File name: Pandora140s1_WashingtonDC_20240417_L2Fit_fout2c10d20200806p1-8.txt File generation date: 20240423T082008.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Luke Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 140 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora140_OF_v3d20200721.txt Instrument calibration file used: Pandora140s1_CF_v10d20200806.txt Level 1 file used: Pandora140s1_WashingtonDC_20240417_L1_smca1c10d20200806p1-8.txt Full location name: McMillan Reservoir Short location name: WashingtonDC Country of location: United States Location latitude [deg]: 38.9218 Location longitude [deg]: -77.0124 Location altitude [m]: 58 Local noon date: 20240417 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0548 305.1956 305.3364 305.4772 305.6179 305.7587 305.8994 306.0401 306.1808 306.3215 306.4622 306.6029 306.7436 306.8842 307.0249 307.1655 307.3061 307.4468 307.5874 307.7279 307.8685 308.0091 308.1496 308.2902 308.4307 308.5712 308.7118 308.8523 308.9927 309.1332 309.2737 309.4141 309.5546 309.6950 309.8354 309.9758 310.1162 310.2566 310.3970 310.5373 310.6777 310.8180 310.9584 311.0987 311.2390 311.3793 311.5196 311.6598 311.8001 311.9403 312.0806 312.2208 312.3610 312.5012 312.6414 312.7816 312.9218 313.0619 313.2021 313.3422 313.4823 313.6224 313.7625 313.9026 314.0427 314.1828 314.3228 314.4629 314.6029 314.7429 314.8829 315.0229 315.1629 315.3029 315.4428 315.5828 315.7227 315.8627 316.0026 316.1425 316.2824 316.4223 316.5621 316.7020 316.8418 316.9817 317.1215 317.2613 317.4011 317.5409 317.6807 317.8205 317.9602 318.1000 318.2397 318.3794 318.5191 318.6588 318.7985 318.9382 319.0779 319.2175 319.3572 319.4968 319.6364 319.7760 319.9156 320.0552 320.1948 320.3343 320.4739 320.6134 320.7529 320.8924 321.0319 321.1714 321.3109 321.4504 321.5898 321.7293 321.8687 322.0081 322.1476 322.2870 322.4263 322.5657 322.7051 322.8444 322.9838 323.1231 323.2624 323.4017 323.5410 323.6803 323.8196 323.9588 324.0981 324.2373 324.3765 324.5158 324.6550 324.7941 324.9333 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240417T111721.1Z 8873.470383 156 1 51.83 2 81.39 83.11 118.19 336.50 0.00 1 0.00 1 0 25 6.405e-01 4.461e-02 4.557e-01 3.440e-02 9.166888e-01 2.008336e-02 1.064389e-02 -6.000000e+00 3.777693e-01 229.02 -2.00 3.47 -2.00 322.01 0.00e+00 1.667709e-02 9.838787e-03 1.621435e-03 -6.000000e+00 1.746886e-02 281.72 -2.00 20.00 -2.00 321.53 0.00e+00 6.297 0.004 302.00 328.00 3 3.3384e+00 7.2217e-02 7.9524e-02 -6.0000e+00 9.4511e-01 1.3919e+00 8.4858e-02 5.1955e-02 -6.0000e+00 1.0310e+00 -1.7592e+00 5.8000e-02 2.4374e-02 -6.0000e+00 6.1104e-01 7.2218e-01 3.0651e-02 1.4963e-02 -6.0000e+00 2.5987e-01 1.0488e-05 -3.3318e-03 9.0734e-04 2.3333e-04 -6.0000e+00 1.7992e-02 -7.5482e-03 -1.9151e-06 12 9 8 11 8 0 96.52 18.52 1.09 -0.00755 -0.03258 15 3 1 5 0 3453.910 26.62 19.99 18.52 21.43 29.6 1004.39 900000 -43344 49598 900000 2964 -49256 160877 54593 91597 253856 -16398 -15688 900000 -46183 289835 21451 900000 -70565 900000 -50841 312417 52220 -4263 112864 -55160 900000 109152 148867 23572 900000 -57100 900000 -1345 -28811 900000 139362 900000 -76195 -2175 9285 162345 27747 76821 48189 15824 6350 39373 900000 11342 65835 68916 24787 93148 10569 136275 72648 140527 -13434 900000 -2158 89892 55634 10285 43673 49221 32308 33248 41264 -7081 41525 9625 13497 19457 14204 11956 -28292 -6029 -9361 7031 10794 18016 20218 486 -2166 -4826 419 -11957 2255 15563 -2357 12799 8040 5976 -17891 -363 -11335 5899 1977 -1292 1453 -8316 2688 -11020 -2690 -5700 -5347 -4771 -3070 -1170 -1720 1091 1508 7516 -3641 -770 -4097 -1008 -745 4200 -1298 -1683 2569 2481 3943 8829 4024 -1847 -1720 -2252 -1395 297 440 4319 157 265 -1613 2466 -707 -1281 327 -1007 -83 -1460 900000 -3494 1660 900000 113 -2595 5385 1827 3066 8497 -549 -525 900000 -2771 9701 1007 900000 -9299 900000 -5532 10457 1770 -229 3778 -4375 900000 3653 4983 789 900000 -4904 900000 -94 -2787 900000 4665 900000 -10394 -164 708 5434 1975 3479 2902 1287 569 2601 900000 1056 3819 4227 2557 5341 1414 5643 5545 5509 -2224 900000 -286 4929 4570 1481 5255 6127 4725 4787 5665 -1650 6894 2387 3329 4426 3143 2417 -7383 -1173 -1914 1386 2491 4634 5892 191 -921 -2213 193 -6436 1086 6606 -1153 5061 3117 2299 -8969 -175 -7212 3774 1549 -1181 1338 -8030 2109 -8677 -1853 -4268 -4232 -3956 -2704 -1125 -1908 1359 2067 10145 -5455 -1087 -5761 -1379 -1062 6028 -2045 -2620 3647 3352 5088 10489 4871 -2300 -2198 -3326 -2383 564 916 9265 373 673 -4411 6608 -1969 -3581 861 -2490 -188 -3136 SS 20240417T113050.2Z 8873.479748 161 1 50.37 2 78.77 85.18 119.17 339.78 0.00 1 0.00 1 0 25 4.861e-01 1.542e-02 2.276e-01 5.679e-03 7.731162e-01 3.207837e-03 8.404563e-03 -6.000000e+00 2.783378e-01 229.02 -2.00 3.47 -2.00 321.78 0.00e+00 -2.907876e-03 1.720821e-03 1.440730e-03 -6.000000e+00 1.299125e-02 281.72 -2.00 20.00 -2.00 321.27 0.00e+00 4.960 0.002 302.00 328.00 3 2.5036e+00 1.1899e-02 6.5325e-02 -6.0000e+00 6.9489e-01 2.3691e-01 1.6845e-02 4.4532e-02 -6.0000e+00 7.5430e-01 -4.7832e-01 1.6732e-02 2.2930e-02 -6.0000e+00 4.4730e-01 2.0240e-01 7.7228e-03 7.3233e-03 -6.0000e+00 1.9312e-01 1.4187e-04 -9.2405e-04 1.6207e-04 8.8269e-05 -6.0000e+00 1.3162e-02 -8.1821e-03 3.8669e-05 12 9 8 11 8 0 69.89 18.52 0.35 -0.00818 -0.01513 113 21 1 5 0 445.660 26.62 20.00 18.52 22.47 29.9 1012.32 900000 -240104 900000 -142969 900000 -97926 -163411 -30827 -207415 900000 -214942 -60651 -166386 -81346 -116776 -66676 -67926 -86505 -3915 -41453 