File name: Pandora140s1_WashingtonDC_20231129_L2Fit_fout2c10d20200806p1-8.txt File generation date: 20231130T061225.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Luke Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 140 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora140_OF_v3d20200721.txt Instrument calibration file used: Pandora140s1_CF_v10d20200806.txt Level 1 file used: Pandora140s1_WashingtonDC_20231129_L1_smca1c10d20200806p1-8.txt Full location name: McMillan Reservoir Short location name: WashingtonDC Country of location: United States Location latitude [deg]: 38.9218 Location longitude [deg]: -77.0124 Location altitude [m]: 58 Local noon date: 20231129 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0548 305.1956 305.3364 305.4772 305.6179 305.7587 305.8994 306.0401 306.1808 306.3215 306.4622 306.6029 306.7436 306.8842 307.0249 307.1655 307.3061 307.4468 307.5874 307.7279 307.8685 308.0091 308.1496 308.2902 308.4307 308.5712 308.7118 308.8523 308.9927 309.1332 309.2737 309.4141 309.5546 309.6950 309.8354 309.9758 310.1162 310.2566 310.3970 310.5373 310.6777 310.8180 310.9584 311.0987 311.2390 311.3793 311.5196 311.6598 311.8001 311.9403 312.0806 312.2208 312.3610 312.5012 312.6414 312.7816 312.9218 313.0619 313.2021 313.3422 313.4823 313.6224 313.7625 313.9026 314.0427 314.1828 314.3228 314.4629 314.6029 314.7429 314.8829 315.0229 315.1629 315.3029 315.4428 315.5828 315.7227 315.8627 316.0026 316.1425 316.2824 316.4223 316.5621 316.7020 316.8418 316.9817 317.1215 317.2613 317.4011 317.5409 317.6807 317.8205 317.9602 318.1000 318.2397 318.3794 318.5191 318.6588 318.7985 318.9382 319.0779 319.2175 319.3572 319.4968 319.6364 319.7760 319.9156 320.0552 320.1948 320.3343 320.4739 320.6134 320.7529 320.8924 321.0319 321.1714 321.3109 321.4504 321.5898 321.7293 321.8687 322.0081 322.1476 322.2870 322.4263 322.5657 322.7051 322.8444 322.9838 323.1231 323.2624 323.4017 323.5410 323.6803 323.8196 323.9588 324.0981 324.2373 324.3765 324.5158 324.6550 324.7941 324.9333 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231129T123958.6Z 8733.527761 283 1 50.51 2 85.04 122.85 71.87 291.35 0.00 1 0.00 1 0 17 6.072e-01 6.605e-02 4.973e-01 5.867e-02 1.036761e+00 3.358622e-02 1.194374e-02 -6.000000e+00 3.469749e-01 223.41 -2.00 3.47 -2.00 321.94 0.00e+00 -7.400197e-03 1.155290e-02 4.364624e-03 -6.000000e+00 1.563593e-02 280.28 -2.00 20.00 -2.00 321.39 0.00e+00 9.891 0.017 302.00 328.00 3 1.4382e-01 1.1080e-01 1.1341e-01 -6.0000e+00 8.5278e-01 2.2812e+00 1.2746e-01 5.5907e-02 -6.0000e+00 9.2970e-01 -2.3878e+00 7.3017e-02 2.6576e-02 -6.0000e+00 5.5482e-01 8.5370e-01 4.1955e-02 7.8358e-03 -6.0000e+00 2.3780e-01 7.0648e-06 -2.5937e-04 1.4916e-03 1.4767e-04 -6.0000e+00 1.6308e-02 -3.9803e-03 -9.0416e-06 12 8 8 10 0 0 31.84 18.35 1.34 -0.00398 -0.00593 30 6 1 5 0 1682.780 26.51 20.00 18.35 3.54 27.2 1015.17 152342 46070 110640 19630 -28206 900000 6161 -6167 23913 57528 9251 160980 53010 187943 900000 -53380 900000 261698 46272 60157 14932 900000 -64662 41286 -32155 142942 168540 11763 134743 -22674 76127 23839 110146 71822 16043 -44325 72434 161875 26918 900000 -38053 900000 -42030 43777 51138 900000 198275 4408 211250 -70318 -2738 -35211 29557 13486 26817 75324 3770 37573 24287 9018 18516 67095 -22794 94903 -16957 123846 -5592 225 22102 -23073 69712 7261 47110 -10233 23858 45708 14730 20215 -4133 -2041 -12545 11645 44348 33439 17537 25081 35745 -12535 25819 -24762 10010 -13841 -8746 -12583 19715 -1527 4177 6492 2300 697 6925 9640 -2712 -4665 17610 -13686 11703 -13155 735 -10502 10767 3367 2445 76 -3568 903 -10218 -1405 -6206 1842 -1476 5618 -332 866 5102 -6407 13678 -1564 3452 -1599 2684 -3784 1293 2891 1274 2958 -2209 -1064 -2507 1310 224 606 -486 8705 5520 6440 2290 -4062 900000 531 -613 1804 3287 756 9198 3319 10739 900000 -13166 900000 14953 4260 4478 1554 900000 -12536 3008 -4897 8167 9630 909 7699 -2149 4350 1891 6294 4104 1355 -6092 4139 9249 2441 900000 -8039 900000 -9102 3869 3883 900000 11329 485 12070 -17335 -385 -7449 3568 2023 3691 6599 663 4541 3027 1180 2113 5006 -4568 6874 -3872 7092 -1138 46 3961 -7233 9690 1874 7925 -2707 3970 5330 2155 2909 -861 -503 -4049 3452 10655 9415 6037 8393 11080 -6227 8737 -12941 3480 -5729 -3445 -5531 7390 -834 2545 4524 1851 578 5087 6166 -1718 -2912 9444 -10425 7390 -11456 633 -11749 11428 4249 3263 105 -4934 1164 -14821 -1958 -9512 2680 -2143 7166 -428 1075 5918 -8129 14031 -1976 4919 -2816 5174 -8578 3017 7166 3466 8354 -6663 -3206 -7601 3624 575 1430 -1098 SS 20231129T125043.5Z 8733.535226 286 1 50.44 2 83.31 124.66 73.75 292.73 0.00 1 0.00 1 0 25 4.897e-01 2.091e-02 3.482e-01 1.223e-02 9.225277e-01 6.931072e-03 1.002825e-02 -6.000000e+00 2.779134e-01 223.41 -2.00 3.47 -2.00 322.30 0.00e+00 1.273564e-02 4.041334e-03 5.835230e-03 -6.000000e+00 1.220845e-02 280.28 -2.00 20.00 -2.00 321.86 0.00e+00 7.819 0.008 302.00 328.00 3 4.2610e-01 2.7492e-02 1.0241e-01 -6.0000e+00 6.8592e-01 1.0912e+00 3.5841e-02 8.2220e-02 -6.0000e+00 7.4906e-01 -1.4244e+00 3.1386e-02 2.7891e-02 -6.0000e+00 4.4359e-01 5.6975e-01 1.4894e-02 1.5372e-02 -6.0000e+00 1.8853e-01 5.6811e-05 -2.0087e-03 3.2841e-04 1.5065e-04 -6.0000e+00 1.3154e-02 -4.6868e-03 1.3273e-05 12 8 8 10 0 0 10.95 18.35 0.39 -0.00469 -0.01978 115 22 1 5 0 438.560 26.51 20.01 18.35 4.01 27.2 1019.30 -94203 -23347 174039 -120872 -61088 -176410 900000 -124305 192895 -65234 -68095 -22522 -85764 4075 -35407 -11577 -43595 206925 -53007 