File name: Pandora270s1_Warsaw-UW_20250204_L2Fit_fwvt1c2d20230919p1-8.txt File generation date: 20250204T225923.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Iwona Stachlewska Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 270 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora270_OF_v3d20230517.txt Instrument calibration file used: Pandora270s1_CF_v2d20230919.txt Level 1 file used: Pandora270s1_Warsaw-UW_20250204_L1_smca1c2d20230919p1-8.txt Full location name: Warsaw Observatory Station, Faculty of Physics, University of Warsaw Short location name: Warsaw-UW Country of location: Poland Location latitude [deg]: 52.2113 Location longitude [deg]: 20.9828 Location altitude [m]: 137 Local noon date: 20250204 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 1624 1774 Nominal wavelengths inside fitting window [nm]: 492.0350 492.1554 492.2759 492.3963 492.5167 492.6371 492.7574 492.8778 492.9981 493.1184 493.2387 493.3590 493.4793 493.5995 493.7197 493.8399 493.9601 494.0803 494.2005 494.3206 494.4407 494.5609 494.6809 494.8010 494.9211 495.0411 495.1611 495.2812 495.4012 495.5211 495.6411 495.7610 495.8810 496.0009 496.1207 496.2406 496.3605 496.4803 496.6001 496.7199 496.8397 496.9595 497.0793 497.1990 497.3187 497.4384 497.5581 497.6778 497.7974 497.9171 498.0367 498.1563 498.2759 498.3955 498.5150 498.6345 498.7541 498.8736 498.9930 499.1125 499.2320 499.3514 499.4708 499.5902 499.7096 499.8290 499.9483 500.0676 500.1870 500.3062 500.4255 500.5448 500.6640 500.7833 500.9025 501.0217 501.1408 501.2600 501.3791 501.4983 501.6174 501.7365 501.8556 501.9746 502.0936 502.2127 502.3317 502.4507 502.5696 502.6886 502.8075 502.9265 503.0454 503.1642 503.2831 503.4020 503.5208 503.6396 503.7584 503.8772 503.9960 504.1147 504.2335 504.3522 504.4709 504.5895 504.7082 504.8269 504.9455 505.0641 505.1827 505.3013 505.4198 505.5384 505.6569 505.7754 505.8939 506.0124 506.1308 506.2493 506.3677 506.4861 506.6045 506.7229 506.8412 506.9595 507.0779 507.1962 507.3144 507.4327 507.5510 507.6692 507.7874 507.9056 508.0238 508.1420 508.2601 508.3782 508.4963 508.6144 508.7325 508.8506 508.9686 509.0866 509.2046 509.3226 509.4406 509.5586 509.6765 509.7944 509.9123 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250204T082154.8Z 9166.348551 117 1 21.59 2 75.48 143.31 89.80 66.32 0.00 1 0.00 1 0 15 2.809e-03 2.794e-03 3.974e-04 3.970e-04 1.996407e+03 2.134130e+01 1.632576e+02 -6.000000e+00 1.417606e+02 265.94 -2.00 20.00 -2.00 505.27 0.00e+00 7.789895e-04 1.035089e-05 4.355934e-05 -6.000000e+00 7.474410e-05 265.94 -2.00 20.00 -2.00 500.49 0.00e+00 3.018237e-01 7.735217e-03 1.577347e-02 -6.000000e+00 5.524122e-02 222.87 -2.00 3.84 -2.00 502.07 0.00e+00 3.907 0.001 489.00 513.00 1 5.2967e+00 5.8820e-04 5.7240e-03 -6.0000e+00 4.2030e-03 7.1455e-03 1.5453e-04 4.8744e-04 -6.0000e+00 1.1091e-03 5.4988e-03 -8.3516e-06 3.5616e-05 3.0153e-05 -6.0000e+00 2.5849e-04 -7.0975e-03 -1.1159e-04 12 1 1 12 1 1 58.52 25.51 1.55 -0.00710 -0.00716 42 11 1 2 0 501.990 20.00 25.51 9.25 34.50 33.75 3.3 891.24 -452 -561 -356 -53 17 373 562 576 562 366 317 276 -49 -272 -165 -264 -264 -82 150 2 91 150 97 107 265 256 383 456 -30 -331 -304 -371 -492 -29 177 -88 92 67 -4 -283 -120 -22 -35 90 211 276 278 375 224 139 -342 -397 -634 -683 -401 -270 -183 27 -54 69 65 89 223 267 278 73 -5 151 36 -340 -431 -278 -78 -32 59 -11 -170 -55 -163 -336 -357 -240 -239 -293 -22 -13 -132 -128 -49 -149 -44 -111 293 337 263 373 408 179 -165 -482 -584 -605 -466 -224 50 -59 -15 -33 -328 -357 -151 -118 -90 135 273 254 377 472 496 334 254 190 14 82 229 -42 115 268 164 274 414 -17 -12 20 -366 -343 -73 -9 -122 95 216 4 141 234 275 404 229 -125 -337 -435 -506 -432 -540 -346 -53 17 379 581 596 583 376 326 281 -49 -273 -166 -262 -265 -83 153 2 94 155 100 111 275 267 398 470 -31 -335 -303 -369 -494 -29 184 -93 96 69 -5 -290 -122 -23 -36 92 219 284 286 388 229 141 -342 -391 -622 -667 -391 -268 -184 27 -55 70 66 91 228 273 283 74 -6 150 36 -335 -418 -272 -76 -31 59 -11 -169 -53 -159 -324 -343 -233 -231 -285 -21 -13 -130 -127 -48 -148 -44 -111 292 337 263 374 402 176 -160 -462 -551 -571 -448 -218 49 -59 -15 -33 -323 -352 -148 -117 -90 136 274 257 383 481 506 338 257 189 14 82 228 -41 114 265 161 269 407 -17 -12 20 -353 -329 -70 -8 -121 95 215 4 142 234 276 407 229 -124 -333 -426 -492 SQ 20250204T091601.5Z 9166.386129 148 1 54.62 2 71.29 156.15 82.04 76.30 0.00 1 0.00 1 0 15 3.453e-03 3.435e-03 8.433e-04 8.419e-04 1.602521e+03 4.484570e+01 1.302241e+02 -6.000000e+00 1.742608e+02 265.94 -2.00 20.00 -2.00 505.26 0.00e+00 4.836324e-04 2.189924e-05 2.802934e-05 -6.000000e+00 9.187439e-05 265.94 -2.00 20.00 -2.00 500.43 0.00e+00 2.182995e-01 1.643736e-02 1.267785e-02 -6.000000e+00 6.789067e-02 222.88 -2.00 3.84 -2.00 502.03 0.00e+00 3.080 0.001 489.00 513.00 1 7.7733e+00 1.2501e-03 4.4906e-03 -6.0000e+00 5.1657e-03 1.1950e-02 3.2874e-04 3.9193e-04 -6.0000e+00 1.3626e-03 5.2429e-04 -4.3651e-04 7.5911e-05 2.3149e-05 -6.0000e+00 3.1778e-04 -7.8062e-03 -8.3977e-05 10 0 0 10 0 0 98.39 25.51 1.57 -0.00781 -0.01083 15 2 1 2 0 3640.640 20.01 25.51 10.18 34.50 33.50 3.2 894.88 -338 -514 -190 -349 -7 214 709 335 950 455 367 174 -254 122 -541 -239 -337 31 158 -129 166 161 63 -168 87 -4 250 385 306 -61 -297 -325 -288 216 29 -158 217 -77 -160 -437 -131 179 302 -253 361 206 31 825 266 315 -465 -506 -615 -495 -396 -251 -261 -177 -234 -402 44 -12 60 255 295 244 193 548 308 -624 -652 -219 240 68 -213 229 -9 133 -469 -228 -154 -285 -22 -299 -271 30 -588 49 22 -204 216 -254 359 236 131 376 348 482 -357 -479 -732 -543 -398 23 580 -92 -358 -72 -32 -325 -312 -299 133 -51 487 -5 232 209 346 481 443 293 -133 -28 405 112 -122 227 75 89 331 154 107 101 -936 -92 -306 498 -178 -214 69 144 556 160 173 951 -54 -332 -669 -460 -143 -323 -494 -187 -346 -7 223 726 350 988 471 375 181 -261 123 -543 -239 -341 32 162 -135 174 169 66 -177 92 -4 264 404 315 -61 -298 -324 -290 215 30 -163 230 -81 -166 -449 -133 182 309 -263 379 212 32 858 274 318 -459 -499 -594 -476 -387 -252 -262 -182 -241 -414 45 -12 62 263 303 248 193 538 300 -604 -642 -214 235 68 -208 224 -8 131 -456 -219 -147 -275 -22 -294 -261 29 -580 48 22 -200 213 -253 361 234 130 380 346 469 -340 -458 -691 -512 -381 22 573 -91 -354 -72 -32 -318 -307 -300 131 -51 489 -5 236 214 354 486 441 287 -129 -28 402 109 -119 221 73 86 320 153 104 96 -895 -87 -293 484 -173 -211 69 144 555 162 176 957 -55 -330 -648 -448 -138 SQ 20250204T094259.5Z 9166.404855 163 1 54.22 2 69.83 162.84 78.04 81.23 0.00 1 0.00 1 0 15 2.779e-03 2.759e-03 4.895e-04 4.889e-04 1.585595e+03 2.596885e+01 1.318782e+02 -6.000000e+00 1.402372e+02 265.94 -2.00 20.00 -2.00 505.26 0.00e+00 5.296891e-04 1.273906e-05 2.904736e-05 -6.000000e+00 7.394172e-05 265.94 -2.00 20.00 -2.00 500.44 0.00e+00 1.828531e-01 9.528138e-03 1.184996e-02 -6.000000e+00 5.465018e-02 222.88 -2.00 3.84 -2.00 502.04 0.00e+00 2.871 0.000 489.00 513.00 1 6.7813e+00 7.2449e-04 4.2012e-03 -6.0000e+00 4.1580e-03 1.1807e-02 1.9081e-04 3.7115e-04 -6.0000e+00 1.0973e-03 1.4584e-03 1.0498e-04 4.4006e-05 2.3408e-05 -6.0000e+00 2.5571e-04 -5.1585e-03 -1.2744e-04 11 1 0 11 32 0 99.37 25.51 1.64 -0.00516 -0.00443 38 4 1 2 0 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