File name: Pandora140s1_WashingtonDC_20221216_L2Fit_fout2c14d20220101p1-8.txt File generation date: 20241218T193203.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Luke Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 140 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora140_OF_v3d20200721.txt Instrument calibration file used: Pandora140s1_CF_v14d20220101.txt Level 1 file used: Pandora140s1_WashingtonDC_20221216_L1_smca1c14d20220101p1-8.txt Full location name: McMillan Reservoir Short location name: WashingtonDC Country of location: United States Location latitude [deg]: 38.9218 Location longitude [deg]: -77.0124 Location altitude [m]: 58 Local noon date: 20221216 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 10 "Based on session 8 "Modif only on SO2 (WashingtonDC)""" First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0439 305.1847 305.3255 305.4663 305.6071 305.7478 305.8885 306.0293 306.1700 306.3107 306.4514 306.5921 306.7328 306.8734 307.0141 307.1547 307.2954 307.4360 307.5766 307.7172 307.8578 307.9983 308.1389 308.2794 308.4200 308.5605 308.7010 308.8415 308.9820 309.1225 309.2630 309.4034 309.5439 309.6843 309.8247 309.9652 310.1056 310.2459 310.3863 310.5267 310.6670 310.8074 310.9477 311.0881 311.2284 311.3687 311.5089 311.6492 311.7895 311.9297 312.0700 312.2102 312.3504 312.4906 312.6308 312.7710 312.9112 313.0514 313.1915 313.3316 313.4718 313.6119 313.7520 313.8921 314.0322 314.1722 314.3123 314.4523 314.5924 314.7324 314.8724 315.0124 315.1524 315.2924 315.4324 315.5723 315.7123 315.8522 315.9921 316.1320 316.2719 316.4118 316.5517 316.6915 316.8314 316.9712 317.1111 317.2509 317.3907 317.5305 317.6703 317.8100 317.9498 318.0895 318.2293 318.3690 318.5087 318.6484 318.7881 318.9278 319.0675 319.2071 319.3468 319.4864 319.6260 319.7656 319.9052 320.0448 320.1844 320.3239 320.4635 320.6030 320.7426 320.8821 321.0216 321.1611 321.3006 321.4400 321.5795 321.7189 321.8584 321.9978 322.1372 322.2766 322.4160 322.5554 322.6947 322.8341 322.9734 323.1128 323.2521 323.3914 323.5307 323.6700 323.8093 323.9485 324.0878 324.2270 324.3662 324.5054 324.6446 324.7838 324.9230 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221216T131346.2Z 8385.551229 317 1 50.42 2 82.23 128.60 43.28 224.07 0.00 1 0.00 1 0 17 5.847e-01 3.466e-02 3.905e-01 2.538e-02 7.975968e-01 1.471078e-02 8.818004e-03 -6.000000e+00 3.400303e-01 223.16 -2.00 3.47 -2.00 321.82 0.00e+00 -1.380205e-03 7.624680e-03 2.629234e-03 -6.000000e+00 1.707384e-02 278.50 -2.00 20.00 -2.00 321.34 0.00e+00 6.890 0.006 302.00 328.00 3 2.4548e+00 5.2769e-02 8.1297e-02 -6.0000e+00 8.4491e-01 7.6984e-01 6.7892e-02 4.6934e-02 -6.0000e+00 9.2863e-01 -9.7683e-01 5.8984e-02 2.2509e-02 -6.0000e+00 