File name: Pandora270s1_Warsaw-UW_20250719_L2Fit_fout2c2d20230919p1-8.txt File generation date: 20250719T224558.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Iwona Stachlewska Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 270 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora270_OF_v3d20230517.txt Instrument calibration file used: Pandora270s1_CF_v2d20230919.txt Level 1 file used: Pandora270s1_Warsaw-UW_20250719_L1_smca1c2d20230919p1-8.txt Full location name: Warsaw Observatory Station, Faculty of Physics, University of Warsaw Short location name: Warsaw-UW Country of location: Poland Location latitude [deg]: 52.2113 Location longitude [deg]: 20.9828 Location altitude [m]: 137 Local noon date: 20250719 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0393 305.1798 305.3202 305.4607 305.6012 305.7416 305.8820 306.0224 306.1629 306.3033 306.4436 306.5840 306.7244 306.8647 307.0051 307.1454 307.2857 307.4260 307.5663 307.7066 307.8469 307.9871 308.1274 308.2676 308.4078 308.5481 308.6883 308.8285 308.9686 309.1088 309.2490 309.3891 309.5293 309.6694 309.8095 309.9496 310.0897 310.2298 310.3698 310.5099 310.6499 310.7900 310.9300 311.0700 311.2100 311.3500 311.4900 311.6299 311.7699 311.9098 312.0498 312.1897 312.3296 312.4695 312.6094 312.7492 312.8891 313.0290 313.1688 313.3086 313.4484 313.5882 313.7280 313.8678 314.0076 314.1473 314.2871 314.4268 314.5666 314.7063 314.8460 314.9857 315.1253 315.2650 315.4047 315.5443 315.6839 315.8236 315.9632 316.1028 316.2424 316.3819 316.5215 316.6610 316.8006 316.9401 317.0796 317.2191 317.3586 317.4981 317.6376 317.7770 317.9165 318.0559 318.1953 318.3348 318.4742 318.6136 318.7529 318.8923 319.0317 319.1710 319.3103 319.4496 319.5890 319.7283 319.8675 320.0068 320.1461 320.2853 320.4246 320.5638 320.7030 320.8422 320.9814 321.1206 321.2598 321.3989 321.5381 321.6772 321.8163 321.9554 322.0945 322.2336 322.3727 322.5117 322.6508 322.7898 322.9289 323.0679 323.2069 323.3459 323.4849 323.6238 323.7628 323.9017 324.0407 324.1796 324.3185 324.4574 324.5963 324.7352 324.8740 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250719T111317.9Z 9331.467568 436 1 50.79 2 32.03 193.69 71.34 278.87 0.00 1 0.00 1 0 17 5.673e-02 2.743e-02 8.832e-03 4.377e-03 2.274200e-01 2.335074e-03 2.916545e-03 -6.000000e+00 3.427206e-02 233.78 -2.00 3.84 -2.00 316.13 0.00e+00 -2.308677e-04 2.448401e-04 1.916706e-04 -6.000000e+00 1.470894e-03 282.66 -2.00 20.00 -2.00 315.46 0.00e+00 1.179 0.000 302.00 328.00 3 7.2454e+00 6.1160e-03 1.7667e-02 -6.0000e+00 8.6396e-02 1.4461e-01 6.7751e-03 1.2828e-02 -6.0000e+00 9.2903e-02 -5.9087e-02 3.8937e-03 6.2008e-03 -6.0000e+00 5.5081e-02 2.0757e-02 1.7809e-03 