File name: Pandora140s1_WashingtonDC_20220127_L2Fit_fout2c14d20220101p1-8.txt File generation date: 20241218T135430.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Luke Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 140 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora140_OF_v3d20200721.txt Instrument calibration file used: Pandora140s1_CF_v14d20220101.txt Level 1 file used: Pandora140s1_WashingtonDC_20220127_L1_smca1c14d20220101p1-8.txt Full location name: McMillan Reservoir Short location name: WashingtonDC Country of location: United States Location latitude [deg]: 38.9218 Location longitude [deg]: -77.0124 Location altitude [m]: 58 Local noon date: 20220127 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 10 "Based on session 8 "Modif only on SO2 (WashingtonDC)""" First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0439 305.1847 305.3255 305.4663 305.6071 305.7478 305.8885 306.0293 306.1700 306.3107 306.4514 306.5921 306.7328 306.8734 307.0141 307.1547 307.2954 307.4360 307.5766 307.7172 307.8578 307.9983 308.1389 308.2794 308.4200 308.5605 308.7010 308.8415 308.9820 309.1225 309.2630 309.4034 309.5439 309.6843 309.8247 309.9652 310.1056 310.2459 310.3863 310.5267 310.6670 310.8074 310.9477 311.0881 311.2284 311.3687 311.5089 311.6492 311.7895 311.9297 312.0700 312.2102 312.3504 312.4906 312.6308 312.7710 312.9112 313.0514 313.1915 313.3316 313.4718 313.6119 313.7520 313.8921 314.0322 314.1722 314.3123 314.4523 314.5924 314.7324 314.8724 315.0124 315.1524 315.2924 315.4324 315.5723 315.7123 315.8522 315.9921 316.1320 316.2719 316.4118 316.5517 316.6915 316.8314 316.9712 317.1111 317.2509 317.3907 317.5305 317.6703 317.8100 317.9498 318.0895 318.2293 318.3690 318.5087 318.6484 318.7881 318.9278 319.0675 319.2071 319.3468 319.4864 319.6260 319.7656 319.9052 320.0448 320.1844 320.3239 320.4635 320.6030 320.7426 320.8821 321.0216 321.1611 321.3006 321.4400 321.5795 321.7189 321.8584 321.9978 322.1372 322.2766 322.4160 322.5554 322.6947 322.8341 322.9734 323.1128 323.2521 323.3914 323.5307 323.6700 323.8093 323.9485 324.0878 324.2270 324.3662 324.5054 324.6446 324.7838 324.9230 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220127T125101.2Z 8062.535431 189 1 51.00 2 85.12 118.40 60.97 181.61 0.00 1 0.00 1 0 33 7.423e-01 1.294e-01 5.054e-01 1.132e-01 1.008313e+00 6.365338e-02 1.179166e-02 -6.000000e+00 4.204325e-01 224.34 -2.00 3.47 -2.00 320.00 0.00e+00 -2.489198e-02 1.039365e-02 4.298484e-03 -6.000000e+00 1.876302e-02 276.68 -2.00 20.00 -2.00 319.02 0.00e+00 10.012 0.018 302.00 328.00 3 4.5469e-01 1.7231e-01 1.1941e-01 -6.0000e+00 1.0392e+00 2.6402e+00 2.0016e-01 8.6505e-02 -6.0000e+00 1.1342e+00 -2.3035e+00 1.1431e-01 2.4114e-02 -6.0000e+00 6.7256e-01 7.3866e-01 6.2193e-02 2.3881e-02 -6.0000e+00 2.8975e-01 3.9901e-06 -1.2914e-03 2.8092e-03 2.3917e-04 -6.0000e+00 2.0035e-02 1.1180e-02 0.0000e+00 12 8 8 10 0 0 29.43 18.40 1.92 0.01118 0.00148 13 2 1 5 0 3922.340 26.51 20.00 18.40 1.09 20.2 1027.59 900000 91073 900000 65621 165385 -47667 900000 -40421 5044 432897 -16215 181410 -22200 34096 11544 900000 23629 36769 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-9320 13721 5432 4560 4033 10306 19407 8253 15352 7504 10798 14573 12188 -9371 11703 900000 -1495 7853 3354 46012 8743 5105 5701 11052 11115 -5724 9090 6699 -4278 7332 -19441 -3764 5253 268 2657 10411 -17033 -7225 -16651 10620 2394 16760 12179 18965 20664 275 -21568 -14021 5811 -559 -12465 -14784 11621 -5689 -13632 -9772 -304 16265 10384 -3949 -10253 -9550 5560 -6456 5570 -10287 22939 -4994 15480 17092 16843 6777 -14603 10785 -19716 11259 -17836 