125303 31771 11800 -16248 -79169 120689 -87264 -30828 -15122 -2577 -25870 -21406 18047 15219 900000 -23253 -35905 20215 130043 19644 85438 49835 37942 14574 8419 39822 66554 62600 7285 33540 53627 34273 52640 24177 45390 32532 55867 25847 42872 26241 3255 7188 -4307 33876 14767 19374 33365 28882 12661 27623 16538 23815 18605 6741 9503 5723 668 -646 -8282 4361 -5703 -3738 -3173 5926 -1948 2216 -1595 2186 -208 1973 1702 -1163 2590 -7774 -725 -3180 -1041 -3839 -1564 -1260 -1605 631 -4002 -852 -3683 -3071 -2407 -2167 -2318 -2430 -1910 -1038 692 -623 -508 -905 -660 -623 -635 -226 -340 1130 1688 2531 2107 1818 1539 1390 1548 -23 1553 740 1042 370 136 -447 76 195 -395 398 293 -47 -1387 -1636 -2340 -354 2075 -4204 -1060 -7713 900000 -3234 2300 -919 -960 -269 -2045 53 -883 -276 -1607 2468 -2413 1494 586 243 -423 -3862 1439 -4446 -869 -344 -50 -701 -696 489 495 900000 -1109 -1790 592 1551 745 1945 1783 1604 806 502 1727 2237 2239 474 1782 2500 2155 3082 2044 3346 2857 3937 2466 3346 2276 339 725 -488 3305 1864 2561 4196 3502 1887 3870 2975 4402 3753 1494 1889 1052 114 -103 -1481 793 -1411 -1092 -1078 2061 -778 898 -712 980 -98 910 761 -499 1006 -3291 -302 -1567 -604 -2532 -1195 -1086 -1426 520 -3094 -607 -2588 -2283 -1887 -1794 -1935 -2281 -2071 -1295 940 -893 -726 -1257 -884 -840 -898 -337 -526 1690 2374 3371 2733 2287 2051 1807 2102 -33 2676 1462 2263 868 343 -1221 218 571 -1176 1176 826 -122 -3392 -3778 SS 20231129T130116.2Z 8733.542549 289 1 50.41 2 81.64 126.48 75.57 294.10 0.00 1 0.00 1 0 25 6.157e-01 1.360e-02 2.221e-01 4.269e-03 8.102682e-01 2.344196e-03 8.814416e-03 -6.000000e+00 3.443697e-01 223.41 -2.00 3.47 -2.00 321.97 0.00e+00 5.876599e-03 1.346658e-03 1.645320e-03 -6.000000e+00 1.528532e-02 280.28 -2.00 20.00 -2.00 321.50 0.00e+00 6.467 0.005 302.00 328.00 3 4.4389e-01 8.9698e-03 7.8570e-02 -6.0000e+00 8.4809e-01 3.4999e-01 1.3151e-02 5.0051e-02 -6.0000e+00 9.2360e-01 -5.0729e-01 1.3752e-02 2.4679e-02 -6.0000e+00 5.5124e-01 2.0868e-01 6.2943e-03 1.0755e-02 -6.0000e+00 2.3688e-01 2.5554e-04 -9.8255e-04 1.1588e-04 1.2458e-04 -6.0000e+00 1.6324e-02 -4.6992e-03 2.3282e-05 12 9 8 11 8 0 -3.75 18.36 0.27 -0.00470 -0.01208 277 52 1 5 0 181.940 26.51 19.99 18.36 4.96 27.3 1025.84 -125042 -220041 -58429 -226783 -177661 -230157 -257796 -169309 -235189 -58514 -193090 39868 -112003 -138566 -118713 -82773 -68341 -94917 -37813 -76733 28820 -86882 28984 -40293 -54085 -62686 -73823 -27980 -66456 -21819 -6902 26584 -7252 -15917 -11863 -23395 7379 -6442 58106 -10438 24389 10095 29197 6198 24820 8102 6798 13216 5270 21717 8777 22958 18068 16370 16243 12123 17691 5487 73820 7766 15557 7055 8981 12941 11405 10499 5263 8540 3440 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