File name: Pandora140s1_WashingtonDC_20230929_L2Fit_fwvt1c10d20200806p1-8.txt File generation date: 20231001T103230.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Luke Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 140 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora140_OF_v3d20200721.txt Instrument calibration file used: Pandora140s1_CF_v10d20200806.txt Level 1 file used: Pandora140s1_WashingtonDC_20230929_L1_smca1c10d20200806p1-8.txt Full location name: McMillan Reservoir Short location name: WashingtonDC Country of location: United States Location latitude [deg]: 38.9218 Location longitude [deg]: -77.0124 Location altitude [m]: 58 Local noon date: 20230929 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1637 1786 Nominal wavelengths inside fitting window [nm]: 492.0752 492.1961 492.3170 492.4379 492.5588 492.6796 492.8005 492.9213 493.0421 493.1629 493.2836 493.4044 493.5251 493.6459 493.7666 493.8873 494.0079 494.1286 494.2492 494.3698 494.4904 494.6110 494.7316 494.8522 494.9727 495.0932 495.2137 495.3342 495.4547 495.5751 495.6956 495.8160 495.9364 496.0568 496.1772 496.2975 496.4179 496.5382 496.6585 496.7788 496.8990 497.0193 497.1395 497.2598 497.3800 497.5002 497.6203 497.7405 497.8606 497.9807 498.1008 498.2209 498.3410 498.4610 498.5811 498.7011 498.8211 498.9411 499.0611 499.1810 499.3009 499.4209 499.5408 499.6606 499.7805 499.9004 500.0202 500.1400 500.2598 500.3796 500.4994 500.6191 500.7389 500.8586 500.9783 501.0980 501.2176 501.3373 501.4569 501.5765 501.6961 501.8157 501.9353 502.0548 502.1743 502.2938 502.4133 502.5328 502.6523 502.7717 502.8912 503.0106 503.1300 503.2493 503.3687 503.4881 503.6074 503.7267 503.8460 503.9653 504.0845 504.2038 504.3230 504.4422 504.5614 504.6806 504.7997 504.9189 505.0380 505.1571 505.2762 505.3953 505.5143 505.6334 505.7524 505.8714 505.9904 506.1093 506.2283 506.3472 506.4661 506.5851 506.7039 506.8228 506.9417 507.0605 507.1793 507.2981 507.4169 507.5357 507.6544 507.7731 507.8919 508.0106 508.1292 508.2479 508.3665 508.4852 508.6038 508.7224 508.8410 508.9595 509.0781 509.1966 509.3151 509.4336 509.5521 509.6705 509.7890 509.9074 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20230929T125308.2Z 8672.536900 300 1 2.95 2 69.75 110.87 110.19 288.67 0.00 1 0.00 1 0 22 4.055e-03 4.038e-03 2.595e-03 2.591e-03 5.531909e+03 1.666020e+02 3.853816e+02 -6.000000e+00 2.271782e+02 287.33 -2.00 20.00 -2.00 505.26 0.00e+00 7.560987e-04 7.188668e-05 5.127134e-05 -6.000000e+00 1.146596e-04 287.33 -2.00 20.00 -2.00 500.45 0.00e+00 2.117544e-01 5.101695e-02 3.573212e-02 -6.000000e+00 8.006217e-02 227.86 -2.00 3.47 -2.00 502.04 0.00e+00 2.858 0.000 489.00 513.00 1 6.3522e+00 3.9108e-03 5.2256e-03 -6.0000e+00 6.1399e-03 1.1790e-02 1.0114e-03 8.8977e-04 -6.0000e+00 1.6036e-03 2.1989e-03 9.4853e-04 2.4415e-04 4.6187e-05 -6.0000e+00 3.9905e-04 -1.0804e-02 6.2125e-05 12 9 1 12 1 1 999.00 18.55 0.86 -0.01080 -0.00423 1 7 1 4 0 1388.060 26.73 20.00 18.55 24.18 29.1 1022.26 -715 -424 -379 268 904 883 666 608 552 399 168 -690 -52 -60 -459 -855 83 -13 -124 -167 337 144 4 101 125 165 166 53 601 -303 -227 -744 32 107 215 130 109 -83 417 -139 -255 -154 39 -199 598 508 669 25 -302 -492 -582 -436 -798 -824 46 -85 125 142 -134 482 -59 72 197 -116 489 -167 -72 -437 96 -186 48 -620 -94 404 150 213 -432 -393 -270 97 -631 -449 -218 -550 -165 -189 -482 -187 -64 108 35 80 570 486 418 865 -518 -469 -237 -572 -965 -194 17 -203 -52 -148 71 -477 -426 -144 -164 282 -125 971 120 713 -13 526 613 -136 433 466 22 120 300 -122 -3 -89 -245 695 384 417 -651 -96 -234 321 -52 