File name: Pandora140s1_WashingtonDC_20240816_L2Fit_fout2c10d20200806p1-8.txt File generation date: 20240817T053223.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Luke Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 140 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora140_OF_v3d20200721.txt Instrument calibration file used: Pandora140s1_CF_v10d20200806.txt Level 1 file used: Pandora140s1_WashingtonDC_20240816_L1_smca1c10d20200806p1-8.txt Full location name: McMillan Reservoir Short location name: WashingtonDC Country of location: United States Location latitude [deg]: 38.9218 Location longitude [deg]: -77.0124 Location altitude [m]: 58 Local noon date: 20240816 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0548 305.1956 305.3364 305.4772 305.6179 305.7587 305.8994 306.0401 306.1808 306.3215 306.4622 306.6029 306.7436 306.8842 307.0249 307.1655 307.3061 307.4468 307.5874 307.7279 307.8685 308.0091 308.1496 308.2902 308.4307 308.5712 308.7118 308.8523 308.9927 309.1332 309.2737 309.4141 309.5546 309.6950 309.8354 309.9758 310.1162 310.2566 310.3970 310.5373 310.6777 310.8180 310.9584 311.0987 311.2390 311.3793 311.5196 311.6598 311.8001 311.9403 312.0806 312.2208 312.3610 312.5012 312.6414 312.7816 312.9218 313.0619 313.2021 313.3422 313.4823 313.6224 313.7625 313.9026 314.0427 314.1828 314.3228 314.4629 314.6029 314.7429 314.8829 315.0229 315.1629 315.3029 315.4428 315.5828 315.7227 315.8627 316.0026 316.1425 316.2824 316.4223 316.5621 316.7020 316.8418 316.9817 317.1215 317.2613 317.4011 317.5409 317.6807 317.8205 317.9602 318.1000 318.2397 318.3794 318.5191 318.6588 318.7985 318.9382 319.0779 319.2175 319.3572 319.4968 319.6364 319.7760 319.9156 320.0552 320.1948 320.3343 320.4739 320.6134 320.7529 320.8924 321.0319 321.1714 321.3109 321.4504 321.5898 321.7293 321.8687 322.0081 322.1476 322.2870 322.4263 322.5657 322.7051 322.8444 322.9838 323.1231 323.2624 323.4017 323.5410 323.6803 323.8196 323.9588 324.0981 324.2373 324.3765 324.5158 324.6550 324.7941 324.9333 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240816T111729.6Z 8994.470482 98 1 50.26 2 80.58 80.22 143.23 273.22 0.00 1 0.00 1 0 17 5.780e-01 2.796e-02 3.731e-01 1.856e-02 6.991249e-01 1.025255e-02 8.307958e-03 -6.000000e+00 3.358107e-01 231.52 -2.00 3.47 -2.00 321.58 0.00e+00 5.934544e-03 5.086692e-03 4.543749e-03 -6.000000e+00 1.524223e-02 291.02 -2.00 20.00 -2.00 320.96 0.00e+00 5.807 0.003 302.00 328.00 3 3.4472e+00 3.7336e-02 7.1466e-02 -6.0000e+00 8.4122e-01 5.9934e-01 4.7540e-02 4.4541e-02 -6.0000e+00 9.0991e-01 -8.0710e-01 3.6850e-02 2.1194e-02 -6.0000e+00 5.4295e-01 3.3723e-01 1.7956e-02 5.6518e-03 -6.0000e+00 2.3157e-01 2.3822e-05 -1.5515e-03 5.2007e-04 1.1417e-04 -6.0000e+00 1.5370e-02 -1.1749e-02 8.2995e-05 12 8 8 10 0 0 45.78 18.50 0.42 -0.01175 -0.02341 16 3 1 5 0 3140.860 26.73 20.01 18.50 29.04 30.7 997.44 -89589 78021 900000 94020 -121547 -145465 -64734 -127628 98534 -92412 22821 206609 34819 75578 41599 453601 -93086 900000 52679 -32628 -89829 40699 -7939 -14723 14559 -48490 3451 -61496 55619 19710 -6094 53348 1386 23111 25568 88808 19436 133358 -24548 62539 -22420 16292 16080 17973 49537 12586 23393 1385 83668 24589 16536 26754 19706 958 23986 73688 12382 53859 13556 23349 8990 8500 19681 18222 19251 1510 5751 -6321 -4362 9977 1312 6385 6007 7057 2616 1882 -5934 1058 -4119 9430 3101 -3643 732 -3214 365 -828 1339 -6731 5639 5307 -3523 -823 -5654 -1439 -9149 1971 -2473 533 766 -906 -968 -923 -6835 -7419 -589 -3604 -1891 -1421 -1531 -303 -870 -747 1053 1139 -1097 63 -578 -1368 1600 1055 1539 1220 1748 359 4254 2575 626 