5.4424e-01 4.0982e-01 2.8299e-02 7.1228e-03 -6.0000e+00 2.3063e-01 2.0833e-05 -1.9045e-03 7.3845e-04 9.6151e-05 -6.0000e+00 1.6331e-02 5.5062e-03 0.0000e+00 12 9 8 11 8 0 99.97 18.30 0.32 0.00551 -0.00881 43 8 1 5 0 1172.340 26.41 20.00 18.30 10.53 25.7 1001.50 -174748 900000 -30739 900000 93153 900000 900000 -187578 900000 900000 -53170 -82767 -59403 900000 900000 900000 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3701 2218 2320 3065 2411 4718 3900 1324 5180 3698 3782 2447 3939 900000 5233 1994 -2097 4184 2888 5860 1486 1546 3870 5354 2259 4260 3677 4965 1970 -3348 532 -5497 -3381 3 -446 -131 -2611 1459 -7161 3190 -1703 1951 -2331 -1912 -165 -3083 3830 1712 -1459 -8270 1623 -59 1274 -3190 1851 -3593 -4186 -1211 676 2330 -2665 -2471 -4867 -3146 -2712 -603 1217 -1897 1436 -3407 2179 215 2951 3847 -2021 2139 522 2072 3810 4326 2375 1903 2726 1347 3147 -1000 5250 -2813 2566 -5320 -2264 -130 2070 539 1510 537 -4759 -2607 SS 20221216T132329.9Z 8385.557985 320 1 49.61 2 80.77 130.31 44.64 226.89 0.00 1 0.00 1 0 25 5.359e-01 1.004e-02 1.835e-01 3.864e-03 7.157109e-01 2.093127e-03 7.901153e-03 -6.000000e+00 2.994312e-01 223.16 -2.00 3.47 -2.00 321.68 0.00e+00 2.250528e-03 1.097775e-03 9.157125e-04 -6.000000e+00 1.337361e-02 278.50 -2.00 20.00 -2.00 321.20 0.00e+00 5.923 0.004 302.00 328.00 3 8.6499e-01 7.4853e-03 6.9672e-02 -6.0000e+00 7.3746e-01 1.4238e-01 1.0750e-02 3.9171e-02 -6.0000e+00 8.0350e-01 -2.3022e-01 1.1437e-02 2.1391e-02 -6.0000e+00 4.7944e-01 9.6321e-02 5.3554e-03 7.1256e-03 -6.0000e+00 2.0664e-01 3.1994e-04 -1.0655e-03 1.0918e-04 9.2360e-05 -6.0000e+00 1.4218e-02 4.7856e-03 0.0000e+00 12 8 8 10 0 0 99.96 18.30 0.18 0.00479 -0.00322 269 51 1 5 0 184.390 26.41 19.99 18.30 10.64 26.0 1004.45 -179252 -226845 900000 -203830 -93663 -224947 -126776 -211048 -195986 -168431 -128487 -105327 -118479 52474 -97934 34517 -67196 -28465 -17098 -31738 -8650 -6644 -2257 -38751 49220 -48100 4857 -38275 -28913 -22835 -37276 -923 -13403 1431 -25298 5312 -23615 -7094 -3126 4569 17632 106 13209 -3937 11861 6158 8091 1314 977 8710 5691 13231 3305 9378 2988 13291 5347 6886 9671 4294 9811 -54 10990 3839 6485 4341 4201 2678 1957 5834 1066 2692 1161 2643 -1005 349 -2928 -2582 -1787 -1975 1827 -1874 1006 -2339 194 -1422 -985 250 -325 1584 -140 796 -1914 -1250 -699 -1022 -585 -147 85 -292 137 -1607 -1402 -1914 -1717 -1477 -751 -248 -658 212 181 630 278 394 -271 -148 -71 -31 -120 -31 352 438 499 137 885 486 353 663 4 640 156 597 -163 -227 -159 -200 186 -84 90 -129 48 -211 -475 -1596 -3561 900000 -2752 -417 -3320 -825 -3313 -3015 -2168 -1276 -938 -1542 198 -1599 201 -1139 -400 -234 -488 -119 -89 -30 -754 472 -1193 80 -865 -581 -466 -1065 -22 -433 44 -985 148 -890 -290 -140 230 894 7 804 -293 763 