107 -558 451 891 -185 209 280 230 -62 -131 -111 -517 -578 -698 -417 -378 271 923 911 694 635 576 414 174 -710 -53 -61 -463 -865 84 -14 -129 -174 352 150 4 105 131 173 174 55 612 -306 -227 -748 32 110 224 136 114 -86 428 -142 -261 -158 40 -206 621 528 692 26 -309 -497 -578 -428 -781 -811 46 -85 127 145 -137 491 -60 74 201 -118 496 -169 -73 -435 95 -183 47 -609 -92 399 148 211 -424 -383 -262 94 -611 -437 -212 -540 -163 -186 -477 -184 -63 107 35 79 570 485 413 844 -503 -448 -224 -536 -907 -183 17 -199 -51 -147 70 -470 -417 -141 -162 280 -125 968 120 715 -13 530 616 -136 428 457 22 117 294 -120 -3 -87 -241 677 373 401 -625 -91 -223 308 -51 105 -551 445 882 -184 208 280 230 -62 -129 -108 -499 -558 SQ 20230929T134431.2Z 8672.572583 341 1 50.41 2 60.77 120.99 118.80 298.37 0.00 1 0.00 1 0 15 3.284e-03 3.276e-03 1.350e-03 1.345e-03 4.237994e+03 8.623748e+01 2.832071e+02 -6.000000e+00 1.839819e+02 287.33 -2.00 20.00 -2.00 505.30 0.00e+00 7.439458e-04 3.745052e-05 4.649519e-05 -6.000000e+00 9.285277e-05 287.33 -2.00 20.00 -2.00 500.35 0.00e+00 2.310026e-01 2.665035e-02 3.179050e-02 -6.000000e+00 6.482493e-02 227.86 -2.00 3.47 -2.00 501.98 0.00e+00 2.038 0.000 489.00 513.00 1 8.1152e+00 2.0411e-03 4.0803e-03 -6.0000e+00 4.9715e-03 6.7654e-03 5.2592e-04 7.3887e-04 -6.0000e+00 1.2982e-03 4.2421e-04 5.4465e-05 1.2706e-04 3.1260e-05 -6.0000e+00 3.2314e-04 -1.2965e-02 9.0373e-05 10 0 0 10 0 0 90.66 18.53 0.89 -0.01296 -0.01259 13 2 1 4 0 3875.900 26.73 20.00 18.53 24.33 29.3 1023.85 -889 -576 -374 333 10 170 653 261 425 80 163 -70 -494 -77 100 -601 -24 -288 230 32 145 154 48 527 263 419 45 231 78 -245 -27 -527 -210 122 350 475 167 44 -164 -358 -66 -120 66 354 172 276 517 182 327 -445 -563 -583 -728 -771 -182 95 448 460 -122 136 60 122 158 97 376 38 313 -6 -518 -344 -69 -150 -307 -14 221 379 53 -335 -644 -37 -317 -710 108 -447 -11 -249 -101 -21 -512 144 2 77 150 497 184 -61 49 -201 -374 -476 -507 -294 -264 76 168 -29 -95 -391 -243 -79 -152 -118 312 567 241 246 451 361 33 198 386 -38 -24 348 473 242 598 170 211 194 132 50 6 -303 -197 -122 -77 -209 -161 226 149 -51 543 52 372 -34 -582 -262 -691 -508 -860 -565 -378 346 11 186 722 271 473 88 177 -75 -523 -80 103 -629 -25 -313 236 33 151 161 50 549 277 439 47 237 84 -257 -28 -549 -223 124 364 497 174 45 -167 -363 -66 -123 68 367 180 289 537 187 329 -439 -581 -587 -728 -779 -188 93 450 466 -124 137 61 124 161 99 379 38 306 -6 -497 -325 -65 -141 -292 -13 214 364 50 -312 -596 -36 -293 -664 101 -424 -11 -241 -97 -20 -496 139 2 76 150 494 181 -59 46 -185 -336 -454 -483 -264 -246 74 166 -29 -94 -380 -233 -76 -149 -117 313 571 245 251 463 371 33 199 381 -37 -23 338 461 237 583 166 205 188 127 48 6 -282 -183 -115 -74 -205 -160 226 150 -52 551 53 379 -35 -582 -255 -663 -485 SQ 20230929T135727.6Z 8672.581570 347 1 34.22 2 58.64 123.82 120.85 301.05 0.00 1 0.00 1 0 15 2.938e-03 2.915e-03 1.189e-03 1.186e-03 3.955388e+03 7.443513e+01 2.747037e+02 -6.000000e+00 1.646291e+02 287.33 -2.00 20.00 -2.00 505.27 0.00e+00 5.868263e-04 3.297884e-05 3.592665e-05 -6.000000e+00 8.308975e-05 287.33 -2.00 20.00 -2.00 500.43 0.00e+00 1.835890e-01 2.337280e-02 2.751701e-02 -6.000000e+00 5.801688e-02 227.86 -2.00 3.47 -2.00 502.03 0.00e+00 1.914 0.000 489.00 513.00 1 7.7586e+00 1.7948e-03 3.6838e-03 -6.0000e+00 4.4493e-03 7.6130e-03 4.6306e-04 6.6616e-04 -6.0000e+00 1.1620e-03 6.2056e-04 5.1554e-04 1.1268e-04 3.1215e-05 -6.0000e+00 2.8917e-04 -9.8622e-03 5.9330e-05 12 1 1 12 1 1 99.93 18.54 0.93 -0.00986 -0.00629 9 3 1 4 0 3404.900 26.73 20.00 18.54 25.11 29.2 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