File name: Pandora140s1_WashingtonDC_20240708_L2Fit_fout2c10d20200806p1-8.txt File generation date: 20240709T085847.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Luke Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 140 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora140_OF_v3d20200721.txt Instrument calibration file used: Pandora140s1_CF_v10d20200806.txt Level 1 file used: Pandora140s1_WashingtonDC_20240708_L1_smca1c10d20200806p1-8.txt Full location name: McMillan Reservoir Short location name: WashingtonDC Country of location: United States Location latitude [deg]: 38.9218 Location longitude [deg]: -77.0124 Location altitude [m]: 58 Local noon date: 20240708 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0548 305.1956 305.3364 305.4772 305.6179 305.7587 305.8994 306.0401 306.1808 306.3215 306.4622 306.6029 306.7436 306.8842 307.0249 307.1655 307.3061 307.4468 307.5874 307.7279 307.8685 308.0091 308.1496 308.2902 308.4307 308.5712 308.7118 308.8523 308.9927 309.1332 309.2737 309.4141 309.5546 309.6950 309.8354 309.9758 310.1162 310.2566 310.3970 310.5373 310.6777 310.8180 310.9584 311.0987 311.2390 311.3793 311.5196 311.6598 311.8001 311.9403 312.0806 312.2208 312.3610 312.5012 312.6414 312.7816 312.9218 313.0619 313.2021 313.3422 313.4823 313.6224 313.7625 313.9026 314.0427 314.1828 314.3228 314.4629 314.6029 314.7429 314.8829 315.0229 315.1629 315.3029 315.4428 315.5828 315.7227 315.8627 316.0026 316.1425 316.2824 316.4223 316.5621 316.7020 316.8418 316.9817 317.1215 317.2613 317.4011 317.5409 317.6807 317.8205 317.9602 318.1000 318.2397 318.3794 318.5191 318.6588 318.7985 318.9382 319.0779 319.2175 319.3572 319.4968 319.6364 319.7760 319.9156 320.0552 320.1948 320.3343 320.4739 320.6134 320.7529 320.8924 321.0319 321.1714 321.3109 321.4504 321.5898 321.7293 321.8687 322.0081 322.1476 322.2870 322.4263 322.5657 322.7051 322.8444 322.9838 323.1231 323.2624 323.4017 323.5410 323.6803 323.8196 323.9588 324.0981 324.2373 324.3765 324.5158 324.6550 324.7941 324.9333 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240708T110204.0Z 8955.459768 75 1 50.72 2 78.23 70.63 102.66 52.22 0.00 1 0.00 1 0 25 3.763e-01 1.048e-02 2.455e-01 7.128e-03 6.015225e-01 3.885223e-03 6.876713e-03 -6.000000e+00 2.183182e-01 232.72 -2.00 3.47 -2.00 321.25 0.00e+00 2.502193e-03 1.871645e-03 2.137686e-03 -6.000000e+00 1.000843e-02 289.83 -2.00 20.00 -2.00 320.59 0.00e+00 4.743 0.002 302.00 328.00 3 3.1765e+00 1.3677e-02 5.7810e-02 -6.0000e+00 5.4892e-01 6.3923e-02 1.8222e-02 3.4432e-02 -6.0000e+00 5.9295e-01 -1.1848e-01 1.6655e-02 1.7392e-02 -6.0000e+00 3.5228e-01 4.3557e-02 7.9867e-03 4.9658e-03 -6.0000e+00 1.4998e-01 1.0465e-04 -6.9246e-04 2.0758e-04 7.1085e-05 -6.0000e+00 1.0000e-02 -9.7284e-03 5.9165e-05 12 8 8 10 0 0 99.93 18.45 0.17 -0.00973 -0.01493 78 15 1 5 0 650.160 26.62 20.00 18.45 33.32 30.8 995.57 -189482 -173837 -69498 -170661 -116286 -143165 -20054 -62933 -124827 900000 -50242 35622 -49503 -42557 -20471 121342 -38408 -659 45938 -24727 6506 3747 -23938 -49431 3532 -15978 -9707 6910 -46825 31549 -18975 24038 8664 21113 563 3842 17968 -18616 11706 5191 9166 -2724 5614 -330 -1301 8696 3349 2540 477 8190 7334 5695 3131 -2989 1933 5753 5730 2492 7308 4747 3978 -4491 6539 4669 2654 2209 1920 5919 934 2553 850 1707 -695 1000 1033 -3863 1487 -3028 -2124 -1729 144 -965 -2745 -1990 -965 -229 112 1178 917 1021 141 -1054 -620 -1367 -1548 -203 939 -333 248 -567 -385 -676 -2147 -2049 -2280 -555 -2038 1044 -3 418 835 895 1125 133 134 -911 -1214 70 -335 37 420 415 979 385 -93 847 13 237 -615 764 -37 376 -51 -299 -54 92 253 -184 343 38 -275 -461 -324 -3737 -3479 -602 -3575 -1399 -2127 -139 -551 -2120 900000 -500 248 -646 -647 -314 843 -905 -12 613 -645 134 79 -664 -1855 89 -506 -300 181 -1905 679 -729 738 347 824 26 166 743 -1229 709 397 762 -271 543 -35 -140 875 360 282 56 942 934 821 503 -551 362 1083 1116 504 1382 906 783 -1038 1531 1249 768 628 535 1617 288 891 337 708 -296 401 384 -1360 460 -968 -730 -694 66 -511 -1628 -1241 -636 -161 82 890 701 760 100 -700 -391 -871 -1081 -160 840 -344 280 -654 -421 -681 -2000 -1890 -2270 -577 -2256 1195 -4 573 1260 1430 1809 209 199 -1307 -1744 103 -525 60 694 669 1520 583 -136 1188 17 327 -946 1293 -68 742 -105 -651 -125 223 632 -472 879 94 -657 -1051 -712 SS 20240708T110733.5Z 8955.463582 78 1 49.81 2 77.22 71.42 101.85 53.19 0.00 1 0.00 1 0 25 3.602e-01 1.749e-02 3.006e-01 1.267e-02 5.536531e-01 6.834525e-03 6.284071e-03 -6.000000e+00 2.104740e-01 232.72 -2.00 3.47 -2.00 320.91 0.00e+00 -2.523291e-03 2.886713e-03 1.466737e-03 -6.000000e+00 9.524622e-03 289.83 -2.00 20.00 -2.00 320.20 0.00e+00 4.396 0.001 302.00 328.00 3 4.4949e+00 2.2552e-02 5.3525e-02 -6.0000e+00 5.2778e-01 1.0652e-01 2.8859e-02 3.2438e-02 -6.0000e+00 5.6980e-01 -1.3550e-01 2.4702e-02 1.4587e-02 -6.0000e+00 3.3833e-01 5.7664e-02 1.2140e-02 5.6241e-03 -6.0000e+00 1.4370e-01 4.0143e-05 -1.2157e-03 3.7036e-04 4.9803e-05 -6.0000e+00 9.7652e-03 -1.1681e-02 1.1019e-04 12 8 8 10 0 0 98.39 18.46 0.25 -0.01168 -0.02082 17 3 1 5 0 2929.340 26.62 20.00 18.46 33.30 30.8 995.59 -17513 -175666 -129879 -68924 900000 -11007 900000 -13327 210071 -49294 -118333 -3811 -102774 18917 -56053 34185 -5756 4504 -36231 -53881 23850 -2317 87912 -68590 6132 -22868 17984 -6723 -47036 123302 -21784 25459 6304 -23144 16322 23031 6605 39486 22888 6946 20167 -4663 48897 -5924 18562 -4378 -1064 3025 -3916 -3235 -4378 11003 2457 11885 10896 15237 3285 7064 -4406 -1424 14552 4962 6893 10363 4204 657 2432 4414 -3388 -1493 -1065 5290 1089 7005 363 -2875 2645 -2256 -1077 -5722 -911 -3417 -1729 886 -1283 -2493 -3037 1619 1142 1184 -1289 -517 -1771 670 -1406 1015 -1434 -533 2005 162 -258 -2436 -2673 -2305 -2663 -516 372 -1061 -231 393 1109 -968 576 1542 -2169 549 -1650 120 344 -202 1429 1458 -232 2195 918 -513 281 1240 -302 877 -783 1356 167 -111 387 133 -321 -44 -349 310 393 -983 -1042 -216 -6228 -3268 -991 900000 -136 900000 -165 2595 -815 -3776 -47 -3542 263 -1814 571 -151 116 -1444 -2652 602 -74 1302 -4577 226 -1168 653 -295 -2824 1615 -1175 1021 341 -1783 849 1093 394 2028 1658 704 2050 -642 4254 -880 2190 -649 -154 425 -602 -515 -768 1856 489 2341 2314 3244 815 1708 -1161 -356 3163 1268 1926 3121 1420 223 785 1410 -1248 -620 -494 2443 527 3083 158 -1167 932 -813 -409 -2634 -465 -2032 -1114 590 -931 -1965 -2536 1341 960 969 -1012 -375 -1231 451 -1043 835 -1373 -576 2318 193 -295 -2612 -2623 -2229 -2785 -562 421 -1290 -299 554 1707 -1607 948 2430 -3343 781 -2376 177 534 -334 2348 2341 -367 3293 1335 -730 381 1673 -453 1443 -1421 2561 333 -231 855 311 -775 -108 -867 746 899 -2171 -2219 SS 20240708T111249.1Z 8955.467235 81 1 50.06 2 76.24 72.17 101.06 54.11 0.00 1 0.00 1 0 25 2.752e-01 9.015e-03 1.516e-01 5.537e-03 5.370277e-01 2.950055e-03 6.129470e-03 -6.000000e+00 1.595337e-01 232.72 -2.00 3.47 -2.00 320.74 0.00e+00 -8.105960e-05 1.204152e-03 8.188521e-04 -6.000000e+00 7.113741e-03 289.83 -2.00 20.00 -2.00 320.02 0.00e+00 4.106 0.001 302.00 328.00 3 3.7094e+00 9.5524e-03 5.0024e-02 -6.0000e+00 4.0032e-01 6.8511e-02 1.2180e-02 2.9123e-02 -6.0000e+00 4.3211e-01 -8.3183e-02 1.0581e-02 1.4194e-02 -6.0000e+00 2.5747e-01 2.8305e-02 5.2411e-03 3.9705e-03 -6.0000e+00 1.0962e-01 1.1824e-04 -9.3308e-04 1.6127e-04 4.5752e-05 -6.0000e+00 7.3112e-03 -1.1000e-02 5.7149e-05 11 8 0 10 0 0 99.89 18.46 0.16 -0.01100 -0.01801 37 7 1 5 0 1352.660 26.62 19.99 18.46 33.27 30.8 995.59 -113194 -111610 129133 -111824 -48069 -71552 -96058 -47927 9350 -80173 -115562 -15850 -51470 -26767 -26854 -445 -37702 -4821 14546 -12273 18457 -10795 -27828 -8902 -5300 27114 -5779 -300 16429 -9755 -12397 10164 1085 16329 -5413 -1341 -10557 624 -1951 6864 4066 4447 -1972 6838 6150 -3191 4087 -916 1149 4313 3060 4477 3613 3618 -96 4408 751 4330 244 869 -157 2295 2959 2342 1922 1676 554 -458 -407 1491 2784 1025 497 823 -1349 1082 -3265 -1857 -4086 -2527 -2822 -931 -1109 -2378 -295 -266 -150 10 964 1372 -59 -473 1404 -987 -1251 -142 -116 655 844 -558 -244 -832 -1416 -1398 -916 -915 -1447 2 -406 769 455 1126 478 847 -247 -532 -681 -179 15 326 191 171 -314 166 151 842 597 -53 595 254 33 551 -598 136 -459 2 -62 496 -136 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