File name: Pandora140s1_WashingtonDC_20231026_L2Fit_fout2c14d20220101p1-8.txt File generation date: 20241218T233437.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Luke Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 140 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora140_OF_v3d20200721.txt Instrument calibration file used: Pandora140s1_CF_v14d20220101.txt Level 1 file used: Pandora140s1_WashingtonDC_20231026_L1_smca1c14d20220101p1-8.txt Full location name: McMillan Reservoir Short location name: WashingtonDC Country of location: United States Location latitude [deg]: 38.9218 Location longitude [deg]: -77.0124 Location altitude [m]: 58 Local noon date: 20231026 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 10 "Based on session 8 "Modif only on SO2 (WashingtonDC)""" First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0439 305.1847 305.3255 305.4663 305.6071 305.7478 305.8885 306.0293 306.1700 306.3107 306.4514 306.5921 306.7328 306.8734 307.0141 307.1547 307.2954 307.4360 307.5766 307.7172 307.8578 307.9983 308.1389 308.2794 308.4200 308.5605 308.7010 308.8415 308.9820 309.1225 309.2630 309.4034 309.5439 309.6843 309.8247 309.9652 310.1056 310.2459 310.3863 310.5267 310.6670 310.8074 310.9477 311.0881 311.2284 311.3687 311.5089 311.6492 311.7895 311.9297 312.0700 312.2102 312.3504 312.4906 312.6308 312.7710 312.9112 313.0514 313.1915 313.3316 313.4718 313.6119 313.7520 313.8921 314.0322 314.1722 314.3123 314.4523 314.5924 314.7324 314.8724 315.0124 315.1524 315.2924 315.4324 315.5723 315.7123 315.8522 315.9921 316.1320 316.2719 316.4118 316.5517 316.6915 316.8314 316.9712 317.1111 317.2509 317.3907 317.5305 317.6703 317.8100 317.9498 318.0895 318.2293 318.3690 318.5087 318.6484 318.7881 318.9278 319.0675 319.2071 319.3468 319.4864 319.6260 319.7656 319.9052 320.0448 320.1844 320.3239 320.4635 320.6030 320.7426 320.8821 321.0216 321.1611 321.3006 321.4400 321.5795 321.7189 321.8584 321.9978 322.1372 322.2766 322.4160 322.5554 322.6947 322.8341 322.9734 323.1128 323.2521 323.3914 323.5307 323.6700 323.8093 323.9485 324.0878 324.2270 324.3662 324.5054 324.6446 324.7838 324.9230 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231026T120114.6Z 8699.500863 184 1 49.94 2 84.81 110.58 125.95 301.81 0.00 1 0.00 1 0 25 7.441e-01 6.164e-02 4.753e-01 4.622e-02 8.048196e-01 2.615526e-02 9.240013e-03 -6.000000e+00 4.270403e-01 225.31 -2.00 3.47 -2.00 321.92 0.00e+00 2.614182e-03 9.523596e-03 3.665224e-03 -6.000000e+00 2.041142e-02 284.16 -2.00 20.00 -2.00 321.34 0.00e+00 9.552 0.015 302.00 328.00 3 5.5411e-01 8.8204e-02 1.0503e-01 -6.0000e+00 1.0588e+00 1.6473e+00 1.0317e-01 4.5841e-02 -6.0000e+00 1.1551e+00 -1.8781e+00 5.7831e-02 2.0356e-02 -6.0000e+00 6.8423e-01 6.9509e-01 3.2816e-02 6.0759e-03 -6.0000e+00 2.9314e-01 9.9402e-06 -2.0108e-03 1.3084e-03 8.6016e-05 -6.0000e+00 2.0325e-02 1.6518e-03 0.0000e+00 12 8 8 10 0 0 7.18 18.60 1.10 0.00165 -0.01346 30 6 1 5 0 1664.340 26.83 20.00 18.60 21.06 29.1 1004.50 362592 8498 900000 -53323 900000 49949 230681 -19052 900000 75662 -24832 25168 -43407 210225 -20507 276455 900000 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4392 4013 4957 4092 5671 -5941 900000 3990 2879 4679 484 6366 -9734 5615 -1740 5557 -1117 6339 2415 7578 6792 2343 7851 7945 10905 7133 6678 653 2049 1852 -2187 7408 -4670 7452 2825 3414 8907 2807 -2696 994 9518 -10089 8484 -5565 1981 -1339 -3843 -4697 578 -4152 -1275 6053 -8419 2309 -14891 1055 -2210 2426 -8088 -8858 -4478 -503 2332 -9427 6779 1318 2495 -69 -1379 3190 -13185 6853 -1489 12016 -1047 11553 1010 -1385 6622 -2102 8701 91 8064 -7972 