430 570 103 82 724 508 1243 379 1113 406 1706 771 980 1296 592 1307 -9 1819 784 1393 943 908 610 492 1638 328 857 374 849 -306 94 -753 -669 -514 -683 673 -829 482 -1232 107 -849 -616 160 -210 971 -82 430 -1024 -683 -426 -731 -487 -141 90 -316 140 -1507 -1177 -1586 -1528 -1392 -741 -262 -766 277 267 995 449 621 -408 -212 -102 -46 -190 -51 578 688 755 202 1241 662 465 896 6 1121 306 1254 -364 -538 -379 -506 480 -221 238 -326 122 -503 -1083 SS 20221216T134231.5Z 8385.571198 332 1 49.28 2 78.02 133.76 47.47 232.04 0.00 1 0.00 1 0 25 2.914e-01 1.311e-02 2.731e-01 8.717e-03 5.792259e-01 4.612296e-03 6.554628e-03 -6.000000e+00 1.646237e-01 223.16 -2.00 3.47 -2.00 320.90 0.00e+00 -4.845910e-03 1.905947e-03 1.373964e-03 -6.000000e+00 7.862365e-03 278.50 -2.00 20.00 -2.00 320.35 0.00e+00 4.672 0.002 302.00 328.00 3 3.7473e+00 1.4612e-02 5.5810e-02 -6.0000e+00 4.0792e-01 1.2288e-01 1.9007e-02 3.3614e-02 -6.0000e+00 4.4535e-01 -9.8090e-02 1.8753e-02 1.5771e-02 -6.0000e+00 2.6266e-01 3.3707e-02 9.3063e-03 7.8500e-03 -6.0000e+00 1.1243e-01 6.4490e-05 -1.0438e-03 2.5529e-04 6.7861e-05 -6.0000e+00 7.9889e-03 3.5989e-03 0.0000e+00 12 8 8 10 0 0 99.93 18.30 0.25 0.00360 -0.00424 22 4 1 5 0 2239.520 26.41 20.00 18.30 10.83 25.9 1004.34 -144633 -74593 -176064 -40568 112646 18112 -38943 900000 900000 -28131 900000 46125 900000 97243 900000 57721 -26477 9154 -34497 41143 16828 9673 -8876 -13346 -34837 71177 81758 -26747 -6910 -6181 29040 -2289 -16052 11640 -3648 -9458 -2962 16898 -9874 17880 8049 13585 6276 7468 2828 -2706 7262 2964 -11246 5172 6501 6448 -1732 13079 2827 4492 2533 5683 -26204 4210 1012 2344 6176 936 4054 -365 1163 -715 1157 -922 890 3794 818 2697 510 -787 764 243 -1310 374 -1931 -82 -964 -2835 -352 618 1703 -1840 1007 1790 1473 225 -947 267 -2637 1470 -548 212 -170 34 -471 -1324 -922 -2657 -895 -1531 -1077 59 -366 527 357 1026 291 188 766 -517 -739 860 -156 91 -118 226 510 132 610 638 -170 303 279 595 -709 596 -716 -664 -196 681 -482 482 549 -116 76 -1002 35 -2648 -830 -5215 -347 957 154 -331 900000 900000 -320 900000 392 900000 826 900000 669 -722 195 -1170 741 389 240 -274 -480 -1683 1414 1520 -1276 -260 -235 904 -109 -983 599 -209 -558 -180 1003 -921 1559 875 1507 777 928 366 -372 913 394 -1764 728 993 1100 -349 2484 635 1041 623 1368 -8321 971 243 598 1698 303 1341 -123 375 -239 409 -382 405 1769 393 1217 217 -305 269 84 -499 163 -1000 -47 -619 -1962 -254 473 1352 -1559 834 1428 1102 159 -645 180 -1996 1217 -526 229 -201 41 -534 -1388 -878 -2554 -912 -1661 -1219 70 -470 737 550 1661 477 298 1142 -741 -1055 1254 -242 149 -194 360 782 198 872 881 -228 408 416 979 -1283 1130 -1428 -1387 -434 1573 -1151 1161 1330 -274 170 -2164 72 SS 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