File name: Pandora140s1_WashingtonDC_20220707_L2Fit_fwvt1c14d20220101p1-8.txt File generation date: 20241218T172649.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c14p1-8 Local principal investigator: Luke Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 140 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora140_OF_v3d20200721.txt Instrument calibration file used: Pandora140s1_CF_v14d20220101.txt Level 1 file used: Pandora140s1_WashingtonDC_20220707_L1_smca1c14d20220101p1-8.txt Full location name: McMillan Reservoir Short location name: WashingtonDC Country of location: United States Location latitude [deg]: 38.9218 Location longitude [deg]: -77.0124 Location altitude [m]: 58 Local noon date: 20220707 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 10 "Based on session 8 "Modif only on SO2 (WashingtonDC)""" First and last pixel inside fitting window: 1637 1786 Nominal wavelengths inside fitting window [nm]: 492.0699 492.1908 492.3117 492.4326 492.5535 492.6743 492.7952 492.9160 493.0368 493.1576 493.2784 493.3991 493.5199 493.6406 493.7613 493.8820 494.0027 494.1233 494.2440 494.3646 494.4852 494.6058 494.7264 494.8469 494.9675 495.0880 495.2085 495.3290 495.4495 495.5699 495.6904 495.8108 495.9312 496.0516 496.1720 496.2923 496.4127 496.5330 496.6533 496.7736 496.8939 497.0141 497.1344 497.2546 497.3748 497.4950 497.6152 497.7353 497.8555 497.9756 498.0957 498.2158 498.3359 498.4559 498.5759 498.6960 498.8160 498.9360 499.0559 499.1759 499.2958 499.4157 499.5356 499.6555 499.7754 499.8953 500.0151 500.1349 500.2547 500.3745 500.4943 500.6140 500.7338 500.8535 500.9732 501.0929 501.2125 501.3322 501.4518 501.5714 501.6910 501.8106 501.9302 502.0497 502.1693 502.2888 502.4083 502.5278 502.6472 502.7667 502.8861 503.0055 503.1249 503.2443 503.3637 503.4830 503.6023 503.7216 503.8409 503.9602 504.0795 504.1987 504.3180 504.4372 504.5564 504.6755 504.7947 504.9138 505.0330 505.1521 505.2712 505.3902 505.5093 505.6283 505.7474 505.8664 505.9854 506.1043 506.2233 506.3422 506.4611 506.5801 506.6989 506.8178 506.9367 507.0555 507.1743 507.2931 507.4119 507.5307 507.6494 507.7682 507.8869 508.0056 508.1243 508.2429 508.3616 508.4802 508.5988 508.7174 508.8360 508.9546 509.0731 509.1916 509.3102 509.4287 509.5471 509.6656 509.7840 509.9025 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20220707T140006.4Z 8223.583408 188 1 51.49 2 43.99 97.30 133.37 55.88 0.00 1 0.00 1 0 15 3.037e-03 3.001e-03 9.520e-04 9.490e-04 5.107010e+03 6.200140e+01 3.530125e+02 -6.000000e+00 1.717867e+02 289.65 -2.00 20.00 -2.00 505.26 0.00e+00 7.142919e-04 2.634072e-05 4.380614e-05 -6.000000e+00 8.635768e-05 289.65 -2.00 20.00 -2.00 500.37 0.00e+00 1.317379e-01 1.884251e-02 3.175086e-02 -6.000000e+00 6.030964e-02 232.73 -2.00 3.47 -2.00 501.97 0.00e+00 1.388 0.000 489.00 513.00 1 7.6780e+00 1.4410e-03 3.5119e-03 -6.0000e+00 4.6259e-03 3.8414e-03 3.7564e-04 7.7049e-04 -6.0000e+00 1.2100e-03 7.2458e-04 9.0045e-04 9.0060e-05 3.9163e-05 -6.0000e+00 2.9909e-04 8.0507e-03 -8.8505e-05 11 1 0 11 8 0 99.08 18.47 0.97 0.00805 0.01430 17 3 1 4 0 3028.170 26.73 20.00 18.47 30.07 25.5 999.80 -854 -447 -376 77 112 314 552 551 369 319 109 -193 -276 -458 -179 -251 -56 -159 297 120 160 123 82 247 230 401 296 125 -157 -367 -251 -452 -65 304 399 379 156 -134 -171 -50 -273 -8 -247 262 -25 257 293 261 264 -279 -551 -830 -581 -636 -225 228 162 587 -143 229 -62 76 -98 228 53 182 319 -253 -258 -91 34 -129 -179 17 235 300 -109 -262 -588 -295 -270 -268 -240 -209 -67 -236 -290 -30 -159 127 1 145 253 354 304 123 207 138 -358 -512 -721 -462 -419 -234 194 -110 -27 -292 -43 -292 -173 27 58 251 300 439 356 340 287 302 281 86 38 207 339 213 587 26 238 105 28 -111 -122 -321 -434 7 38 -3 218 267 134 30 269 159 144 202 -195 -350 -643 -607 -841 -446 -387 76 114 325 580 583 390 333 113 -197 -277 -454 -176 -249 -56 -164 311 127 171 131 88 265 247 430 316 132 -161 -366 -246 -447 -66 315 425 406 166 -141 -178 -52 -282 -9 -260 277 -27 275 312 274 272 -281 -541 -796 -550 -608 -220 229 167 607 -149 237 -65 79 -102 238 55 185 320 -251 -252 -88 32 -125 -174 16 233 294 -105 -250 -556 -277 -254 -255 -230 -202 -66 -233 -287 -30 -157 126 1 146 257 359 304 120 198 129 -327 -461 -650 -423 -396 -230 195 -111 -27 -290 -42 -288 -173 28 59 242 291 428 350 334 281 291 284 86 38 205 337 213 584 26 236 104 28 -108 -116 -304 -411 7 37 -3 206 255 129 29 262 155 141 196 -186 -326 -630 -591 SQ 20220707T141819.7Z 8223.596061 203 1 49.37 2 40.49 100.78 130.54 60.31 0.00 1 0.00 1 0 22 3.003e-03 2.964e-03 9.968e-04 9.926e-04 4.903858e+03 6.439037e+01 3.287892e+02 -6.000000e+00 1.698679e+02 289.65 -2.00 20.00 -2.00 505.21 0.00e+00 6.319616e-04 2.750234e-05 3.976771e-05 -6.000000e+00 8.539285e-05 289.65 -2.00 20.00 -2.00 500.28 0.00e+00 1.081363e-01 1.975683e-02 3.210434e-02 -6.000000e+00 5.963454e-02 232.73 -2.00 3.47 -2.00 501.87 0.00e+00 1.314 0.000 489.00 513.00 1 7.7702e+00 1.5125e-03 3.4295e-03 -6.0000e+00 4.5742e-03 4.6927e-03 3.9481e-04 7.5592e-04 -6.0000e+00 1.1965e-03 6.7001e-04 7.2201e-04 9.4289e-05 3.7070e-05 -6.0000e+00 2.9574e-04 8.0031e-03 -8.6233e-05 10 0 0 10 0 0 98.71 18.48 0.94 0.00800 0.01301 15 3 1 4 0 3290.790 26.73 20.01 18.48 30.52 25.5 1002.44 -819 -53 -325 108 -4 156 414 613 313 149 177 -307 -327 -415 -339 -468 -6 -16 166 61 2 490 148 234 154 491 -18 261 71 -234 -72 -292 -159 215 315 111 124 -168 -438 -62 28 -258 -56 147 219 308 433 104 115 -329 -455 -548 -583 -668 -110 56 316 365 -6 141 227 209 -88 316 198 235 215 56 -138 -174 -213 -381 -60 77 -46 318 -247 -315 -381 -183 -265 -581 -226 -310 -146 -326 -227 -11 -110 -144 -77 184 210 409 261 -61 373 -136 -418 -414 -757 -440 -188 145 226 -33 143 -234 -188 -233 -299 55 196 350 379 305 500 575 268 282 294 -82 -55 330 113 10 609 -35 314 146 439 -159 -12 -306 -373 -43 -311 -135 -93 155 167 -84 188 281 302 311 -260 -352 -627 -519 -814 -53 -315 108 -4 163 440 655 334 157 184 -317 -332 -415 -338 -469 -6 -17 176 66 2 526 159 253 167 530 -20 277 74 -235 -71 -290 -161 224 338 120 133 -179 -462 -64 30 -271 -60 157 236 332 464 110 119 -335 -449 -529 -557 -644 -108 57 327 381 -6 147 236 219 -93 331 206 241 217 56 -136 -169 -205 -370 -59 77 -46 315 -242 -303 -362 -173 -251 -559 -219 -302 -144 -324 -226 -11 -109 -143 -77 186 215 418 264 -61 360 -128 -385 -376 -688 -406 -179 143 229 -31 145 -234 -186 -232 -283 53 190 341 371 299 494 569 264 274 281 -77 -52 309 107 10 572 -33 295 137 407 -155 -12 -292 -356 -41 -288 -128 -88 149 162 -82 184 276 296 302 -250 -330 -580 -477 SQ 20220707T142305.3Z 8223.599367 206 1 51.45 2 39.58 101.74 129.78 61.42 0.00 1 0.00 1 0 22 3.126e-03 3.095e-03 1.125e-03 1.119e-03 4.929626e+03 7.273574e+01 3.371022e+02 -6.000000e+00 1.768502e+02 289.65 -2.00 20.00 -2.00 505.20 0.00e+00 7.152804e-04 3.115121e-05 4.428643e-05 -6.000000e+00 8.890252e-05 289.65 -2.00 20.00 -2.00 500.22 0.00e+00 1.253457e-01 2.246978e-02 3.168312e-02 -6.000000e+00 6.208284e-02 232.73 -2.00 3.47 -2.00 501.83 0.00e+00 1.296 0.000 489.00 513.00 1 7.9295e+00 1.7270e-03 3.4250e-03 -6.0000e+00 4.7620e-03 4.5460e-03 4.4749e-04 7.5718e-04 -6.0000e+00 1.2455e-03 5.7134e-04 5.5178e-04 1.0578e-04 3.9176e-05 -6.0000e+00 3.0790e-04 5.5149e-03 -6.6802e-05 10 0 0 10 0 0 92.08 18.48 0.93 0.00551 0.00934 13 2 1 4 0 3956.860 26.73 19.99 18.48 30.60 25.5 1003.22 -692 -608 -364 94 264 396 381 496 414 332 -8 -115 -291 -189 -215 -304 -254 -89 384 58 173 141 203 146 78 221 -78 339 -96 -77 -417 -148 -90 449 353 178 311 -285 -171 -385 13 -334 -154 314 146 488 433 255 131 -427 -669 -501 -768 -597 -117 -115 418 166 69 -53 276 328 170 230 105 231 123 -144 -314 -241 -285 -68 -135 62 113 362 -100 -524 -194 -382 -423 -434 -578 -204 -68 -441 -151 -14 -266 143 63 23 369 372 451 37 473 -254 -345 -545 -587 -454 -492 114 -119 65 -273 -41 -332 -54 -206 -33 156 360 371 396 648 384 438 492 212 178 -341 449 51 135 343 280 171 139 353 -221 -69 -198 -144 98 -106 -194 152 122 40 110 57 31 176 -37 -47 -185 -446 -603 -648 -578 -356 95 273 418 408 536 447 354 -8 -119 -297 -191 -216 -307 -260 -94 411 63 188 153 221 159 85 242 -85 364 -101 -78 -418 -148 -92 472 382 195 337 -306 -182 -406 14 -355 -165 339 148 496 469 273 138 -439 -669 -488 -742 -581 -117 -118 436 176 73 -56 290 346 169 228 110 240 125 -146 -314 -237 -279 -66 -134 63 113 362 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