75545 -40939 97135 -16887 -9866 -11258 -60165 39038 -57026 -6064 -42959 29881 1393 10658 3415 5404 3484 -5734 38311 -7433 40123 7521 24251 18880 6728 20736 4808 13799 16988 27210 10552 18236 6801 8606 16183 12241 20809 9563 19347 2971 14740 11501 8771 10092 7988 9459 2525 2649 -130 6984 5924 6732 3714 4772 2957 820 1914 -6010 -23 -2620 171 -2486 -2112 -2129 -1505 2084 -2782 758 -558 2541 1347 369 -262 -5018 -1449 -4046 -901 -1063 62 -1294 -915 -1835 -2345 -1823 -1672 -772 -2250 -75 -603 252 291 1188 698 -148 -107 -1024 -151 -696 358 443 274 966 574 1012 408 1135 242 353 366 999 725 384 -292 -693 113 76 112 233 357 215 -228 -336 -1644 900000 -5647 900000 -1439 900000 -542 -1891 -171 -4905 900000 -6380 -470 -4186 -1105 -2820 -1174 -1367 -2307 -49 -793 502 -783 538 -297 -179 -221 -1968 497 -1635 -110 -1340 541 39 300 100 150 107 -228 1214 -456 1756 451 1403 1168 428 1262 319 944 1188 1848 871 1581 731 1000 1881 1558 2534 1305 2302 400 1774 1549 1383 1801 1573 1819 518 566 -31 1823 1751 2080 1177 1411 810 204 436 -1497 -6 -845 64 -1104 -1045 -1123 -843 1205 -1638 444 -332 1539 771 200 -138 -2867 -899 -2785 -703 -965 62 -1333 -890 -1629 -1872 -1533 -1393 -677 -2110 -74 -660 310 406 1781 1076 -227 -157 -1441 -211 -1017 548 707 434 1454 834 1416 552 1475 332 459 541 1687 1370 789 -640 -1621 282 201 303 640 981 567 -563 -778 -3661 SS 20240417T113625.8Z 8873.483631 164 1 50.30 2 77.69 86.04 119.54 341.17 0.00 1 0.00 1 0 25 4.775e-01 9.391e-03 1.840e-01 4.031e-03 7.182280e-01 2.196529e-03 7.974877e-03 -6.000000e+00 2.728399e-01 229.02 -2.00 3.47 -2.00 321.54 0.00e+00 1.633277e-03 1.127958e-03 2.613178e-03 -6.000000e+00 1.202187e-02 281.72 -2.00 20.00 -2.00 321.02 0.00e+00 4.555 0.002 302.00 328.00 3 2.4504e+00 7.8507e-03 6.0620e-02 -6.0000e+00 6.8036e-01 8.9225e-02 1.1205e-02 4.1969e-02 -6.0000e+00 7.3763e-01 -2.0521e-01 1.1597e-02 2.2272e-02 -6.0000e+00 4.3900e-01 7.9093e-02 5.4176e-03 6.6917e-03 -6.0000e+00 1.8783e-01 2.2868e-04 -6.0602e-04 1.1170e-04 9.8531e-05 -6.0000e+00 1.2681e-02 -8.1823e-03 4.8188e-05 12 8 8 10 0 0 92.78 18.52 0.20 -0.00818 -0.01274 140 26 1 5 0 359.260 26.62 20.00 18.52 22.75 29.7 1014.29 -218616 900000 -201455 -94932 -169752 -119831 -167697 -69915 -102307 -161484 -155956 -173371 -44939 -85000 -76147 -62708 -7208 -61785 -73574 -5294 -64430 -12547 -40873 -4867 -27118 -22168 -34118 -14806 17925 -40317 23744 -27156 4592 -2741 7943 -31232 -9558 -2186 -13999 15250 1636 12122 5550 14425 6500 -2102 6815 8269 10659 -3630 7835 2631 8767 8913 9031 4717 7374 5611 -10671 4217 -2340 7673 3423 6798 4733 3403 2273 2549 3524 2188 5162 841 2654 1686 487 -1221 -3517 -1772 -4662 -682 -1012 0 -417 -679 -1092 -185 549 -734 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