File name: Pandora270s1_Warsaw-UW_20240604_L2Fit_fout2c2d20230919p1-8.txt File generation date: 20240604T223610.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Iwona Stachlewska Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 270 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora270_OF_v3d20230517.txt Instrument calibration file used: Pandora270s1_CF_v2d20230919.txt Level 1 file used: Pandora270s1_Warsaw-UW_20240604_L1_smca1c2d20230919p1-8.txt Full location name: Warsaw Observatory Station, Faculty of Physics, University of Warsaw Short location name: Warsaw-UW Country of location: Poland Location latitude [deg]: 52.2113 Location longitude [deg]: 20.9828 Location altitude [m]: 137 Local noon date: 20240604 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0393 305.1798 305.3202 305.4607 305.6012 305.7416 305.8820 306.0224 306.1629 306.3033 306.4436 306.5840 306.7244 306.8647 307.0051 307.1454 307.2857 307.4260 307.5663 307.7066 307.8469 307.9871 308.1274 308.2676 308.4078 308.5481 308.6883 308.8285 308.9686 309.1088 309.2490 309.3891 309.5293 309.6694 309.8095 309.9496 310.0897 310.2298 310.3698 310.5099 310.6499 310.7900 310.9300 311.0700 311.2100 311.3500 311.4900 311.6299 311.7699 311.9098 312.0498 312.1897 312.3296 312.4695 312.6094 312.7492 312.8891 313.0290 313.1688 313.3086 313.4484 313.5882 313.7280 313.8678 314.0076 314.1473 314.2871 314.4268 314.5666 314.7063 314.8460 314.9857 315.1253 315.2650 315.4047 315.5443 315.6839 315.8236 315.9632 316.1028 316.2424 316.3819 316.5215 316.6610 316.8006 316.9401 317.0796 317.2191 317.3586 317.4981 317.6376 317.7770 317.9165 318.0559 318.1953 318.3348 318.4742 318.6136 318.7529 318.8923 319.0317 319.1710 319.3103 319.4496 319.5890 319.7283 319.8675 320.0068 320.1461 320.2853 320.4246 320.5638 320.7030 320.8422 320.9814 321.1206 321.2598 321.3989 321.5381 321.6772 321.8163 321.9554 322.0945 322.2336 322.3727 322.5117 322.6508 322.7898 322.9289 323.0679 323.2069 323.3459 323.4849 323.6238 323.7628 323.9017 324.0407 324.1796 324.3185 324.4574 324.5963 324.7352 324.8740 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240604T083350.5Z 8921.356834 265 1 55.78 2 37.64 130.51 33.63 180.27 0.00 1 0.00 1 0 17 2.099e-02 1.061e-02 3.284e-03 1.730e-03 2.243386e-01 9.189970e-04 2.944916e-03 -6.000000e+00 1.260569e-02 232.68 -2.00 3.84 -2.00 315.86 0.00e+00 6.397307e-04 9.158233e-05 6.166452e-05 -6.000000e+00 5.349669e-04 278.62 -2.00 20.00 -2.00 315.28 0.00e+00 1.262 0.000 302.00 328.00 3 5.9487e+00 2.4006e-03 1.8115e-02 -6.0000e+00 3.1730e-02 7.1144e-02 2.6591e-03 1.2801e-02 -6.0000e+00 3.4197e-02 -1.4753e-02 1.5245e-03 6.2149e-03 -6.0000e+00 2.0244e-02 6.5024e-05 6.9308e-04 1.7439e-03 -6.0000e+00 8.5446e-03 2.9444e-04 1.7669e-04 5.1545e-05 2.2114e-05 -6.0000e+00 6.0717e-04 -6.5258e-03 1.1138e-04 12 9 8 11 8 0 99.36 25.67 0.37 -0.00653 -0.00520 17 2 1 8 0 3280.800 19.99 25.67 25.91 34.50 33.50 2.2 967.27 4160 -3434 -3912 -10970 -1504 -406 -5126 3418 -1210 -4216 3285 -1228 8308 -6016 758 1745 3955 2279 2386 -2463 1124 3088 837 1420 4179 2173 -864 -1562 -578 -4141 5750 -1323 1684 -1697 362 -2948 -3064 -3070 -542 -1519 -1238 -167 -588 -1895 473 -636 -101 605 -735 -1506 219 93 2212 1580 1315 1723 693 302 1195 854 -310 1599 1530 998 2423 616 -398 -2220 -503 -29 1129 675 251 -44 841 445 -984 -1245 -950 -1618 -987 -1294 -1333 -2024 -1105 -1696 63 6 64 1252 155 -270 311 -678 -1216 -1369 345 1630 1042 615 -454 -843 -627 -164 -1363 -758 -375 -796 285 -67 719 515 868 392 -830 93 -851 -759 -392 1529 1111 437 459 244 723 -53 -771 392 666 1046 1114 340 -728 -893 -267 669 -95 182 354 322 -585 -1070 -784 797 -779 -917 -2631 -324 -81 -1093 733 -273 -1036 749 -294 1957 -1842 245 612 1425 859 929 -1036 465 1248 348 610 1824 1000 -378 -715 -244 -1735 2234 -586 773 -767 168 -1357 -1484 -1549 -315 -963 -868 -122 -445 -1472 357 -484 -75 433 -518 -1057 155 70 1719 1295 1039 1380 569 249 963 682 -255 1358 1400 977 2379 583 -349 -1881 -426 -27 1146 682 259 -45 854 414 -833 -1051 -794 -1371 -929 -1352 -1404 -2257 -1292 -2004 77 8 84 1579 186 -318 330 -679 -1232 -1494 408 1972 1369 824 -589 -1021 -754 -194 -1625 -961 -496 -1041 385 -96 1072 747 1306 558 -1103 119 -1068 -968 -527 2031 1552 620 639 329 980 -68 -957 496 810 1346 1512 455 -1001 -1259 -392 1026 -144 282 556 503 -894 -1681 -1191 SS 20240604T083850.4Z 8921.360305 268 1 4.79 2 37.06 132.16 33.63 182.36 0.00 1 0.00 1 0 17 1.234e-02 7.785e-03 5.764e-03 3.677e-03 2.104377e-01 1.968540e-03 2.758838e-03 -6.000000e+00 7.405663e-03 232.68 -2.00 3.84 -2.00 315.20 0.00e+00 6.326948e-04 1.704087e-04 2.689282e-05 -6.000000e+00 3.143339e-04 278.62 -2.00 20.00 -2.00 314.65 0.00e+00 1.252 0.000 302.00 328.00 3 4.8485e+00 5.1053e-03 1.7414e-02 -6.0000e+00 1.8641e-02 4.1791e-02 5.6329e-03 1.1972e-02 -6.0000e+00 2.0095e-02 -1.9516e-03 3.2232e-03 5.8110e-03 -6.0000e+00 1.1896e-02 -2.0754e-03 1.4261e-03 1.6426e-03 -6.0000e+00 5.0175e-03 9.2533e-04 -3.8788e-04 1.0895e-04 2.2047e-05 -6.0000e+00 3.5704e-04 -5.3221e-03 -3.1809e-05 12 9 1 12 33 1 999.00 25.67 0.17 -0.00532 -0.00824 2 4 1 8 0 1594.640 20.00 25.67 26.29 34.75 33.50 2.2 968.44 1219 -2128 2408 -5403 -3163 -1002 -2860 -731 1286 -1490 729 -401 3294 -1429 1524 -1444 531 938 376 982 2364 2211 1307 1896 1895 679 -641 -813 -2685 -2448 3372 725 511 -973 -2 -3594 -2068 -1114 917 -428 -912 306 -1367 -227 -844 -818 -1537 -1168 -430 174 -588 1032 1605 1145 1128 -164 203 681 958 1048 -197 1159 1203 1998 1543 614 -488 -558 -855 482 597 532 -160 -180 1255 334 211 -1207 -627 -1213 -264 -1682 -1294 -1576 -1164 -1120 -212 -168 -261 677 76 590 162 231 -131 507 792 782 207 349 -480 -703 -875 -85 -576 -784 -554 -584 -303 -237 -159 597 484 114 -619 274 246 188 210 172 657 288 487 163 447 260 29 433 744 496 930 -184 -226 -446 35 302 -265 -60 -86 218 -144 -683 -785 339 -670 742 -1713 -879 -255 -760 -208 396 -499 238 -133 1050 -537 625 -621 234 423 176 471 1140 1064 639 956 932 349 -335 -406 -1359 -1186 1576 369 259 -519 -1 -1813 -1081 -657 587 -305 -684 239 -1117 -186 -693 -669 -1242 -912 -323 128 -448 819 1337 951 969 -145 182 608 840 909 -176 1024 1143 1906 1501 597 -440 -503 -785 457 596 564 -166 -191 1244 320 191 -1025 -526 -1107 -254 -1723 -1360 -1746 -1301 -1341 -256 -211 -334 840 89 657 173 240 -137 542 890 929 266 437 -605 -862 -1005 -96 -694 -973 -718 -760 -410 -324 -229 842 697 156 -812 342 309 230 272 230 916 391 674 219 594 328 37 523 920 624 1229 -244 -306 -619 48 442 -390 -90 -132 331 -213 -982 -1138 SS 20240604T102139.4Z 8921.431706 327 1 53.43 2 29.80 174.02 39.13 221.82 0.00 1 0.00 1 0 17 2.103e-02 1.123e-02 3.266e-03 1.849e-03 2.061594e-01 9.862617e-04 2.682797e-03 -6.000000e+00 1.263327e-02 232.69 -2.00 3.84 -2.00 315.60 0.00e+00 6.490412e-04 9.315363e-05 5.905548e-05 -6.000000e+00 5.360816e-04 278.63 -2.00 20.00 -2.00 315.03 0.00e+00 1.152 0.000 302.00 328.00 3 6.1573e+00 2.5676e-03 1.6551e-02 -6.0000e+00 3.1800e-02 6.5625e-02 2.8363e-03 1.1696e-02 -6.0000e+00 3.4269e-02 -1.0002e-02 1.6250e-03 5.6690e-03 -6.0000e+00 2.0287e-02 -1.2060e-03 7.3288e-04 1.5947e-03 -6.0000e+00 8.5652e-03 2.7560e-04 3.6985e-04 5.5119e-05 2.0412e-05 -6.0000e+00 6.0827e-04 -7.8094e-03 1.4238e-04 12 9 8 11 8 0 99.78 25.72 0.21 -0.00781 -0.00503 15 2 1 8 0 3561.320 20.00 25.72 28.03 34.50 33.50 2.1 975.23 5862 -2750 -4023 -9694 -2991 -171 -5124 4683 -1876 -4746 1444 -2392 9059 -4544 95 915 2980 1640 2692 -1440 1537 2943 1698 1168 4693 2243 -1062 -1041 -451 -4410 4667 -235 1960 -2293 122 -4205 -2438 -2357 -1382 -1048 -1615 349 -665 -1941 379 -436 -209 698 -1535 -1409 -718 406 2963 1629 1617 1885 563 -230 1605 693 -463 1477 1797 1053 2404 138 -270 -1834 -707 -506 1114 767 361 -211 1005 235 -896 -1313 -655 -1513 -852 -1570 -1327 -1981 -709 -1767 -187 -194 201 1405 18 113 403 -508 -1256 -1670 3 1842 1265 675 -632 -864 -276 -80 -1423 -979 -345 -789 331 -196 690 459 975 337 -741 -146 -733 -818 -446 1648 1312 970 559 420 732 -230 -907 -113 581 889 1105 278 -867 -827 -149 678 63 199 290 92 -611 -1208 -510 1259 -704 -1070 -2598 -671 -38 -1116 1112 -477 -1312 375 -644 2340 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