File name: Pandora270s1_Warsaw-UW_20250603_L2Fit_fout2c2d20230919p1-8.txt File generation date: 20250603T223655.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Iwona Stachlewska Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 270 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora270_OF_v3d20230517.txt Instrument calibration file used: Pandora270s1_CF_v2d20230919.txt Level 1 file used: Pandora270s1_Warsaw-UW_20250603_L1_smca1c2d20230919p1-8.txt Full location name: Warsaw Observatory Station, Faculty of Physics, University of Warsaw Short location name: Warsaw-UW Country of location: Poland Location latitude [deg]: 52.2113 Location longitude [deg]: 20.9828 Location altitude [m]: 137 Local noon date: 20250603 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0393 305.1798 305.3202 305.4607 305.6012 305.7416 305.8820 306.0224 306.1629 306.3033 306.4436 306.5840 306.7244 306.8647 307.0051 307.1454 307.2857 307.4260 307.5663 307.7066 307.8469 307.9871 308.1274 308.2676 308.4078 308.5481 308.6883 308.8285 308.9686 309.1088 309.2490 309.3891 309.5293 309.6694 309.8095 309.9496 310.0897 310.2298 310.3698 310.5099 310.6499 310.7900 310.9300 311.0700 311.2100 311.3500 311.4900 311.6299 311.7699 311.9098 312.0498 312.1897 312.3296 312.4695 312.6094 312.7492 312.8891 313.0290 313.1688 313.3086 313.4484 313.5882 313.7280 313.8678 314.0076 314.1473 314.2871 314.4268 314.5666 314.7063 314.8460 314.9857 315.1253 315.2650 315.4047 315.5443 315.6839 315.8236 315.9632 316.1028 316.2424 316.3819 316.5215 316.6610 316.8006 316.9401 317.0796 317.2191 317.3586 317.4981 317.6376 317.7770 317.9165 318.0559 318.1953 318.3348 318.4742 318.6136 318.7529 318.8923 319.0317 319.1710 319.3103 319.4496 319.5890 319.7283 319.8675 320.0068 320.1461 320.2853 320.4246 320.5638 320.7030 320.8422 320.9814 321.1206 321.2598 321.3989 321.5381 321.6772 321.8163 321.9554 322.0945 322.2336 322.3727 322.5117 322.6508 322.7898 322.9289 323.0679 323.2069 323.3459 323.4849 323.6238 323.7628 323.9017 324.0407 324.1796 324.3185 324.4574 324.5963 324.7352 324.8740 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250603T063456.9Z 9285.274270 217 1 23.80 2 54.18 99.53 117.71 29.00 0.00 1 0.00 1 0 17 7.814e-02 2.268e-02 7.799e-03 3.190e-03 2.648659e-01 1.682271e-03 3.374724e-03 -6.000000e+00 4.697319e-02 232.51 -2.00 3.84 -2.00 316.56 0.00e+00 1.607309e-03 1.961429e-04 5.496553e-05 -6.000000e+00 1.989812e-03 278.37 -2.00 20.00 -2.00 315.95 0.00e+00 1.704 0.000 302.00 328.00 3 5.6278e+00 4.4262e-03 2.2744e-02 -6.0000e+00 1.1821e-01 1.0785e-01 4.9119e-03 1.5072e-02 -6.0000e+00 1.2734e-01 -4.5192e-02 2.8690e-03 7.2630e-03 -6.0000e+00 7.5391e-02 1.2994e-02 1.3510e-03 2.3722e-03 -6.0000e+00 3.1877e-02 2.4471e-04 2.0970e-03 9.4670e-05 2.5343e-05 -6.0000e+00 2.2592e-03 -7.3731e-03 5.7084e-04 12 9 9 12 13 1 99.97 32.74 -0.98 -0.00737 0.00838 6 2 1 8 0 3398.790 20.00 32.74 23.64 41.50 34.25 3.3 953.51 687 -18440 -7936 -24528 -10094 6899 2598 17422 -1784 -19212 12958 7953 38968 -14653 15921 5737 53859 -2760 984 -2353 6347 33 2931 5708 15322 4190 -3677 -7142 -3237 -10618 15303 -3598 3627 -5645 1879 -6252 1067 -6918 -3403 -3428 -2515 5728 -2095 -2634 2511 -2041 -1324 1128 -1774 -3228 2289 602 5808 2391 1532 1237 1155 -1338 1372 2453 -2314 3529 2267 -155 4728 -417 -1329 1029 -5307 -2800 1598 50 -868 -631 2940 969 -392 -1143 1421 -2975 288 -1780 2643 -625 167 -2748 408 -1837 -346 1755 -756 -776 2450 -78 -2963 -3270 -1491 2901 1247 733 -1607 50 -627 842 -1811 34 42 -802 975 -1493 679 482 1707 1762 -2180 -887 -706 -1879 -673 1756 2402 1204 -44 816 567 -429 -2318 111 1046 1292 655 1157 -1295 -1601 -211 379 839 873 975 536 -687 -1518 -1361 107 -3494 -1405 -4926 -1737 932 373 2347 -321 -3961 2141 1395 5480 -3659 3680 1485 10054 -856 305 -779 1966 11 939 1844 4693 1482 -1418 -2733 -1113 -3805 4818 -1338 1351 -2414 720 -2490 414 -3295 -1694 -2001 -1620 3594 -1355 -1742 1709 -1339 -923 748 -1184 -2172 1505 428 4156 1718 1153 951 902 -1073 1055 1842 -1851 2811 1977 -138 4096 -362 -1157 835 -4682 -2466 1493 50 -898 -635 2694 888 -328 -894 1082 -2583 272 -1769 2723 -654 184 -3329 508 -2282 -430 2233 -928 -873 2611 -80 -3167 -3537 -1756 3628 1610 968 -2082 63 -742 966 -2263 44 55 -1092 1366 -2134 1005 738 2550 2491 -3145 -1169 -896 -2457 -919 2502 3551 1704 -66 1168 773 -561 -3134 142 1371 1693 916 1677 -1851 -2354 -320 604 1383 1392 1577 863 -1146 -2462 -2133 SS 20250603T085537.9Z 9285.371966 296 1 17.36 2 35.35 138.16 103.42 61.86 0.00 1 0.00 1 0 17 1.046e-02 7.444e-03 1.686e-03 1.201e-03 1.833759e-01 6.457615e-04 2.426194e-03 -6.000000e+00 6.274567e-03 232.52 -2.00 3.84 -2.00 314.70 0.00e+00 7.131635e-04 5.076275e-05 3.255305e-05 -6.000000e+00 2.662316e-04 278.38 -2.00 20.00 -2.00 314.20 0.00e+00 1.225 0.000 302.00 328.00 3 4.3876e+00 1.6677e-03 1.6137e-02 -6.0000e+00 1.5789e-02 3.6858e-02 1.8369e-03 1.0507e-02 -6.0000e+00 1.7022e-02 -2.7440e-03 1.0494e-03 5.0895e-03 -6.0000e+00 1.0077e-02 -2.0771e-03 4.5587e-04 1.4840e-03 -6.0000e+00 4.2509e-03 1.6021e-03 2.5211e-04 3.5452e-05 2.0104e-05 -6.0000e+00 3.0257e-04 -2.0040e-03 1.4211e-04 12 9 1 12 37 1 99.97 32.67 -0.00 -0.00200 -0.00011 27 9 2 8 0 619.740 20.00 32.67 25.94 41.50 34.25 3.2 963.19 1044 -1485 -1281 -3777 -2652 -1654 -654 2449 1562 -1532 664 -425 -1882 -1494 1463 1511 168 51 954 742 2106 776 1345 1343 2326 1056 -209 -1377 -821 -688 2634 750 1761 -225 -1212 -3079 -1452 -2057 -472 -630 -803 -109 -1198 -967 -31 -1013 -1069 -303 -600 -1236 202 791 1339 1213 948 688 771 551 714 853 219 1362 1358 1406 1715 -134 -720 -638 -1308 9 827 282 401 82 698 -11 -516 -1297 -709 -1072 -717 -1013 -615 -1426 -1035 -1010 -476 -110 391 669 93 130 239 -196 -616 -371 121 981 841 427 -313 -389 -793 -347 -561 -383 -664 -521 -267 -69 367 514 904 634 -458 -515 -440 -441 -22 502 472 185 121 459 388 490 -155 258 711 755 599 488 -204 -362 -163 -47 5 50 241 -42 -218 -705 -812 372 -548 -481 -1379 -921 -530 -212 842 554 -590 249 -160 -773 -637 676 760 84 26 495 396 1130 419 727 751 1341 598 -120 -809 -444 -355 1424 408 1004 -135 -703 -1745 -852 -1299 -327 -482 -647 -87 -995 -812 -26 -843 -872 -249 -478 -972 161 658 1110 1052 851 629 681 489 653 772 193 1256 1287 1410 1733 -130 -668 -586 -1172 9 844 294 425 85 713 -11 -479 -1118 -631 -986 -698 -1043 -650 -1598 -1174 -1182 -566 -136 488 817 111 148 256 -205 -650 -401 137 1170 1040 537 -379 -457 -911 -394 -655 -479 -839 -663 -352 -92 512 732 1253 858 -596 -643 -528 -540 -27 667 635 252 163 595 495 616 -186 310 840 942 759 639 -273 -478 -224 -66 6 72 354 -62 -322 -1013 -1134 SS 20250603T090000.0Z 9285.374999 298 1 7.90 2 34.91 139.74 102.86 62.77 0.00 1 0.00 1 0 17 5.373e-02 2.491e-02 1.217e-02 7.199e-03 1.970219e-01 3.819240e-03 2.585620e-03 -6.000000e+00 3.221475e-02 232.52 -2.00 3.84 -2.00 315.44 0.00e+00 1.527528e-03 3.496353e-04 2.897909e-05 -6.000000e+00 1.367062e-03 278.38 -2.00 20.00 -2.00 314.90 0.00e+00 1.219 0.000 302.00 328.00 3 6.1980e+00 9.9367e-03 1.6647e-02 -6.0000e+00 8.1063e-02 8.8577e-02 1.0983e-02 1.1340e-02 -6.0000e+00 8.7413e-02 -2.6603e-02 6.2727e-03 5.4471e-03 -6.0000e+00 5.1745e-02 8.5105e-03 2.7981e-03 1.7424e-03 -6.0000e+00 2.1817e-02 2.5172e-04 -1.0624e-03 2.1337e-04 2.0041e-05 -6.0000e+00 1.5547e-03 -1.4650e-03 4.6582e-06 12 9 9 12 5 1 999.00 32.67 -1.77 -0.00146 -0.00945 1 1 1 8 0 3949.930 20.00 32.67 26.12 41.50 34.25 3.3 965.54 5092 -12763 -7026 -16725 -3828 2398 757 3239 -2635 -13527 10116 5474 24028 -9889 9734 4317 36845 118 3858 -524 5269 -1743 2096 2468 6473 3600 -3456 -2381 -1959 -7511 13368 -2385 1589 -3622 144 -4492 -2848 -5013 -3269 -5037 -3601 4055 -2582 -1905 2944 -2321 -1662 1642 -1566 -4220 1419 660 6764 3000 2245 1831 -494 -545 2281 2606 -213 2461 963 468 4059 -813 -1275 655 -5089 -1241 2103 604 1536 329 1888 -609 -2966 -999 555 -4193 -20 -2504 2511 -1635 532 -2805 1870 -2014 -114 2592 -174 -864 420 -1955 -2953 -3829 -2863 1799 1770 1373 -1966 448 -1251 1311 -2126 1582 -37 -1226 1350 -957 662 349 2853 1658 -2777 -184 32 -3255 -57 1603 3433 1053 -2 789 1066 -796 -2200 585 705 1148 2598 623 -1834 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