File name: Pandora270s1_Warsaw-UW_20250611_L2Fit_fout2c2d20230919p1-8.txt File generation date: 20250611T224157.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Iwona Stachlewska Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 270 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora270_OF_v3d20230517.txt Instrument calibration file used: Pandora270s1_CF_v2d20230919.txt Level 1 file used: Pandora270s1_Warsaw-UW_20250611_L1_smca1c2d20230919p1-8.txt Full location name: Warsaw Observatory Station, Faculty of Physics, University of Warsaw Short location name: Warsaw-UW Country of location: Poland Location latitude [deg]: 52.2113 Location longitude [deg]: 20.9828 Location altitude [m]: 137 Local noon date: 20250611 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0393 305.1798 305.3202 305.4607 305.6012 305.7416 305.8820 306.0224 306.1629 306.3033 306.4436 306.5840 306.7244 306.8647 307.0051 307.1454 307.2857 307.4260 307.5663 307.7066 307.8469 307.9871 308.1274 308.2676 308.4078 308.5481 308.6883 308.8285 308.9686 309.1088 309.2490 309.3891 309.5293 309.6694 309.8095 309.9496 310.0897 310.2298 310.3698 310.5099 310.6499 310.7900 310.9300 311.0700 311.2100 311.3500 311.4900 311.6299 311.7699 311.9098 312.0498 312.1897 312.3296 312.4695 312.6094 312.7492 312.8891 313.0290 313.1688 313.3086 313.4484 313.5882 313.7280 313.8678 314.0076 314.1473 314.2871 314.4268 314.5666 314.7063 314.8460 314.9857 315.1253 315.2650 315.4047 315.5443 315.6839 315.8236 315.9632 316.1028 316.2424 316.3819 316.5215 316.6610 316.8006 316.9401 317.0796 317.2191 317.3586 317.4981 317.6376 317.7770 317.9165 318.0559 318.1953 318.3348 318.4742 318.6136 318.7529 318.8923 319.0317 319.1710 319.3103 319.4496 319.5890 319.7283 319.8675 320.0068 320.1461 320.2853 320.4246 320.5638 320.7030 320.8422 320.9814 321.1206 321.2598 321.3989 321.5381 321.6772 321.8163 321.9554 322.0945 322.2336 322.3727 322.5117 322.6508 322.7898 322.9289 323.0679 323.2069 323.3459 323.4849 323.6238 323.7628 323.9017 324.0407 324.1796 324.3185 324.4574 324.5963 324.7352 324.8740 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250611T050948.9Z 9293.215149 230 1 54.39 2 66.83 81.69 118.66 259.40 0.00 1 0.00 1 0 17 4.325e-01 3.171e-02 1.181e-01 3.260e-03 4.439956e-01 1.723394e-03 5.809788e-03 -6.000000e+00 2.589688e-01 233.14 -2.00 3.84 -2.00 319.04 0.00e+00 5.132765e-03 3.979711e-04 2.629040e-04 -6.000000e+00 1.157747e-02 279.33 -2.00 20.00 -2.00 318.42 0.00e+00 2.522 0.000 302.00 328.00 3 5.2456e+00 4.7659e-03 3.6443e-02 -6.0000e+00 6.5242e-01 1.9582e-01 5.4377e-03 2.6475e-02 -6.0000e+00 7.0420e-01 -1.7003e-01 3.8931e-03 1.2887e-02 -6.0000e+00 4.1669e-01 7.0239e-02 2.0409e-03 5.1906e-03 -6.0000e+00 1.7532e-01 1.1959e-04 -5.8810e-03 9.6324e-05 5.2192e-05 -6.0000e+00 1.2619e-02 7.2971e-03 -7.4564e-04 12 9 8 11 36 0 100.00 32.17 0.50 0.00730 -0.03690 93 10 2 8 0 584.740 20.01 32.17 20.17 41.25 34.25 3.4 938.59 220890 -89029 -18839 11131 -4665 197885 71704 160488 97527 -96588 900000 176979 46920 -37763 14856 58895 17674 24317 35509 1692 42903 -17286 37436 46122 154419 51879 -18000 8425 6834 -26464 166662 -16920 9499 -16429 24275 -11951 14062 -11158 -3369 -3065 2695 25448 -183 -1605 15260 -8853 -2380 14095 1614 -14051 5632 7423 13868 7462 5551 4774 3620 -3823 6195 7225 -5973 11612 3427 -8125 8855 -2612 -2796 3651 -5183 -3351 5899 1716 -3164 -1715 6552 -1636 -2255 -129 6842 -5157 3719 -3361 -1793 3322 1461 -4502 -1954 -3217 -1781 2678 -2825 1215 2291 -1088 -913 -5789 -3664 3431 977 730 -1960 1934 -721 3144 -2591 -361 179 -710 2559 -2716 -158 16 3156 1995 -2996 -787 -955 -2965 -433 2499 2739 758 -1440 2086 2117 195 -3169 1278 1967 2107 2052 1808 -2265 -1688 -843 1141 904 1469 193 210 -787 -2820 -504 766 -7820 -865 367 -163 858 1119 1224 1519 -10019 900000 1406 1596 -3306 1015 2995 1489 2048 2833 197 3368 -2456 3094 3621 4270 4122 -2900 1010 799 -4382 4397 -3167 1522 -3629 3472 -2370 2266 -2635 -872 -844 783 6907 -61 -555 4502 -3356 -849 4264 556 -5793 2021 2837 5341 3260 2587 2296 1791 -2036 2925 3323 -3191 5549 1956 -5702 5491 -1768 -1796 2155 -3479 -2460 4389 1294 -2533 -1309 4686 -1150 -1446 -77 3926 -3746 2835 -2842 -1636 3055 1449 -5062 -2264 -3620 -2001 3055 -3206 1222 2111 -996 -867 -6389 -4133 4067 1304 1004 -2665 2339 -820 3609 -3050 -444 230 -968 3585 -4015 -247 26 5053 3113 -4603 -1192 -1402 -4530 -679 3747 4227 1185 -2237 3251 3147 282 -4526 1709 2739 3201 3137 2938 -3977 -3053 -1589 2084 1716 2831 380 409 -1485 -5538 -925 SS 20250611T064343.1Z 9293.280360 291 1 54.08 2 52.51 100.50 132.39 277.02 0.00 1 0.00 1 0 17 5.208e-02 1.421e-02 4.141e-03 1.549e-03 2.793855e-01 8.178398e-04 3.612986e-03 -6.000000e+00 3.136472e-02 233.15 -2.00 3.84 -2.00 316.73 0.00e+00 9.444407e-04 1.000777e-04 7.939271e-05 -6.000000e+00 1.331871e-03 279.34 -2.00 20.00 -2.00 316.10 0.00e+00 1.639 0.000 302.00 328.00 3 5.2460e+00 2.1613e-03 2.3030e-02 -6.0000e+00 7.9026e-02 7.6362e-02 2.4004e-03 1.5973e-02 -6.0000e+00 8.5099e-02 -2.3270e-02 1.4073e-03 7.7458e-03 -6.0000e+00 5.0382e-02 3.7049e-03 6.7064e-04 2.2563e-03 -6.0000e+00 2.1277e-02 3.7319e-04 1.3417e-03 4.5980e-05 2.6002e-05 -6.0000e+00 1.5065e-03 -5.4562e-03 4.2601e-04 12 9 8 11 36 0 100.00 32.15 0.21 -0.00546 0.00463 76 8 2 8 0 711.470 20.00 32.15 21.17 41.00 34.25 3.3 942.69 7254 -11712 -7862 -20415 -2350 6395 851 13213 8198 -18049 18639 7873 35126 -5061 1986 5886 -2247 2036 4626 -345 5452 -2820 2942 4979 10350 5778 -3272 -3151 518 -5274 12606 -3792 2102 -3555 1098 -4711 595 -4036 -2708 -1872 -2164 -2115 -2382 -1923 2025 -2820 -2485 894 -102 -3586 299 1189 2751 2602 1863 1236 1354 -529 1401 1429 -867 2384 1312 1854 2819 -266 -1045 188 -2233 -428 1618 734 -304 214 2036 46 -563 -876 949 -1873 281 -1530 899 -904 -898 -2091 -1072 -626 31 1246 -355 -779 1173 232 -2405 -1292 -402 1314 720 705 -679 -131 -695 206 -1198 -276 -418 -849 236 -799 150 577 1201 807 -1137 -781 -500 -963 -207 1293 1058 468 -363 865 826 307 -1093 279 776 1234 1151 1029 -966 -895 -463 327 357 338 329 202 -238 -1424 -802 899 -1953 -1312 -3719 -323 754 109 1639 1185 -3613 2610 1248 4654 -1148 437 1390 -612 553 1276 -104 1579 -886 881 1524 3153 1913 -1197 -1104 164 -1713 3558 -1361 769 -1442 412 -1799 227 -1833 -1319 -1063 -1270 -1315 -1535 -1255 1270 -1853 -1609 547 -62 -2242 186 784 1896 1894 1421 970 1079 -431 1102 1109 -699 1966 1100 1657 2558 -238 -869 148 -1842 -384 1574 715 -304 207 1960 41 -456 -713 760 -1568 259 -1491 927 -1000 -987 -2491 -1340 -763 38 1576 -429 -867 1249 235 -2534 -1459 -468 1670 938 936 -875 -166 -822 237 -1486 -363 -543 -1161 335 -1145 226 895 1827 1169 -1644 -1042 -642 -1266 -285 1876 1515 677 -519 1250 1136 402 -1471 360 1031 1643 1629 1522 -1408 -1339 -723 507 575 557 552 335 -384 -2238 -1279 SS 20250611T070532.7Z 9293.295517 306 1 4.55 2 49.25 105.42 135.55 281.65 0.00 1 0.00 1 0 17 1.155e-02 7.040e-03 3.989e-03 2.217e-03 2.526400e-01 1.183942e-03 3.337761e-03 -6.000000e+00 6.947007e-03 233.15 -2.00 3.84 -2.00 315.74 0.00e+00 6.091793e-04 1.145850e-04 3.681727e-05 -6.000000e+00 2.952716e-04 279.34 -2.00 20.00 -2.00 315.15 0.00e+00 1.529 0.000 302.00 328.00 3 3.7789e+00 3.0870e-03 2.1179e-02 -6.0000e+00 1.7503e-02 2.7198e-02 3.4122e-03 1.4504e-02 -6.0000e+00 1.8859e-02 -5.1997e-03 1.9578e-03 7.0376e-03 -6.0000e+00 1.1165e-02 -7.2162e-04 8.8455e-04 1.9719e-03 -6.0000e+00 4.7067e-03 1.9224e-03 -8.2089e-05 6.5507e-05 2.5787e-05 -6.0000e+00 3.3441e-04 -1.1265e-03 1.0382e-04 12 9 1 12 37 1 99.84 32.17 0.29 -0.00113 -0.00174 8 11 3 8 0 504.760 20.00 32.17 21.89 41.25 34.25 3.4 946.88 1895 -3270 -1874 -4351 -1745 268 -1071 1194 3111 -3330 1996 793 -1051 -2902 306 782 1373 1326 789 1085 1909 -898 835 1110 2228 337 -202 -880 -144 -1008 3058 97 1738 -182 -1516 -3680 -920 -2358 -668 -239 -808 75 -1605 -872 -83 -640 -1187 -682 -435 -819 1104 918 860 1114 616 1046 753 810 463 223 307 1652 1923 1202 1401 -132 -770 -484 -734 940 701 419 405 299 714 -466 226 -645 -661 -1138 -908 -832 -1075 -1353 -1434 -1165 -116 -104 -57 225 206 20 357 219 -184 232 -206 815 946 375 -406 -396 -1237 -592 -361 -605 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