e-03 5.1586e-02 -6.0000e+00 2.0550e-01 -5.2637e-02 5.4610e-03 3.5415e-02 -6.0000e+00 2.2230e-01 -5.6843e-04 4.7488e-03 1.6879e-02 -6.0000e+00 1.3259e-01 -9.7993e-04 2.3211e-03 4.1060e-03 -6.0000e+00 5.5739e-02 9.0053e-04 4.6588e-03 7.3641e-05 8.9418e-05 -6.0000e+00 4.0024e-03 1.4575e-01 -5.8221e-05 11 8 0 10 0 0 90.38 23.01 0.23 0.14575 0.18076 116 27 1 5 0 419.690 27.45 20.00 23.01 32.43 7.6 1034.02 -62590 1555 -54565 -5458 -36248 -67583 -19449 -42158 6779 -65521 7481 -60213 19477 -21587 6929 -26683 6414 -2605 804 8459 -12361 6873 -12646 7433 -10229 1446 -14728 6974 -3467 -604 5988 -4254 1372 -10831 -3251 -4650 -1004 -4093 1060 -993 1123 2356 2773 2641 581 228 -2150 706 -2911 1990 501 1877 1626 2307 281 722 -27 -2010 1778 26 3726 1101 3509 304 462 -289 -311 210 811 888 578 1052 -1777 604 -2821 -2869 -3403 -1619 -1218 -2124 -1075 -1230 -531 -334 1315 856 2407 1044 2160 -91 -267 -913 -1005 -336 -38 645 137 437 -771 -861 -2132 -1234 -920 -635 -640 -149 335 447 1175 851 892 16 -24 -863 -862 -761 -192 146 229 774 63 600 -241 256 -657 -636 -506 55 75 28 -436 -321 -95 -139 546 351 699 273 190 -317 -367 -529 900000 -662 10 -519 -33 -304 -786 -176 -481 55 -1067 75 -1337 243 -489 135 -801 151 -72 22 224 -410 199 -484 250 -424 53 -620 239 -144 -28 305 -264 82 -712 -206 -342 -87 -441 125 -120 154 305 398 387 88 35 -350 116 -532 382 99 431 365 588 69 197 -7 -551 476 8 1160 359 1199 108 171 -106 -120 83 361 424 283 501 -818 271 -1190 -1156 -1436 -760 -663 -1223 -679 -837 -382 -257 1059 726 2038 881 1716 -69 -188 -632 -734 -274 -35 674 159 526 -912 -936 -2153 -1206 -942 -694 -741 -181 434 633 1806 1395 1483 26 -38 -1264 -1235 -1117 -297 239 384 1280 101 929 -363 368 -914 -878 -746 90 134 53 -866 -669 -194 -300 1219 803 1608 623 418 -664 -798 -1164 900000 SS 20250717T112508.8Z 9329.475797 226 1 48.25 2 74.01 75.43 32.43 210.48 0.00 1 0.00 1 0 25 1.438e-01 9.207e-03 1.233e-01 5.238e-03 4.496075e-01 2.771207e-03 5.615357e-03 -6.000000e+00 8.521610e-02 232.58 -2.00 3.45 -2.00 320.42 0.00e+00 3.338042e-03 1.048176e-03 4.042427e-03 -6.000000e+00 3.872999e-03 291.23 -2.00 20.00 -2.00 319.62 0.00e+00 3.567 0.001 302.00 328.00 3 3.5846e+00 8.7617e-03 4.5740e-02 -6.0000e+00 2.1342e-01 -2.9611e-03 1.0815e-02 3.1993e-02 -6.0000e+00 2.3085e-01 -3.0492e-02 8.7113e-03 1.4947e-02 -6.0000e+00 1.3769e-01 1.0179e-02 4.3744e-03 3.5720e-03 -6.0000e+00 5.7900e-02 2.5295e-04 4.4928e-03 1.6379e-04 7.7017e-05 -6.0000e+00 4.1557e-03 1.4478e-01 -3.3898e-05 11 9 0 11 8 0 97.81 23.06 0.19 0.14478 0.17854 29 7 1 5 0 1663.520 27.45 20.01 23.06 32.85 7.6 1037.31 -61722 -60749 -72325 -52663 -37699 30669 31868 79076 4066 3907 -7973 -17883 8390 -16119 -15456 -2017 -6825 -156 -5291 -507 -6788 -11199 2695 -1175 -14033 20389 -2383 11700 -10973 11189 -8464 -403 -1011 782 -4303 -7051 -2552 803 -4382 -5398 3372 5456 1116 5477 761 2440 -3888 7165 -3957 2806 4015 -273 -718 1512 -553 -372 1325 -93 -1796 1348 3830 3162 2770 2531 119 -645 144 860 -412 655 2283 1010 -378 -1020 -2806 -1257 -6360 -2114 -1807 -1660 -45 -1426 78 -1413 1270 490 2157 1292 1750 379 -8 -1549 -680 -1272 -218 718 25 800 -891 -1779 -3022 -1323 -1237 -589 -819 268 -27 885 935 816 1143 338 -299 -1016 -332 -280 288 629 600 606 -71 183 414 799 -844 -542 -66 -585 -846 -193 -355 87 -23 -393 329 801 386 222 342 -435 -706 -224 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