1748 -1167 2889 1500 -6807 579 117 7688 -2374 352 -1110 -7016 SS 20231026T121209.4Z 8699.508442 187 1 50.65 2 82.84 112.38 127.61 304.33 0.00 1 0.00 1 0 17 4.553e-01 1.793e-02 3.264e-01 9.629e-03 7.080856e-01 5.310467e-03 7.811645e-03 -6.000000e+00 2.574177e-01 225.31 -2.00 3.47 -2.00 321.91 0.00e+00 -6.983955e-04 3.005569e-03 1.841738e-03 -6.000000e+00 1.175052e-02 284.16 -2.00 20.00 -2.00 321.39 0.00e+00 7.385 0.007 302.00 328.00 3 9.2887e-01 2.0586e-02 8.2796e-02 -6.0000e+00 6.3586e-01 3.9741e-01 2.7978e-02 4.1052e-02 -6.0000e+00 6.9195e-01 -6.2908e-01 2.5729e-02 2.0524e-02 -6.0000e+00 4.1299e-01 2.6702e-01 1.1962e-02 6.1975e-03 -6.0000e+00 1.7695e-01 7.8369e-05 -1.5785e-03 2.8204e-04 8.1342e-05 -6.0000e+00 1.2079e-02 1.1474e-03 0.0000e+00 12 9 8 11 8 0 66.17 18.60 0.30 0.00115 -0.01071 90 17 1 5 0 562.700 26.83 20.00 18.60 22.27 29.0 1012.56 -121053 -88914 8730 -98352 -38105 -176262 62540 -208582 -64543 -159933 -104188 -5082 48608 32840 -114738 -485 -49241 225843 -100372 900000 -79564 -44036 17710 899 900000 -34354 37037 -80384 55007 -30112 60420 15989 50729 21266 -24032 7854 -12742 -4337 -5004 28569 51785 48326 22984 20836 27437 -12064 40664 6003 16992 15406 23913 19235 20838 13271 9909 24916 4996 23922 3494 15034 28420 8861 18435 15373 13259 7095 13163 7263 6821 10027 11369 6271 1077 4218 -2070 2417 -3923 -2641 -2900 1572 396 1191 1896 -4330 -2237 -3530 142 -301 1461 2472 -2757 2068 384 -2166 -7403 1099 -2184 37 -836 -1519 -594 -3193 -555 -4441 -2057 -2395 145 -1094 -394 574 -756 30 -951 456 -589 445 -1030 132 374 -177 1639 1112 1706 994 1379 671 1089 -188 447 1113 241 262 -766 544 -361 269 83 426 118 188 -244 -731 -1409 -1665 -1028 82 -1257 -358 -3938 587 -7339 -654 -4288 -1705 -48 456 308 -4031 -7 -1225 2120 -4578 900000 -3119 -1219 282 18 900000 -1092 613 -3780 696 -875 874 412 1086 649 -1069 251 -527 -191 -267 1337 2208 2271 1415 1327 1639 -1043 2194 456 1215 1181 1869 1752 2039 1508 1240 2832 705 2843 485 1817 3063 1230 2637 2556 2410 1350 2342 1408 1439 2358 2948 1795 323 1171 -562 566 -904 -604 -731 450 135 463 813 -2098 -1135 -1941 79 -175 842 1375 -1516 1022 187 -1103 -4413 702 -1668 32 -809 -1511 -559 -2824 -433 -3539 -1724 -2145 134 -1097 -430 697 -1047 45 -1460 679 -849 609 -1432 189 568 -284 2589 1710 2521 1442 1926 918 1440 -258 686 1926 465 547 -1703 1266 -906 713 227 1176 328 507 -624 -1777 -3310 SS 20231026T122245.2Z 8699.515801 190 1 50.25 2 80.95 114.16 129.17 306.87 0.00 1 0.00 1 0 25 3.770e-01 7.922e-03 9.853e-02 2.874e-03 6.096485e-01 1.529454e-03 6.911574e-03 -6.000000e+00 2.125171e-01 225.31 -2.00 3.47 -2.00 321.41 0.00e+00 1.520578e-03 7.670944e-04 1.642356e-03 -6.000000e+00 9.512172e-03 284.16 -2.00 20.00 -2.00 320.84 0.00e+00 6.025 0.004 302.00 328.00 3 4.7569e-01 5.4145e-03 6.7940e-02 -6.0000e+00 5.2492e-01 7.3875e-02 7.3781e-03 3.4081e-02 -6.0000e+00 5.7038e-01 -1.4262e-01 7.2364e-03 1.7672e-02 -6.0000e+00 3.4073e-01 5.6826e-02 3.4427e-03 5.2717e-03 -6.0000e+00 1.4648e-01 4.9379e-04 -8.8058e-04 8.4200e-05 7.4056e-05 -6.0000e+00 9.9989e-03 7.5405e-04 0.0000e+00 11 8 0 10 0 0 -3.33 18.60 0.23 0.00075 -0.00586 316 60 1 5 0 158.990 26.83 20.00 18.60 23.20 28.9 1018.07 -151647 -137156 -118763 -144919 -103343 -118825 -80381 -123997 -112851 -113720 -103080 -45013 -99257 -26103 -40364 -51182 -68945 -48428 -46429 -23631 -28571 -32002 -8517 -19458 2932 -24268 -13668 -16492 -31805 -12890 -22543 -7498 -17714 1905 -15067 -796 -11941 -12275 -674 1559 6549 3924 11506 4201 13054 4384 4326 2408 306 5534 1246 10651 2794 7526 4551 5783 2405 2772 -5314 -197 4091 2388 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