File name: Pandora140s1_WashingtonDC_20231225_L2Fit_fout2c14d20220101p1-8.txt File generation date: 20241219T001550.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Luke Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 140 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora140_OF_v3d20200721.txt Instrument calibration file used: Pandora140s1_CF_v14d20220101.txt Level 1 file used: Pandora140s1_WashingtonDC_20231225_L1_smca1c14d20220101p1-8.txt Full location name: McMillan Reservoir Short location name: WashingtonDC Country of location: United States Location latitude [deg]: 38.9218 Location longitude [deg]: -77.0124 Location altitude [m]: 58 Local noon date: 20231225 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 10 "Based on session 8 "Modif only on SO2 (WashingtonDC)""" First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0439 305.1847 305.3255 305.4663 305.6071 305.7478 305.8885 306.0293 306.1700 306.3107 306.4514 306.5921 306.7328 306.8734 307.0141 307.1547 307.2954 307.4360 307.5766 307.7172 307.8578 307.9983 308.1389 308.2794 308.4200 308.5605 308.7010 308.8415 308.9820 309.1225 309.2630 309.4034 309.5439 309.6843 309.8247 309.9652 310.1056 310.2459 310.3863 310.5267 310.6670 310.8074 310.9477 311.0881 311.2284 311.3687 311.5089 311.6492 311.7895 311.9297 312.0700 312.2102 312.3504 312.4906 312.6308 312.7710 312.9112 313.0514 313.1915 313.3316 313.4718 313.6119 313.7520 313.8921 314.0322 314.1722 314.3123 314.4523 314.5924 314.7324 314.8724 315.0124 315.1524 315.2924 315.4324 315.5723 315.7123 315.8522 315.9921 316.1320 316.2719 316.4118 316.5517 316.6915 316.8314 316.9712 317.1111 317.2509 317.3907 317.5305 317.6703 317.8100 317.9498 318.0895 318.2293 318.3690 318.5087 318.6484 318.7881 318.9278 319.0675 319.2071 319.3468 319.4864 319.6260 319.7656 319.9052 320.0448 320.1844 320.3239 320.4635 320.6030 320.7426 320.8821 321.0216 321.1611 321.3006 321.4400 321.5795 321.7189 321.8584 321.9978 322.1372 322.2766 322.4160 322.5554 322.6947 322.8341 322.9734 323.1128 323.2521 323.3914 323.5307 323.6700 323.8093 323.9485 324.0878 324.2270 324.3662 324.5054 324.6446 324.7838 324.9230 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231225T130925.9Z 8759.548216 287 1 50.00 2 83.61 127.16 105.35 323.58 0.00 1 0.00 1 0 17 5.577e-01 3.691e-02 4.343e-01 3.096e-02 1.026977e+00 1.775446e-02 1.111395e-02 -6.000000e+00 3.120636e-01 223.39 -2.00 3.47 -2.00 322.32 0.00e+00 -1.755956e-02 8.063155e-03 8.302838e-03 -6.000000e+00 1.404236e-02 277.97 -2.00 20.00 -2.00 321.86 0.00e+00 8.120 0.009 302.00 328.00 3 1.2880e+00 6.2817e-02 1.1531e-01 -6.0000e+00 7.6880e-01 1.5969e+00 7.7663e-02 1.0753e-01 -6.0000e+00 8.3758e-01 -2.0299e+00 5.6364e-02 3.4703e-02 -6.0000e+00 4.9955e-01 