1.7615e-03 -6.0000e+00 2.3340e-02 8.5249e-05 -4.0279e-04 1.3019e-04 2.1318e-05 -6.0000e+00 1.6411e-03 -2.0639e-02 1.3444e-04 12 8 8 10 0 0 99.84 26.04 -0.29 -0.02064 -0.02367 13 1 1 8 0 3906.480 20.00 26.04 27.97 35.00 33.75 3.4 972.56 7625 -15725 -2244 -19581 -2703 4878 10639 8070 -6383 -15207 -2899 2328 26091 -15989 7331 11725 18716 1899 -1743 -4771 858 9749 9230 2451 9361 3410 -844 -3478 -2714 -8625 19048 -4047 7859 -4093 2831 -7757 -3180 -10267 -1915 -1831 265 4879 -635 -1247 1379 -2430 -75 2740 70 -6178 1279 0 6359 3558 222 2251 2426 -1317 2627 2683 -4514 2843 2544 -1364 4985 1256 -3648 628 -3724 -3888 2654 484 -2789 -1592 4716 1232 -416 -3609 1617 -7188 1915 -4474 865 751 2321 -2052 206 -261 520 1791 -128 -2127 1302 -707 -3648 -4616 -3581 4447 2234 1298 -2448 1113 1415 2561 -3738 -1461 20 -1120 1367 -1772 951 805 3697 1352 -2950 -2062 -1483 -2856 -228 3151 3367 1790 595 1199 1835 -1546 -2834 923 1190 1630 1602 325 -3074 -2249 -918 2366 134 1351 602 39 -686 -2635 54 1435 -3734 -528 -5248 -548 843 1753 1485 -1501 -4160 -704 533 5000 -5200 2115 3553 5552 682 -668 -1932 335 3462 3297 970 3616 1447 -377 -1523 -1089 -3475 5870 -1658 3039 -1861 1162 -3360 -1361 -5307 -1072 -1092 173 3218 -455 -910 975 -1768 -52 1798 46 -4209 825 0 4343 2618 175 1772 1934 -1093 2064 2071 -3774 2309 2223 -1321 4639 1156 -3228 502 -3119 -3559 2526 502 -3055 -1691 4458 1103 -340 -2785 1275 -6033 1639 -4517 897 821 2633 -2386 248 -330 665 2224 -153 -2592 1394 -716 -3779 -5151 -4350 5505 2809 1688 -3183 1420 1671 2919 -4782 -1797 26 -1504 1866 -2620 1442 1263 5569 1975 -4147 -2644 -1966 -3878 -291 4157 4661 2548 843 1636 2366 -2129 -3751 1132 1481 2141 2224 436 -4346 -3214 -1349 3551 215 2184 997 65 -1112 -4203 81 SS 20250719T114447.7Z 9331.489441 452 1 52.01 2 33.71 206.92 75.83 284.64 0.00 1 0.00 1 0 17 2.069e-02 1.174e-02 3.463e-03 2.021e-03 2.016713e-01 1.079075e-03 2.632214e-03 -6.000000e+00 1.249527e-02 233.78 -2.00 3.84 -2.00 315.49 0.00e+00 1.000839e-04 1.008440e-04 7.411940e-05 -6.000000e+00 5.364794e-04 282.66 -2.00 20.00 -2.00 314.86 0.00e+00 1.201 0.000 302.00 328.00 3 6.1670e+00 2.8122e-03 1.6772e-02 -6.0000e+00 3.1498e-02 7.6531e-02 3.1059e-03 1.1509e-02 -6.0000e+00 3.3876e-02 -1.6133e-02 1.7757e-03 5.5726e-03 -6.0000e+00 2.0084e-02 3.4573e-03 7.9719e-04 1.5243e-03 -6.0000e+00 8.5062e-03 2.6233e-04 5.3059e-05 5.9810e-05 2.0010e-05 -6.0000e+00 5.9856e-04 -1.7594e-02 1.2841e-04 12 9 9 12 1 1 99.98 26.08 0.28 -0.01759 -0.01720 12 1 2 8 0 4000.000 20.00 26.08 29.26 35.00 33.75 3.3 976.94 3074 -5736 -693 -8156 -4800 3230 2105 169 -2358 -4493 -1259 -1426 7452 -5638 1658 5123 5261 -320 -612 -1613 1432 3375 3049 1278 3291 1012 -377 -980 -1548 -3228 5533 -373 3843 -1168 -925 -3874 -2697 -4110 -1525 -1365 -473 1121 -724 -1155 -252 -1199 -506 -233 -1057 -2280 540 819 2844 1974 506 1574 1323 54 1569 1376 -1208 1854 2137 527 2294 713 -1290 -1174 -1173 -1223 1125 639 -413 -598 1578 416 -500 -2494 -556 -2281 -638 -2051 -729 -670 -174 -1057 26 -222 348 1110 341 -513 758 -643 -1293 -1636 -591 1773 1073 278 -581 -469 9 540 -1765 -513 -446 -855 43 -961 1087 793 1549 751 -1151 -688 -864 -1105 171 1502 947 621 270 623 398 -96 -745 641 658 892 1223 281 -839 -908 -363 640 -330 300 493 232 -515 -1206 -496 711 -1587 -188 -2275 -1160 733 490 40 -630 -1303 -354 -399 2030 -1950 596 1948 2091 -138 -272 -742 652 1503 1366 604 1592 475 -181 -492 -724 -1456 2308 -174 1821 -605 -461 -1896 -1358 -2172 -926 -969 -343 844 -571 -927 -200 -952 -392 -173 -768 -1645 387 616 2212 1622 437 1368 1170 49 1369 1186 -1082 1689 1935 515 2248 673 -1136 -1047 -1052 -1115 1111 676 -451 -642 1573 383 -450 -2099 -450 -2016 -619 -2069 -785 -758 -193 -1269 33 -274 436 1358 423 -587 833 -664 -1338 -1813 -665 2147 1327 354 -765 -575 10 601 -2126 -655 -559 -1124 58 -1382 1610 1141 2178 1068 -1534 -896 -1078 -1400 225 1967 1312 875 376 838 544 -125 -926 756 792 1132 1630 368 -1131 -1247 -517 954 -487 450 753 354 -770 -1864 -737 SS 20250719T120610.5Z 9331.504288 465 1 7.36 2 35.41 215.22 78.81 288.53 0.00 1 0.00 1 0 17 8.131e-03 6.278e-03 1.816e-03 1.307e-03 1.866298e-01 7.060941e-04 2.472939e-03 -6.000000e+00 4.908998e-03 233.77 -2.00 3.84 -2.00 314.66 0.00e+00 4.007437e-04 5.570148e-05 1.920706e-05 -6.000000e+00 2.108234e-04 282.66 -2.00 20.00 -2.00 314.10 0.00e+00 1.226 0.000 302.00 328.00 3 3.7062e+00 1.8274e-03 1.6350e-02 -6.0000e+00 1.2374e-02 2.4133e-02 2.0078e-03 1.0735e-02 -6.0000e+00 1.3310e-02 4.3775e-03 1.1479e-03 5.1971e-03 -6.0000e+00 7.8911e-03 -4.1387e-03 4.9982e-04 1.4425e-03 -6.0000e+00 3.3411e-03 3.1387e-03 3.8950e-05 3.8559e-05 2.0300e-05 -6.0000e+00 2.3522e-04 -1.7260e-02 5.7560e-05 12 1 1 12 1 1 99.92 26.12 0.24 -0.01726 -0.01697 18 15 1 8 0 387.330 20.00 26.12 30.71 35.00 33.75 3.3 983.57 15 -981 -372 -2033 -2412 -1784 -520 1073 1283 188 -414 -956 -64 -415 222 474 580 586 741 348 1027 792 1174 817 854 466 238 61 -913 226 1175 1512 1540 863 -1369 -2720 -2439 -1664 -271 -16 -740 -809 -1112 -831 -660 -847 -827 -471 -439 -585 300 607 1177 1149 837 687 900 825 528 518 533 1257 1380 1273 1113 216 -431 -642 -506 482 413 204 211 392 31 -89 -125 -855 -1163 -675 -516 -1225 -1486 -1565 -1156 -788 -608 -207 118 526 418 337 190 -6 -74 170 432 590 752 310 -99 -585 -784 -568 -260 -346 -669 -591 -338 -40 387 494 355 202 -17 -179 26 8 363 398 223 137 41 256 265 401 95 418 350 745 612 333 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