File name: Pandora140s1_WashingtonDC_20220210_L2Fit_fout2c14d20220101p1-8.txt File generation date: 20241218T140946.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Luke Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 140 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora140_OF_v3d20200721.txt Instrument calibration file used: Pandora140s1_CF_v14d20220101.txt Level 1 file used: Pandora140s1_WashingtonDC_20220210_L1_smca1c14d20220101p1-8.txt Full location name: McMillan Reservoir Short location name: WashingtonDC Country of location: United States Location latitude [deg]: 38.9218 Location longitude [deg]: -77.0124 Location altitude [m]: 58 Local noon date: 20220210 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 10 "Based on session 8 "Modif only on SO2 (WashingtonDC)""" First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0439 305.1847 305.3255 305.4663 305.6071 305.7478 305.8885 306.0293 306.1700 306.3107 306.4514 306.5921 306.7328 306.8734 307.0141 307.1547 307.2954 307.4360 307.5766 307.7172 307.8578 307.9983 308.1389 308.2794 308.4200 308.5605 308.7010 308.8415 308.9820 309.1225 309.2630 309.4034 309.5439 309.6843 309.8247 309.9652 310.1056 310.2459 310.3863 310.5267 310.6670 310.8074 310.9477 311.0881 311.2284 311.3687 311.5089 311.6492 311.7895 311.9297 312.0700 312.2102 312.3504 312.4906 312.6308 312.7710 312.9112 313.0514 313.1915 313.3316 313.4718 313.6119 313.7520 313.8921 314.0322 314.1722 314.3123 314.4523 314.5924 314.7324 314.8724 315.0124 315.1524 315.2924 315.4324 315.5723 315.7123 315.8522 315.9921 316.1320 316.2719 316.4118 316.5517 316.6915 316.8314 316.9712 317.1111 317.2509 317.3907 317.5305 317.6703 317.8100 317.9498 318.0895 318.2293 318.3690 318.5087 318.6484 318.7881 318.9278 319.0675 319.2071 319.3468 319.4864 319.6260 319.7656 319.9052 320.0448 320.1844 320.3239 320.4635 320.6030 320.7426 320.8821 321.0216 321.1611 321.3006 321.4400 321.5795 321.7189 321.8584 321.9978 322.1372 322.2766 322.4160 322.5554 322.6947 322.8341 322.9734 323.1128 323.2521 323.3914 323.5307 323.6700 323.8093 323.9485 324.0878 324.2270 324.3662 324.5054 324.6446 324.7838 324.9230 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220210T123645.1Z 8076.525522 135 1 51.04 2 85.06 112.79 118.22 1.55 0.00 1 0.00 1 0 25 7.060e-01 9.451e-02 4.836e-01 5.985e-02 1.139473e+00 3.507385e-02 1.763244e-02 -6.000000e+00 4.020617e-01 224.82 -2.00 3.47 -2.00 321.89 0.00e+00 -7.216962e-02 9.278711e-03 5.012157e-03 -6.000000e+00 1.780688e-02 276.61 -2.00 20.00 -2.00 321.18 0.00e+00 9.927 0.017 302.00 328.00 3 -5.5596e-02 1.0960e-01 1.4888e-01 -6.0000e+00 9.9730e-01 2.3605e+00 1.2939e-01 1.7460e-01 -6.0000e+00 1.0889e+00 -2.2322e+00 7.8839e-02 2.7887e-02 -6.0000e+00 6.4860e-01 6.6936e-01 4.2808e-02 5.7780e-02 -6.0000e+00 2.7844e-01 8.3397e-06 -3.6192e-03 1.4448e-03 7.5944e-04 -6.0000e+00 1.8951e-02 7.5400e-03 0.0000e+00 12 8 8 10 0 0 60.45 18.40 0.95 0.00754 -0.01966 34 6 1 5 0 1500.880 26.51 19.99 18.40 11.65 21.6 995.12 900000 900000 8918 -92883 -67640 -27648 187832 15496 266650 29455 97369 39559 900000 122311 122061 24789 900000 900000 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4911 5025 13842 7096 8712 9270 10430 10173 -71663 9926 1230 1867 6068 7283 2013 1075 7916 -8597 -1612 3633 11493 9988 9837 7441 -555 4867 -484 -1312 -8202 2693 3212 -8586 878 2372 8232 3927 15922 2826 7921 5122 6710 -1185 9628 74 12500 5572 3779 5928 6066 8032 1462 -2693 2654 -1323 -3183 1560 5426 447 1214 -807 -4936 4548 1586 7791 1641 9717 2718 -12811 -3556 2529 -2448 432 -6180 -5339 10578 -636 2024 -3611 -10886 133 -19264 -4743 -8373 -2306 -128 5097 3332 8225 3870 -151 -3793 -2925 11000 SS 20220210T124746.6Z 8076.533179 138 1 50.45 2 83.10 114.61 118.09 4.30 0.00 1 0.00 1 0 25 3.855e-01 2.163e-02 2.921e-01 1.084e-02 9.646625e-01 6.191688e-03 1.035738e-02 -6.000000e+00 2.184177e-01 224.82 -2.00 3.47 -2.00 322.37 0.00e+00 -1.952929e-03 3.512486e-03 4.531313e-03 -6.000000e+00 9.847600e-03 276.61 -2.00 20.00 -2.00 321.95 0.00e+00 7.625 0.008 302.00 328.00 3 3.9651e-01 2.4165e-02 9.4627e-02 -6.0000e+00 5.3900e-01 1.0718e+00 3.2212e-02 6.0906e-02 -6.0000e+00 5.8724e-01 -1.5196e+00 2.8701e-02 3.1114e-02 -6.0000e+00 3.4857e-01 6.2027e-01 1.3575e-02 9.3595e-03 -6.0000e+00 1.4822e-01 7.3165e-05 -1.4200e-03 2.9127e-04 1.5271e-04 -6.0000e+00 1.0227e-02 7.3977e-03 0.0000e+00 12 8 8 10 0 0 17.75 18.40 0.35 0.00740 -0.00327 127 24 1 5 0 397.170 26.51 20.00 18.40 12.29 21.7 1000.85 -141380 23749 -99267 62776 -86325 900000 -124151 -21586 -84878 -112668 -50049 -165646 -62641 -73016 1700 -32026 -29811 30873 107778 21204 26216 13506 -42738 -13479 35698 900000 9784 -25939 -11781 1668 24904 -18717 21385 37932 42140 -23338 7678 6770 17426 1801 2796 81893 38630 55505 29054 98878 52996 24672 30234 21716 41611 51636 66027 43079 75455 41542 40191 43886 16957 28953 -136 37143 16154 30001 34226 30178 20719 14067 16110 9345 20979 16820 12219 17635 14778 29 -3250 -1315 1322 1456 1818 885 2215 5862 -449 1104 2097 -1959 4182 -2630 2580 -6932 1281 -3083 -4491 -650 -2705 -2648 -4212 -2884 -4017 -2680 -329 -2458 -2245 -1877 -880 -1546 -2423 -2420 -613 -1084 324 -88 -468 -1040 -1610 74 -1271 1619 281 3028 1691 1314 3629 928 2129 -595 682 560 1201 1886 283 -98 -246 226 -32 459 -286 370 -702 -358 -2408 -5978 251 -2973 664 -1825 900000 -3460 -228 -1795 -3248 -770 -8026 -1445 -2316 31 -954 -945 564 1139 428 479 260 -1438 -363 618 900000 216 -748 -272 35 503 -702 617 984 972 -964 243 247 687 99 169 2361 1745 2080 1368 2509 1935 1233 1511 1273 2239 2829 3426 3064 4133 3314 3322 3416 1613 2282 -14 2856 1754 3287 3914 3596 2519 1933 2398 1721 3807 3304 2454 3091 2369 5 -510 -210 236 318 476 274 763 2076 -180 462 905 -901 1801 -1168 1014 -2834 478 -1284 -2204 -368 -1720 -1988 -3614 -2498 -3332 -1966 -225 -1659 -1616 -1429 -703 -1252 -2230 -2597 -752 -1484 457 -124 -647 -1400 -2197 104 -1911 2445 420 4149 2245 1699 4438 1232 2723 -824 1009 978 2372 4082 670 -251 -679 658 -96 1371 -858 1046 -1844 -863 -5580 SS 20220210T125823.1Z 8076.540545 141 1 50.25 2 81.23 116.40 117.88 6.93 0.00 1 0.00 1 0 17 6.414e-01 1.240e-02 1.713e-01 3.661e-03 8.396762e-01 2.044564e-03 9.078076e-03 -6.000000e+00 3.604482e-01 224.82 -2.00 3.47 -2.00 322.03 0.00e+00 8.935304e-03 1.125037e-03 1.709405e-03 -6.000000e+00 1.568196e-02 276.61 -2.00 20.00 -2.00 321.58 0.00e+00 6.204 0.004 302.00 328.00 3 3.4070e-01 7.5894e-03 7.8083e-02 -6.0000e+00 8.9158e-01 3.8874e-01 1.1239e-02 5.3762e-02 -6.0000e+00 9.7075e-01 -5.3417e-01 1.2220e-02 2.5908e-02 -6.0000e+00 5.7750e-01 2.1732e-01 5.6297e-03 1.3037e-02 -6.0000e+00 2.4650e-01 3.4178e-04 -1.0147e-03 1.0044e-04 1.4722e-04 -6.0000e+00 1.7008e-02 7.1687e-03 0.0000e+00 12 8 8 10 0 0 2.50 18.40 0.26 0.00717 -0.00046 306 58 1 5 0 164.190 26.51 20.00 18.40 13.00 21.7 1006.50 -153213 -233592 -88186 -239873 -201896 -250104 -186106 -179055 -185700 -189444 -185715 -108038 -186386 -77127 -151026 -81286 -124781 -14632 -16493 -68893 -34748 -95772 -57054 -92103 -7847 -50802 4109 -46990 -40509 -28596 -46797 13454 -18561 1692 -20419 14186 -12824 -8317 8586 8250 21658 -4171 20929 4681 15903 13793 19129 21581 1015 16177 4566 16099 13022 22335 15270 13234 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