7.7575e-01 2.9357e-02 1.6491e-02 -6.0000e+00 2.1517e-01 1.6080e-05 -7.3848e-04 7.9854e-04 1.6046e-04 -6.0000e+00 1.5017e-02 5.0360e-03 0.0000e+00 12 9 8 11 8 0 91.93 18.42 0.49 0.00504 -0.00051 40 8 1 5 0 1249.660 26.51 20.00 18.42 13.17 28.5 1019.52 21310 279185 26300 900000 -21885 -39119 -32208 21764 73821 -64531 -97376 151276 -28109 -1735 -6076 18554 9786 11354 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4875 4782 5688 5152 3075 1624 4513 1775 1886 418 4002 4975 829 5827 -3195 5643 3651 5978 3232 6360 552 -2588 -1905 -5357 1078 1766 4266 -984 2881 -1156 -4556 4115 969 4212 -6432 8402 -1980 -233 998 -6177 1521 760 -590 -5519 -4048 -4700 -3073 -9447 -6233 -3005 -6031 5458 -2224 2012 1812 -4587 -106 1138 142 881 730 -1326 4543 5109 -665 1161 3423 356 1117 3418 1211 3978 -1968 1199 -728 5902 -601 702 -1246 -3775 2620 491 -3666 -913 6018 -426 -2770 -3508 SS 20231225T132010.3Z 8759.555675 290 1 50.60 2 81.96 129.01 106.49 325.65 0.00 1 0.00 1 0 25 5.279e-01 3.759e-02 4.582e-01 3.353e-02 8.699864e-01 1.979862e-02 9.993841e-03 -6.000000e+00 3.173366e-01 223.39 -2.00 3.47 -2.00 321.94 0.00e+00 1.727427e-02 9.452744e-03 3.033423e-03 -6.000000e+00 1.562765e-02 277.97 -2.00 20.00 -2.00 321.49 0.00e+00 6.694 0.005 302.00 328.00 3 2.8866e+00 6.8802e-02 8.6335e-02 -6.0000e+00 7.8472e-01 1.2454e+00 8.3527e-02 6.7244e-02 -6.0000e+00 8.6092e-01 -1.5294e+00 6.4485e-02 2.2673e-02 -6.0000e+00 5.0380e-01 6.3389e-01 3.2522e-02 1.8104e-02 -6.0000e+00 2.1577e-01 1.2486e-05 -3.4344e-03 9.4185e-04 1.8819e-04 -6.0000e+00 1.5251e-02 3.9127e-03 0.0000e+00 12 8 8 10 0 0 98.53 18.43 0.63 0.00391 -0.02190 18 3 1 5 0 2810.600 26.51 20.00 18.43 14.20 28.2 1025.16 900000 -51752 70968 -114770 900000 900000 900000 900000 900000 -31699 -68171 900000 4820 900000 -65133 900000 900000 63097 900000 109871 53535 205082 900000 62204 106437 51610 900000 -78923 59482 900000 127554 900000 22666 900000 147384 60399 190893 136529 98321 900000 900000 -8753 -18316 114289 900000 11258 900000 900000 159282 -2587 21365 57789 90862 98614 95327 54008 28151 16834 900000 13310 89630 18016 48847 17197 -4857 12869 39571 3004 -206 5751 8402 18427 5074 40326 1241 12087 55 12241 -13472 -9477 30703 -1161 3911 8378 -232 -1571 8882 -3043 -2098 1286 -12952 4478 6155 -1934 -1097 -8355 -53 -958 -1378 -6379 1156 -3732 1663 502 -6252 -8597 -8225 -3506 -5040 -3032 1197 -685 -672 86 922 -927 550 -2857 -1520 1526 4611 5138 2744 1245 339 3251 1453 1726 1560 3816 3527 1980 -384 83 -1720 1477 -1644 -1085 1416 -1276 1038 -1056 -2614 900000 -3138 2310 -11719 900000 900000 900000 900000 900000 -1032 -2349 900000 157 900000 -4766 900000 900000 2054 900000 3576 1764 6675 900000 2025 3465 1680 900000 -6005 1936 900000 4152 900000 1190 900000 4797 2022 