5877 5064 20002 -10730 9710 -261 -21426 8279 1709 22592 -3176 5686 1513 -27487 13034 790 9162 -203 -4234 -13791 -3040 14781 579 SS 20220127T130213.4Z 8062.543210 192 1 50.74 2 83.22 120.27 61.11 184.50 0.00 1 0.00 1 0 25 6.296e-01 4.739e-02 4.275e-01 1.946e-02 1.040515e+00 1.083647e-02 1.485371e-02 -6.000000e+00 3.530837e-01 224.34 -2.00 3.47 -2.00 322.30 0.00e+00 -7.002342e-02 5.507386e-03 9.886665e-03 -6.000000e+00 1.539927e-02 276.68 -2.00 20.00 -2.00 321.83 0.00e+00 7.738 0.008 302.00 328.00 3 1.1957e+00 4.1381e-02 1.5861e-01 -6.0000e+00 8.7238e-01 1.2598e+00 5.3242e-02 2.1336e-01 -6.0000e+00 9.5028e-01 -1.7412e+00 4.4290e-02 3.2801e-02 -6.0000e+00 5.6554e-01 6.5130e-01 2.1643e-02 6.0360e-02 -6.0000e+00 2.4156e-01 3.1751e-05 -4.5990e-04 5.0020e-04 6.2647e-04 -6.0000e+00 1.6696e-02 9.5494e-03 0.0000e+00 12 8 8 10 0 0 5.21 18.40 0.60 0.00955 0.00609 66 12 1 5 0 768.620 26.51 20.00 18.40 1.82 20.3 1034.50 51842 82105 27133 18144 -93340 -18972 -67835 -50866 188116 192052 59416 72360 43962 38489 -30845 21731 -9671 62688 86367 6425 186744 -33198 -864 20766 185267 101313 158028 116326 125335 23881 -23204 93817 -24496 154810 17463 52425 -34410 41600 184803 58220 145159 70507 180240 125836 145093 15097 22656 26894 83337 66496 21821 63427 13961 109318 48263 98382 114516 127503 -95142 55555 55550 15027 32939 9229 41932 68890 8654 63399 22915 35719 25249 34831 25564 19493 16799 38651 12738 -9579 11101 2189 2569 -5449 12231 5048 10976 10302 17408 8380 5152 8612 1572 5523 3696 3053 1471 6047 6266 -2685 -3658 -7042 -8529 -7267 -4909 -2505 -2416 3995 -425 -1965 -3812 850 -2439 1707 643 2729 2826 1609 389 -1324 -2095 -2727 975 825 1217 3190 807 2588 -682 499 -2061 -51 -69 -955 -2687 -749 -269 893 2066 1268 625 -190 47 -337 -2069 984 1558 515 344 -3220 -360 -2691 -2632 3569 3644 2152 2247 1592 1261 -1862 750 -434 1298 1639 211 3543 -1546 -36 1039 3515 3845 3598 3090 2378 906 -1241 1780 -1479 2937 729 1492 -2374 1894 3506 3816 5233 5108 4446 4536 3579 1068 1462 1582 2846 2902 1698 3731 1373 5185 4412 6907 7605 7500 -38812 5060 4427 1607 3500 1258 4340 5882 1254 6375 3597 5792 5096 6729 5335 4001 3129 5500 1956 -1851 1915 483 669 -1823 3924 1889 4165 4176 6786 3599 2231 3402 618 2010 1396 1264 713 3254 3870 -2084 -3162 -6353 -7370 -5590 -3302 -1625 -1692 2784 -327 -1668 -3709 922 -3193 2197 883 4052 4089 2275 555 -1989 -3317 -4450 1486 1186 1669 4182 1052 3232 -855 654 -3246 -92 -142 -2203 -6270 -1862 -726 2535 5916 3695 1814 -522 129 -853 -5047 SS 20220127T131250.8Z 8062.550588 195 1 50.48 2 81.45 122.08 61.34 187.23 0.00 1 0.00 1 0 25 6.339e-01 1.723e-02 2.866e-01 5.920e-03 8.604044e-01 3.324515e-03 9.218313e-03 -6.000000e+00 3.554659e-01 224.34 -2.00 3.47 -2.00 322.12 0.00e+00 5.024932e-03 1.862648e-03 1.561812e-03 -6.000000e+00 1.550371e-02 276.68 -2.00 20.00 -2.00 321.69 0.00e+00 6.343 0.004 302.00 328.00 3 9.6755e-01 1.2538e-02 7.8712e-02 -6.0000e+00 8.7827e-01 5.1529e-01 1.8188e-02 5.0598e-02 -6.0000e+00 9.5670e-01 -7.5833e-01 1.9060e-02 2.6372e-02 -6.0000e+00 5.6936e-01 3.1364e-01 8.7812e-03 9.8041e-03 -6.0000e+00 2.4319e-01 1.5864e-04 -1.2581e-03 1.6289e-04 1.2474e-04 -6.0000e+00 1.6809e-02 9.7456e-03 0.0000e+00 12 8 8 10 0 0 29.65 18.40 0.33 0.00975 0.00029 172 33 1 5 0 293.420 26.51 20.00 18.40 3.06 20.3 1043.92 -195443 -103221 -173583 -154247 141801 -268918 -81198 -190751 -75987 -206276 -170207 -142179 -150503 -40406 -117785 137752 -101582 60014 -62191 45686 -37507 -50276 -26227 -81145 10094 -60212 162398 -95064 -23202 -6647 -54050 39895 -7078 44968 -14706 76193 -43274 31031 -16761 7589 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