File name: Pandora270s1_Warsaw-UW_20250818_L2Fit_fout2c2d20230919p1-8.txt File generation date: 20250818T224405.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Iwona Stachlewska Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 270 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora270_OF_v3d20230517.txt Instrument calibration file used: Pandora270s1_CF_v2d20230919.txt Level 1 file used: Pandora270s1_Warsaw-UW_20250818_L1_smca1c2d20230919p1-8.txt Full location name: Warsaw Observatory Station, Faculty of Physics, University of Warsaw Short location name: Warsaw-UW Country of location: Poland Location latitude [deg]: 52.2113 Location longitude [deg]: 20.9828 Location altitude [m]: 137 Local noon date: 20250818 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0393 305.1798 305.3202 305.4607 305.6012 305.7416 305.8820 306.0224 306.1629 306.3033 306.4436 306.5840 306.7244 306.8647 307.0051 307.1454 307.2857 307.4260 307.5663 307.7066 307.8469 307.9871 308.1274 308.2676 308.4078 308.5481 308.6883 308.8285 308.9686 309.1088 309.2490 309.3891 309.5293 309.6694 309.8095 309.9496 310.0897 310.2298 310.3698 310.5099 310.6499 310.7900 310.9300 311.0700 311.2100 311.3500 311.4900 311.6299 311.7699 311.9098 312.0498 312.1897 312.3296 312.4695 312.6094 312.7492 312.8891 313.0290 313.1688 313.3086 313.4484 313.5882 313.7280 313.8678 314.0076 314.1473 314.2871 314.4268 314.5666 314.7063 314.8460 314.9857 315.1253 315.2650 315.4047 315.5443 315.6839 315.8236 315.9632 316.1028 316.2424 316.3819 316.5215 316.6610 316.8006 316.9401 317.0796 317.2191 317.3586 317.4981 317.6376 317.7770 317.9165 318.0559 318.1953 318.3348 318.4742 318.6136 318.7529 318.8923 319.0317 319.1710 319.3103 319.4496 319.5890 319.7283 319.8675 320.0068 320.1461 320.2853 320.4246 320.5638 320.7030 320.8422 320.9814 321.1206 321.2598 321.3989 321.5381 321.6772 321.8163 321.9554 322.0945 322.2336 322.3727 322.5117 322.6508 322.7898 322.9289 323.0679 323.2069 323.3459 323.4849 323.6238 323.7628 323.9017 324.0407 324.1796 324.3185 324.4574 324.5963 324.7352 324.8740 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250818T052116.8Z 9361.223111 230 1 3.40 2 73.45 90.01 26.06 153.35 0.00 1 0.00 1 0 25 1.770e-01 1.304e-02 1.457e-01 7.852e-03 4.701271e-01 4.160855e-03 6.017164e-03 -6.000000e+00 1.061608e-01 232.17 -2.00 3.84 -2.00 318.98 0.00e+00 -7.308630e-04 9.789932e-04 5.286490e-04 -6.000000e+00 4.584300e-03 282.47 -2.00 20.00 -2.00 318.30 0.00e+00 3.454 0.001 302.00 328.00 3 3.4366e+00 1.1534e-02 4.3830e-02 -6.0000e+00 2.6653e-01 4.0362e-02 1.3280e-02 2.7473e-02 -6.0000e+00 2.8713e-01 -3.3834e-02 9.8966e-03 1.3345e-02 -6.0000e+00 1.7044e-01 9.2449e-03 5.2153e-03 3.7520e-03 -6.0000e+00 7.2324e-02 3.2329e-04 -1.5167e-04 2.2975e-04 4.2124e-05 -6.0000e+00 5.1197e-03 -1.2713e-02 -8.2878e-06 12 9 9 12 1 1 999.00 25.96 0.39 -0.01271 -0.01385 2 5 3 8 0 1132.280 20.00 25.96 22.21 34.75 33.75 3.6 945.95 58435 -36914 -35005 -79342 -19431 29054 121469 28363 11615 -51638 -11742 28853 50007 -58607 13983 21305 16317 -10436 1146 791 -2619 4648 12537 -4658 2728 17949 11494 -10888 460 -1929 33176 -10709 15045 -4913 -4336 -4003 -5022 -1134 -4459 -9820 -854 3045 -777 -3177 5576 -5199 445 2698 -2281 5165 2623 3641 72 5073 -822 2762 3589 1297 871 1531 -745 2661 5344 1219 2386 1130 -1355 -2832 -1905 -1859 5520 1036 -135 -1091 1148 928 -677 -2965 -1946 -1883 -2368 -1373 -2543 -279 -744 -2898 -156 383 103 1341 -98 205 135 305 -193 -1474 800 1449 585 -334 -4 -354 -137 -881 -1042 -171 -1662 -402 -423 -28 439 837 871 572 -987 -1015 432 532 25 982 707 321 -357 -84 454 378 133 1059 35 296 773 55 -385 -846 -166 563 403 -127 -85 -555 -460 -462 208 582 -1102 -1099 -3827 -476 423 930 500 276 -2531 -405 707 1149 -4802 664 1093 975 -879 92 67 -239 399 1027 -489 288 1732 1215 -1401 50 -217 2871 -1632 1993 -858 -744 -668 -904 -207 -1018 -2844 -258 956 -266 -1141 1847 -1772 157 933 -840 1823 932 1406 31 2263 -414 1396 1857 694 461 791 -399 1464 2912 762 1554 732 -859 -1801 -1261 -1282 3961 831 -112 -883 851 627 -455 -1940 -1304 -1318 -1919 -1166 -2412 -276 -738 -3148 -175 419 114 1444 -107 207 135 297 -185 -1587 899 1828 774 -459 -6 -435 -163 -1027 -1280 -211 -2184 -551 -585 -41 674 1357 1425 908 -1498 -1523 621 779 38 1522 1133 512 -558 -126 686 547 184 1512 50 444 1256 91 -668 -1467 -302 1033 770 -249 -170 -1096 -870 -870 373 SS 20250818T072216.0Z 9361.307130 305 1 23.44 2 55.54 116.15 27.09 213.28 0.00 1 0.00 1 0 17 2.905e-02 1.186e-02 7.534e-03 3.128e-03 2.534915e-01 1.656315e-03 3.305179e-03 -6.000000e+00 1.744035e-02 232.16 -2.00 3.84 -2.00 316.57 0.00e+00 -5.170633e-05 1.957515e-04 1.994377e-04 -6.000000e+00 7.526335e-04 282.46 -2.00 20.00 -2.00 315.88 0.00e+00 1.762 0.000 302.00 328.00 3 5.5938e+00 4.3586e-03 2.2753e-02 -6.0000e+00 4.3788e-02 6.8492e-02 4.8404e-03 1.4454e-02 -6.0000e+00 4.7155e-02 -1.5867e-02 2.8244e-03 7.0016e-03 -6.0000e+00 2.7992e-02 3.9907e-03 1.3328e-03 1.9359e-03 -6.0000e+00 1.1891e-02 2.4876e-04 4.2861e-04 9.3491e-05 2.4284e-05 -6.0000e+00 8.4010e-04 -1.5051e-02 1.9358e-04 12 9 9 12 1 1 99.99 25.99 0.16 -0.01505 -0.01183 8 2 1 8 0 2604.300 20.00 25.99 24.46 34.75 33.75 3.5 955.64 8046 -9504 -2779 -13628 -4675 828 5689 3469 -2495 -6173 -3306 774 13023 -9535 2225 3321 6991 1110 1894 -2315 905 2706 2205 944 5374 4874 -179 -3082 -783 -3664 5177 -1871 5177 -2151 862 -3086 -2833 -4731 -1362 -2453 -1985 1072 6 -1242 57 -2258 337 760 -696 -2679 1229 306 3337 2315 601 1638 1814 96 2019 970 -1422 1702 2888 1262 2409 329 -1795 -1413 -1500 -81 1150 973 -529 4 1275 435 -1330 -2781 -1194 -1990 45 -1409 -437 -1181 -530 -1589 -447 -757 788 918 -50 -403 813 -167 -1566 -1305 -256 2210 919 431 -1087 0 -1013 121 -1782 -690 40 -847 201 -896 436 606 941 681 -702 -625 37 -691 188 1058 905 1163 260 734 1061 -234 -706 346 970 634 831 257 -962 -780 -763 185 -41 387 451 293 -115 -1629 -315 1109 -1731 -491 -2582 -730 114 765 525 -446 -1224 -643 146 2348 -2437 573 853 1832 319 561 -738 286 840 694 314 1802 1708 -67 -1134 -262 -1210 1605 -666 1843 -864 326 -1161 -1113 -2151 -710 -1395 -1258 699 4 -870 39 -1587 227 498 -451 -1756 798 214 2395 1632 448 1237 1393 75 1532 734 -1115 1361 2463 1172 2266 301 -1549 -1156 -1248 -73 1057 956 -538 4 1180 400 -1118 -2194 -919 -1675 41 -1366 -456 -1307 -576 -1871 -552 -978 1020 1167 -61 -449 875 -170 -1624 -1453 -292 2717 1164 561 -1381 0 -1187 137 -2186 -898 51 -1137 279 -1329 636 912 1397 1021 -986 -811 49 -932 248 1485 1334 1724 382 1039 1426 -323 -930 436 1248 872 1134 368 -1425 -1181 -1138 288 -67 642 761 493 -188 -2609 -482 SS 20250818T074011.8Z 9361.319581 316 1 40.64 2 53.12 120.63 28.69 220.73 0.00 1 0.00 1 0 17 8.502e-03 5.855e-03 9.868e-04 5.904e-04 2.298298e-01 3.146917e-04 3.041587e-03 -6.000000e+00 5.101531e-03 232.15 -2.00 3.84 -2.00 315.49 0.00e+00 4.197854e-04 2.928196e-05 3.153100e-05 -6.000000e+00 2.202695e-04 282.46 -2.00 20.00 -2.00 314.87 0.00e+00 1.662 0.000 302.00 328.00 3 3.3733e+00 8.1675e-04 2.1133e-02 -6.0000e+00 1.2808e-02 2.2504e-02 9.0332e-04 1.3156e-02 -6.0000e+00 1.3796e-02 2.6380e-03 5.1720e-04 6.3901e-03 -6.0000e+00 8.1896e-03 -3.4420e-03 2.3141e-04 1.7850e-03 -6.0000e+00 3.4764e-03 2.6699e-03 1.0670e-04 1.7468e-05 2.3942e-05 -6.0000e+00 2.4593e-04 -1.3372e-02 6.4667e-05 12 1 1 12 1 1 99.98 25.98 0.30 -0.01337 -0.01257 136 19 1 8 0 296.620 19.99 25.98 24.78 34.75 33.75 3.5 957.24 -136 -1425 -913 -2896 -3503 -2491 -261 354 810 -878 -978 -1305 673 -672 359 728 787 247 814 921 934 802 1145 539 982 890 295 -313 -234 -166 1621 1176 1797 294 -1151 -2087 -1637 -1424 -205 -342 -717 -601 -956 -877 -574 -565 -535 -509 -675 -707 278 747 1189 1093 772 907 849 602 657 530 364 1071 1558 1323 1101 92 -577 -734 -311 225 578 256 91 -99 254 13 -464 -815 -765 -772 -709 -968 -1390 -1505 -1276 -998 -592 -152 207 449 330 363 350 104 295 223 518 735 456 186 -190 -474 -826 -519 -422 -470 -623 -547 -303 43 338 471 487 182 -135 2 -59 185 169 247 -7 178 -8 221 398 327 271 462 608 712 526 280 -73 -140 -105 -106 -225 -32 -63 -105 -149 -468 -559 -34 -395 -260 -807 -885 -582 -61 91 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