6214 4444 3200 900000 900000 -856 -2009 3734 900000 965 900000 900000 5185 -291 2090 4442 5508 5885 6068 5030 3296 2120 900000 1565 5236 2199 5090 2750 -1039 2331 5550 608 -46 1368 2146 4424 1352 7179 286 2227 10 2118 -3325 -2721 7183 -423 1508 3271 -103 -747 3977 -1568 -1074 619 -6682 1832 2406 -843 -536 -5187 -36 -771 -1255 -6292 1011 -3092 1152 334 -4693 -6998 -7024 -3086 -4990 -3369 1467 -940 -958 121 1242 -1222 715 -4005 -2221 2255 6523 6880 3581 1599 424 3843 1697 2063 2141 5956 6223 3879 -819 187 -4221 3711 -4337 -2871 3656 -3240 2390 -2298 -5422 SS 20231225T134709.9Z 8759.574420 305 1 6.35 2 78.03 133.86 109.10 331.06 0.00 1 0.00 1 0 17 6.198e-01 3.234e-02 3.455e-01 2.138e-02 6.557191e-01 1.141674e-02 8.482341e-03 -6.000000e+00 3.522664e-01 223.39 -2.00 3.47 -2.00 320.85 0.00e+00 -4.773832e-03 4.802028e-03 7.509567e-03 -6.000000e+00 1.753835e-02 277.97 -2.00 20.00 -2.00 320.34 0.00e+00 4.674 0.002 302.00 328.00 3 3.8690e+00 3.5820e-02 6.8961e-02 -6.0000e+00 8.6897e-01 2.2368e-01 4.6368e-02 6.3147e-02 -6.0000e+00 9.4968e-01 -3.8969e-01 4.2779e-02 2.2485e-02 -6.0000e+00 5.6029e-01 1.7851e-01 2.0949e-02 6.8722e-03 -6.0000e+00 2.4321e-01 5.3215e-05 3.2805e-04 6.0186e-04 8.2673e-05 -6.0000e+00 1.7442e-02 2.3470e-03 0.0000e+00 12 9 9 12 1 1 999.00 18.43 0.32 0.00235 0.00481 1 3 1 5 0 3084.770 26.51 20.00 18.43 13.44 28.3 1018.78 900000 65210 -188556 900000 900000 900000 -144152 900000 -119723 -142779 900000 -177376 900000 -162221 900000 384625 1458 107963 114510 900000 -18901 44311 -29702 86142 272516 -16073 61871 31886 -10474 28964 101461 8354 26886 36007 38069 -3104 36323 45876 66818 6099 9867 90941 35001 40616 56658 51230 16311 13128 17774 48066 29219 1968 2823 16341 22547 11147 7988 7845 157298 11503 37610 12862 -8292 10272 2419 1165 3503 -2945 12135 -770 6092 7128 584 -5440 -5674 -6678 -1683 -7104 391 7449 -9728 -1106 -1493 -893 -1538 3417 -1099 -405 343 -1944 -531 1655 728 -5346 -1498 -2001 -1773 -1445 -2536 304 -3043 -866 -3246 -2007 -2648 -303 -1452 -389 3834 -1679 -1033 983 1021 28 1084 -2205 -2109 646 2123 3682 2872 2928 1079 782 -609 -541 -84 1965 1032 381 -522 581 -621 -1007 578 244 -289 -535 978 148 377 -1268 -2120 900000 1357 -9156 900000 900000 900000 -4237 900000 -3670 -5907 900000 -11324 900000 -12836 900000 8004 39 2247 2383 900000 -717 932 -1293 1793 5671 -798 1521 978 -446 883 2111 404 1248 1645 1630 -189 1679 2268 3316 637 1121 5192 3469 3843 4572 4366 1928 1628 2186 4707 3759 363 563 3117 4331 2490 1903 1873 9038 2477 6408 2970 -2604 3038 810 385 1118 -1024 3990 -325 2672 3235 280 -2616 -2522 -2701 -605 -2685 151 3143 -5532 -659 -976 -612 -1125 2539 -884 -332 281 -1573 -399 1153 494 -3895 -1158 -1759 -1755 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