File name: Pandora140s1_WashingtonDC_20240223_L2Fit_fout2c10d20200806p1-8.txt File generation date: 20240224T053122.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Luke Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 140 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora140_OF_v3d20200721.txt Instrument calibration file used: Pandora140s1_CF_v10d20200806.txt Level 1 file used: Pandora140s1_WashingtonDC_20240223_L1_smca1c10d20200806p1-8.txt Full location name: McMillan Reservoir Short location name: WashingtonDC Country of location: United States Location latitude [deg]: 38.9218 Location longitude [deg]: -77.0124 Location altitude [m]: 58 Local noon date: 20240223 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0548 305.1956 305.3364 305.4772 305.6179 305.7587 305.8994 306.0401 306.1808 306.3215 306.4622 306.6029 306.7436 306.8842 307.0249 307.1655 307.3061 307.4468 307.5874 307.7279 307.8685 308.0091 308.1496 308.2902 308.4307 308.5712 308.7118 308.8523 308.9927 309.1332 309.2737 309.4141 309.5546 309.6950 309.8354 309.9758 310.1162 310.2566 310.3970 310.5373 310.6777 310.8180 310.9584 311.0987 311.2390 311.3793 311.5196 311.6598 311.8001 311.9403 312.0806 312.2208 312.3610 312.5012 312.6414 312.7816 312.9218 313.0619 313.2021 313.3422 313.4823 313.6224 313.7625 313.9026 314.0427 314.1828 314.3228 314.4629 314.6029 314.7429 314.8829 315.0229 315.1629 315.3029 315.4428 315.5828 315.7227 315.8627 316.0026 316.1425 316.2824 316.4223 316.5621 316.7020 316.8418 316.9817 317.1215 317.2613 317.4011 317.5409 317.6807 317.8205 317.9602 318.1000 318.2397 318.3794 318.5191 318.6588 318.7985 318.9382 319.0779 319.2175 319.3572 319.4968 319.6364 319.7760 319.9156 320.0552 320.1948 320.3343 320.4739 320.6134 320.7529 320.8924 321.0319 321.1714 321.3109 321.4504 321.5898 321.7293 321.8687 322.0081 322.1476 322.2870 322.4263 322.5657 322.7051 322.8444 322.9838 323.1231 323.2624 323.4017 323.5410 323.6803 323.8196 323.9588 324.0981 324.2373 324.3765 324.5158 324.6550 324.7941 324.9333 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240223T192735.5Z 8819.810827 553 1 51.76 2 56.87 217.99 115.49 40.08 0.00 1 0.00 1 0 17 4.794e-02 1.885e-02 3.366e-02 5.813e-03 3.185382e-01 2.900367e-03 3.811498e-03 -6.000000e+00 2.703796e-02 225.41 -2.00 3.47 -2.00 318.44 0.00e+00 -4.059696e-03 5.540529e-04 5.371114e-04 -6.000000e+00 1.174842e-03 277.13 -2.00 20.00 -2.00 317.81 0.00e+00 1.824 0.000 302.00 328.00 3 6.3891e+00 7.8132e-03 2.4641e-02 -6.0000e+00 6.6963e-02 5.3106e-02 8.8958e-03 1.7659e-02 -6.0000e+00 7.2827e-02 6.9998e-03 5.9545e-03 8.1711e-03 -6.0000e+00 4.3320e-02 -1.4686e-02 3.1094e-03 4.3250e-03 -6.0000e+00 1.8512e-02 9.4722e-05 -5.2576e-05 1.6846e-04 3.7607e-05 -6.0000e+00 1.2706e-03 -1.1377e-02 1.3172e-04 12 8 8 10 0 0 99.98 18.40 0.40 -0.01138 -0.01177 15 3 1 5 0 3450.030 26.51 19.99 18.40 16.35 29.0 1011.37 -2516 14313 -13111 10737 -19091 -11030 19080 7852 11607 1837 233 321 11000 843 6906 -1114 -2988 -5056 -34 -2920 -6405 4254 -8781 7888 362 10445 6682 3456 6205 -428 2289 -3069 1557 -548 -2845 -7122 -2132 -4974 -928 3346 3132 3644 2814 4676 -1053 -825 16 -1905 -2970 -1387 1454 -41 852 -1370 2860 3638 2982 5929 -25119 2443 1422 2485 741 989 1455 582 187 -1327 -125 -44 1731 880 1777 917 1945 406 -310 -127 -1866 688 -1193 -97 -1024 -783 -717 442 -113 635 1687 912 763 1434 666 -443 -785 746 270 980 429 802 -1645 -956 -2272 -1895 -758 -465 -276 -396 -100 434 778 633 1139 322 -123 -48 -1429 -608 41 254 -129 -138 -77 267 116 -66 455 -833 -369 -864 -378 400 -441 -9 -237 372 40 698 292 452 61 -648 -169 -136 728 -898 563 -1187 -610 853 446 729 138 18 25 862 83 727 -141 -406 -728 -5 -448 -1045 626 -1511 1258 67 1858 1254 632 1015 -72 396 -606 321 -122 -613 -1539 -476 -1323 -287 1184 1238 1511 1210 1991 -469 -366 7 -820 -1275 -589 635 -20 430 -749 1573 2043 1732 3368 -18669 1375 819 1502 494 707 1056 400 120 -847 -82 -33 1399 752 1516 764 1508 289 -201 -78 -1192 480 -954 -85 -973 -775 -753 491 -132 764 2023 1071 839 1447 627 -404 -751 772 309 1234 581 1078 -2146 -1153 -2583 -2162 -924 -598 -369 -552 -145 667 1267 1058 1862 503 -179 -66 -1947 -849 61 396 -206 -218 -119 398 165 -90 593 -1085 -509 -1281 -590 641 -726 -15 -423 693 77 1355 574 871 114 -1177 -297 SS 20240223T193302.0Z 8819.814606 556 1 50.71 2 57.53 219.38 114.84 41.27 0.00 1 0.00 1 0 25 1.896e-02 5.733e-03 1.273e-02 2.450e-03 3.095416e-01 1.216997e-03 3.678496e-03 -6.000000e+00 1.068749e-02 225.41 -2.00 3.47 -2.00 318.33 0.00e+00 7.586982e-04 2.279643e-04 1.692501e-04 -6.000000e+00 4.644972e-04 277.13 -2.00 20.00 -2.00 317.70 0.00e+00 1.856 0.000 302.00 328.00 3 5.2207e+00 3.2649e-03 2.4231e-02 -6.0000e+00 2.6468e-02 1.8277e-02 3.7106e-03 1.5614e-02 -6.0000e+00 2.8793e-02 -5.7723e-03 2.4506e-03 7.8228e-03 -6.0000e+00 1.7126e-02 -1.8329e-03 1.2763e-03 2.3244e-03 -6.0000e+00 7.3143e-03 3.0091e-04 -3.4154e-04 7.0299e-05 2.4937e-05 -6.0000e+00 5.0263e-04 -9.9552e-03 2.8109e-05 10 0 0 10 0 0 99.47 18.40 0.10 -0.00996 -0.01252 26 5 1 5 0 1950.030 26.51 20.01 18.40 16.44 29.0 1011.98 -5519 -2482 -3285 5428 -5830 -7576 -9463 670 -3167 -2199 -4509 -8069 536 -386 -2892 -3282 -3964 2036 -456 1841 -1493 1302 -1630 785 -169 -190 1295 -298 -1100 -1956 1913 1467 1235 -1096 -1346 -1927 -3056 245 -379 29 -1121 526 -359 681 -353 158 53 -789 -696 -368 17 752 800 1228 1059 936 893 1153 -520 762 -201 1031 1455 1780 1363 60 -475 -981 10 428 742 1002 226 280 -327 -173 -1507 -1178 -2143 -757 -658 -917 -1693 -1232 -600 -798 -60 220 778 648 462 34 -267 -633 -376 -109 337 806 684 287 -592 -635 -1185 -764 -462 -549 -528 -427 -456 365 799 550 720 75 -580 -191 -411 -65 -32 101 22 322 45 443 408 226 231 500 121 270 517 256 -401 -113 -299 137 -98 71 44 252 -88 -476 -492 -335 -163 -227 331 -354 -444 -594 43 -234 -172 -361 -682 47 -40 -354 -452 -583 295 -71 292 -251 211 -277 139 -32 -37 254 -57 -197 -348 351 295 272 -260 -303 -420 -727 65 -120 11 -464 225 -160 306 -160 72 24 -352 -307 -162 8 373 419 676 607 548 533 688 -309 443 -121 650 992 1299 1015 43 -318 -644 7 324 615 865 198 237 -262 -126 -1018 -755 -1427 -556 -540 -829 -1644 -1239 -634 -899 -70 265 941 765 513 35 -258 -592 -366 -116 390 1021 923 387 -768 -771 -1356 -879 -569 -710 -709 -596 -664 558 1281 904 1161 115 -843 -262 -557 -91 -46 157 34 505 70 661 585 312 307 656 169 400 802 410 -655 -189 -525 251 -184 135 85 476 -161 -851 -861 SS 20240223T193808.3Z 8819.818152 559 1 51.00 2 58.17 220.66 114.21 42.37 0.00 1 0.00 1 0 25 1.841e-02 5.756e-03 1.111e-02 2.045e-03 3.134600e-01 1.016995e-03 3.730922e-03 -6.000000e+00 1.037624e-02 225.41 -2.00 3.47 -2.00 318.38 0.00e+00 3.979165e-04 1.935335e-04 1.799648e-04 -6.000000e+00 4.509754e-04 277.13 -2.00 20.00 -2.00 317.75 0.00e+00 1.889 0.000 302.00 328.00 3 4.8773e+00 2.7322e-03 2.4618e-02 -6.0000e+00 2.5697e-02 6.6687e-03 3.1076e-03 1.5837e-02 -6.0000e+00 2.7954e-02 2.0043e-05 2.0724e-03 7.9221e-03 -6.0000e+00 1.6628e-02 -3.9933e-03 1.0821e-03 2.2921e-03 -6.0000e+00 7.1012e-03 4.1067e-04 -4.3580e-04 5.8723e-05 2.5005e-05 -6.0000e+00 4.8801e-04 -9.9171e-03 2.5824e-05 10 0 0 10 0 0 99.51 18.41 0.25 -0.00992 -0.01319 41 8 1 5 0 1243.840 26.51 20.01 18.41 16.60 29.0 1012.91 -6126 -1418 -879 -7715 -1781 -5600 -1091 -8060 2162 -3418 -6080 -3989 -4329 1079 -2508 5974 -4173 1310 1125 -362 1374 1336 206 -2028 149 -139 878 -854 988 -2405 246 1082 -941 2264 -3800 -697 -4039 -1681 -1201 487 37 -1798 -59 -47 64 -682 258 -584 -870 -402 222 821 707 1002 343 1274 717 1301 102 274 1103 1221 2283 1633 1624 3 -224 -773 -247 -26 506 723 113 420 118 -258 -1085 -952 -1642 -572 -1030 -1157 -1317 -1353 -945 -751 23 70 482 491 422 225 -172 -131 -302 268 364 735 457 14 -110 -894 -1194 -1039 -363 -554 -492 -463 -135 626 464 1004 387 277 -393 -200 -404 -425 -161 -2 -169 192 611 110 459 -2 -22 193 65 463 146 676 -355 -33 -147 37 110 298 198 -142 -168 -580 -387 -354 -87 -56 -506 -99 -306 -60 -532 145 -260 -475 -312 -384 106 -294 724 -592 184 167 -57 217 210 33 -357 27 -26 169 -159 169 -419 45 213 -206 509 -856 -147 -949 -444 -377 177 15 -774 -26 -21 28 -306 114 -256 -378 -175 101 401 366 546 196 735 425 769 60 158 646 761 1529 1181 1196 2 -149 -503 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