File name: Pandora270s1_Warsaw-UW_20250711_L2Fit_fout2c2d20230919p1-8.txt File generation date: 20250711T224753.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Iwona Stachlewska Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 270 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora270_OF_v3d20230517.txt Instrument calibration file used: Pandora270s1_CF_v2d20230919.txt Level 1 file used: Pandora270s1_Warsaw-UW_20250711_L1_smca1c2d20230919p1-8.txt Full location name: Warsaw Observatory Station, Faculty of Physics, University of Warsaw Short location name: Warsaw-UW Country of location: Poland Location latitude [deg]: 52.2113 Location longitude [deg]: 20.9828 Location altitude [m]: 137 Local noon date: 20250711 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0393 305.1798 305.3202 305.4607 305.6012 305.7416 305.8820 306.0224 306.1629 306.3033 306.4436 306.5840 306.7244 306.8647 307.0051 307.1454 307.2857 307.4260 307.5663 307.7066 307.8469 307.9871 308.1274 308.2676 308.4078 308.5481 308.6883 308.8285 308.9686 309.1088 309.2490 309.3891 309.5293 309.6694 309.8095 309.9496 310.0897 310.2298 310.3698 310.5099 310.6499 310.7900 310.9300 311.0700 311.2100 311.3500 311.4900 311.6299 311.7699 311.9098 312.0498 312.1897 312.3296 312.4695 312.6094 312.7492 312.8891 313.0290 313.1688 313.3086 313.4484 313.5882 313.7280 313.8678 314.0076 314.1473 314.2871 314.4268 314.5666 314.7063 314.8460 314.9857 315.1253 315.2650 315.4047 315.5443 315.6839 315.8236 315.9632 316.1028 316.2424 316.3819 316.5215 316.6610 316.8006 316.9401 317.0796 317.2191 317.3586 317.4981 317.6376 317.7770 317.9165 318.0559 318.1953 318.3348 318.4742 318.6136 318.7529 318.8923 319.0317 319.1710 319.3103 319.4496 319.5890 319.7283 319.8675 320.0068 320.1461 320.2853 320.4246 320.5638 320.7030 320.8422 320.9814 321.1206 321.2598 321.3989 321.5381 321.6772 321.8163 321.9554 322.0945 322.2336 322.3727 322.5117 322.6508 322.7898 322.9289 323.0679 323.2069 323.3459 323.4849 323.6238 323.7628 323.9017 324.0407 324.1796 324.3185 324.4574 324.5963 324.7352 324.8740 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250711T130105.2Z 9323.542421 505 1 54.38 2 40.32 234.96 146.82 44.65 0.00 1 0.00 1 0 17 8.128e-03 5.819e-03 9.838e-04 5.575e-04 2.033466e-01 2.986216e-04 2.680936e-03 -6.000000e+00 4.909155e-03 233.88 -2.00 3.84 -2.00 315.60 0.00e+00 3.478108e-04 2.828746e-05 3.083753e-05 -6.000000e+00 2.103992e-04 282.25 -2.00 20.00 -2.00 314.96 0.00e+00 1.310 0.000 302.00 328.00 3 3.7537e+00 7.7995e-04 1.7649e-02 -6.0000e+00 1.2380e-02 2.2160e-02 8.6103e-04 1.1715e-02 -6.0000e+00 1.3316e-02 6.3120e-03 4.9326e-04 5.6716e-03 -6.0000e+00 7.8919e-03 -5.1383e-03 2.2177e-04 1.5668e-03 -6.0000e+00 3.3392e-03 2.6663e-03 9.7719e-05 1.6624e-05 2.0756e-05 -6.0000e+00 2.3516e-04 -1.6609e-02 6.9117e-05 10 0 0 10 0 0 100.00 26.04 0.51 -0.01661 -0.01587 1124 117 4 8 0 48.370 20.00 26.04 24.46 35.00 33.75 3.4 957.48 3 -1184 -1197 -2546 -2063 -3012 -370 291 1020 41 -172 -1062 410 -642 342 405 191 173 874 790 884 461 990 521 1142 763 214 -408 -215 364 1350 1236 1944 395 -1051 -2193 -1883 -1569 -408 -140 -696 -619 -1130 -943 -719 -580 -566 -578 -692 -853 335 852 1073 917 967 795 1011 607 714 470 470 1148 1423 1347 1240 28 -613 -708 -384 463 543 247 184 149 283 83 -446 -829 -753 -757 -471 -1171 -1335 -1557 -1246 -927 -640 -95 219 491 284 273 249 16 103 220 469 754 623 288 -130 -412 -825 -439 -438 -360 -618 -463 -429 24 257 473 450 111 -193 -108 -20 131 225 254 129 80 -22 239 313 329 258 301 597 606 577 321 -95 -247 -126 -93 -228 -83 67 -18 -18 -419 -603 1 -303 -316 -652 -472 -647 -79 67 260 11 -47 -294 120 -212 126 150 74 69 358 333 381 199 428 235 535 371 106 -194 -95 152 566 548 911 196 -510 -1029 -921 -866 -242 -91 -504 -474 -895 -757 -575 -460 -442 -437 -508 -616 244 655 869 728 795 667 860 520 604 393 400 1020 1355 1282 1203 26 -561 -613 -335 439 535 260 198 157 283 77 -395 -725 -648 -655 -453 -1177 -1454 -1683 -1420 -1068 -781 -121 282 620 339 317 263 16 106 244 538 899 804 380 -165 -492 -977 -510 -540 -450 -812 -602 -581 35 363 686 642 158 -254 -138 -25 162 294 338 181 114 -30 323 426 424 316 376 718 773 776 425 -129 -342 -182 -135 -345 -129 106 -29 -28 -622 -917 SS 20250711T131910.0Z 9323.554977 516 1 2.47 2 42.66 240.21 144.84 50.66 0.00 1 0.00 1 0 25 9.302e-03 6.895e-03 4.411e-03 2.944e-03 2.103073e-01 1.584473e-03 2.798363e-03 -6.000000e+00 5.615969e-03 233.88 -2.00 3.84 -2.00 315.03 0.00e+00 4.037665e-04 1.334613e-04 2.311892e-05 -6.000000e+00 2.407688e-04 282.25 -2.00 20.00 -2.00 314.45 0.00e+00 1.358 0.000 302.00 328.00 3 3.8205e+00 4.1121e-03 1.8281e-02 -6.0000e+00 1.4162e-02 2.5758e-02 4.5307e-03 1.2133e-02 -6.0000e+00 1.5235e-02 6.4469e-03 2.5871e-03 5.8788e-03 -6.0000e+00 9.0296e-03 -5.2015e-03 1.1372e-03 1.6254e-03 -6.0000e+00 3.8182e-03 2.3448e-03 -4.7337e-04 8.6959e-05 2.2551e-05 -6.0000e+00 2.6921e-04 -1.3931e-02 1.2773e-05 12 9 1 12 1 1 96.59 26.04 0.31 -0.01393 -0.01749 3 9 1 8 0 616.360 20.00 26.04 25.50 35.00 33.75 3.4 961.09 822 -2051 -1369 -3028 -2707 -881 35 698 1599 9 255 -1077 -214 692 901 833 1531 -262 1028 -5 883 -401 1041 1017 2237 1293 -553 -1017 -631 -244 1273 1388 1623 1036 -1046 -2516 -2560 -1285 -598 367 -1295 -401 -886 -1382 -858 -574 -329 -607 -1043 -748 296 550 1073 1159 990 598 1037 193 373 490 -53 674 1758 1293 1840 638 -424 -963 -642 769 750 263 -15 -161 589 104 -514 -812 -1454 -436 -295 -864 -1036 -1838 -1482 -1247 -488 120 108 380 431 907 711 522 384 -193 868 705 307 367 -309 -689 -725 -1100 -141 -843 -598 -497 -111 23 95 354 288 224 66 -2 209 7 41 279 181 131 -31 160 132 112 226 566 320 872 833 48 6 -397 131 372 -113 -436 -100 -8 43 -483 -654 241 -681 -466 -1004 -804 -257 10 208 525 3 91 -387 -76 275 377 383 691 -124 496 -2 450 -206 532 510 1160 701 -308 -545 -331 -122 636 734 862 577 -574 -1340 -1427 -760 -394 256 -977 -317 -696 -1108 -683 -454 -266 -478 -799 -563 226 443 871 985 840 518 910 172 326 423 -47 621 1658 1257 1814 604 -386 -867 -582 726 757 274 -16 -169 603 102 -473 -718 -1274 -392 -284 -893 -1118 -2034 -1671 -1456 -582 148 136 471 519 1029 760 539 396 -207 981 853 391 463 -389 -837 -849 -1274 -166 -1040 -771 -650 -146 31 134 499 401 304 88 -3 260 9 53 374 248 182 -42 213 172 142 281 678 392 1095 1070 64 8 -541 181 526 -167 -644 -150 -12 65 -702 -949 SS 20250711T134339.2Z 9323.571981 528 1 1.33 2 46.02 246.76 141.89 58.05 0.00 1 0.00 1 0 25 7.920e-03 5.952e-03 2.245e-03 1.488e-03 2.243543e-01 8.002738e-04 2.967377e-03 -6.000000e+00 4.783448e-03 233.88 -2.00 3.84 -2.00 315.10 0.00e+00 4.318233e-04 6.848469e-05 3.762325e-05 -6.000000e+00 2.050141e-04 282.25 -2.00 20.00 -2.00 314.51 0.00e+00 1.438 0.000 302.00 328.00 3 1.9883e+00 2.0773e-03 1.9406e-02 -6.0000e+00 1.2063e-02 1.7136e-02 2.2891e-03 1.2910e-02 -6.0000e+00 1.2975e-02 3.0089e-03 1.3078e-03 6.2517e-03 -6.0000e+00 7.6898e-03 -3.0458e-03 5.7563e-04 1.7411e-03 -6.0000e+00 3.2538e-03 1.3259e-02 -8.0365e-05 4.3880e-05 2.3834e-05 -6.0000e+00 2.2914e-04 -1.6828e-02 6.0506e-05 12 1 1 12 1 1 46.56 26.06 0.31 -0.01683 -0.01743 13 59 1 8 0 94.970 20.00 26.06 25.57 35.00 33.75 3.3 960.31 -510 -709 -1033 -1073 -3155 -2150 -902 538 697 458 -1222 -1257 -220 355 563 693 283 253 565 707 997 440 784 736 466 1246 221 -415 393 64 841 1670 1685 1111 -1476 -1875 -2168 -1491 122 11 -701 -962 -1022 -825 -484 -246 -360 -719 -577 -632 480 735 793 913 612 878 801 297 225 483 575 847 1478 1289 1043 220 -618 -851 -379 212 605 203 51 296 157 75 -285 -666 -862 -637 -569 -810 -1440 -1549 -1576 -974 -601 -130 220 328 482 552 14 302 454 503 658 521 605 356 76 -432 -988 -368 -236 -316 -680 -591 -403 -121 182 392 245 203 102 -187 -125 226 86 221 123 36 7 3 490 568 79 520 289 641 505 638 -175 -213 68 -64 -368 -64 125 -2 -291 -345 -676 -157 -227 -345 -344 -988 -620 -262 169 228 160 -414 -427 -80 136 231 314 130 119 275 339 487 216 387 377 240 662 120 -217 198 31 412 864 891 617 -815 -994 -1206 -895 79 8 -519 -731 -802 -657 -384 -194 -280 -564 -440 -475 366 574 655 767 519 758 704 264 197 417 504 756 1372 1244 1004 208 -575 -752 -337 200 598 209 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