2525 -2374 2097 -205 1980 -439 1365 -652 526 -966 -643 873 -827 -62 -1777 -108 -2520 1411 900000 1701 -4543 -6199 -1305 -4857 1782 -2786 413 3737 630 1367 752 8205 -7004 900000 1157 -1614 -7509 975 -296 -608 472 -2865 126 -3914 1141 587 -268 1581 76 1110 1143 2085 913 2454 -2299 3060 -2685 1436 1471 1644 3375 1222 2074 154 4471 2378 1879 3060 2603 162 3440 6809 2072 6058 2144 3266 1454 1488 3485 3691 4134 378 1353 -1700 -1235 2815 448 2178 2047 2257 800 519 -1622 269 -1205 2868 1178 -1695 362 -1750 204 -500 831 -4672 3501 3219 -2181 -464 -3203 -792 -5997 1346 -2046 496 789 -971 -989 -862 -6088 -6486 -517 -3465 -1883 -1508 -1774 -388 -1259 -1162 1647 1742 -1636 88 -819 -2035 2452 1711 2488 1914 2630 532 5838 3480 833 3350 -3696 3543 -391 3983 -952 3070 -1596 1346 -2572 -1735 2336 -2175 -153 -4192 -240 SS 20240816T113124.3Z 8994.480142 106 1 50.51 2 77.90 82.33 145.77 275.61 0.00 1 0.00 1 0 17 5.137e-01 1.728e-02 3.463e-01 1.252e-02 5.939387e-01 6.772871e-03 6.682988e-03 -6.000000e+00 2.964787e-01 231.52 -2.00 3.47 -2.00 321.14 0.00e+00 -3.999564e-03 3.172433e-03 1.129179e-03 -6.000000e+00 1.400694e-02 291.02 -2.00 20.00 -2.00 320.46 0.00e+00 4.626 0.002 302.00 328.00 3 4.2205e+00 2.3448e-02 5.6295e-02 -6.0000e+00 7.4172e-01 1.0791e-01 3.0758e-02 3.3932e-02 -6.0000e+00 8.0155e-01 -2.0699e-01 2.6643e-02 1.5810e-02 -6.0000e+00 4.7808e-01 9.7276e-02 1.2858e-02 6.3903e-03 -6.0000e+00 2.0484e-01 4.1853e-05 -6.8830e-04 3.6332e-04 5.9810e-05 -6.0000e+00 1.3769e-02 -9.9583e-03 1.0130e-05 12 8 8 10 0 0 99.86 18.48 0.25 -0.00996 -0.01513 26 5 1 5 0 1942.160 26.62 20.00 18.48 29.24 30.7 998.81 -184906 -78033 -24106 -29992 16130 -84136 -96237 -126847 -102473 -114709 900000 -126664 -6430 -96157 -61647 45318 75724 12995 -29645 131222 -25681 185252 -7904 -24765 41630 34743 -58119 -4635 177995 -19543 237565 21410 22758 -23093 6979 5396 -28760 23228 8414 22967 -438 30955 4121 8717 -516 11250 3462 -19682 18070 -14684 15719 7740 10494 7389 6531 10918 -3012 13198 255810 13752 2522 951 8933 1372 5342 974 6361 1460 410 616 1730 3753 112 1440 485 -808 -8022 2244 -3355 -301 -4150 -1590 -416 -3248 770 -568 1790 -836 3476 1410 2722 -1181 230 -564 -2205 -2767 503 722 -479 -315 -1777 128 -3638 -4133 -2513 -1855 1971 -1548 254 -752 925 129 -223 299 -593 290 -563 -281 -397 1495 977 1400 35 -294 476 130 1915 548 743 1129 -650 1572 -929 334 -324 287 65 215 -211 -405 686 -834 -1100 -5424 -1005 -294 -366 197 -1058 -1468 -2913 -2169 -2972 900000 -4067 -83 -3302 -1852 606 924 274 -974 1602 -877 2262 -242 -973 991 937 -3683 -175 2173 -811 2900 793 943 -1559 347 266 -2099 1237 622 1787 -48 2706 480 988 -64 1254 416 -2981 1985 -2292 2027 1198 1724 1355 1291 2169 -710 2693 5605 2649 547 225 2186 403 1594 295 1782 437 134 231 717 1610 50 607 191 -290 -2844 711 -1210 -123 -2047 -872 -249 -2115 516 -414 1340 -665 2672 1075 1917 -806 148 -366 -1589 -2287 461 751 -553 -367 -1991 130 -3480 -3948 -2551 -1986 2135 -1843 321 -1057 1411 211 -368 474 -899 415 -808 -419 -626 2441 1611 2241 55 -449 693 184 2560 751 1124 1893 -1208 3041 -1918 715 -745 694 160 543 -538 -1002 1596 -1871 -2385 SS 20240816T113633.4Z 8994.483720 109 1 13.05 2 76.91 83.11 146.72 276.54 0.00 1 0.00 1 0 25 3.843e-01 1.843e-02 3.005e-01 1.325e-02 5.558660e-01 6.982959e-03 6.457299e-03 -6.000000e+00 2.215458e-01 231.52 -2.00 3.47 -2.00 320.62 0.00e+00 2.297636e-03 2.766923e-03 1.212785e-03 -6.000000e+00 9.988455e-03 291.02 -2.00 20.00 -2.00 319.88 0.00e+00 4.300 0.001 302.00 328.00 3 4.2457e+00 2.2261e-02 5.2027e-02 -6.0000e+00 5.5398e-01 1.2800e-01 2.8074e-02 2.9928e-02 -6.0000e+00 5.9871e-01 -1.7606e-01 2.3693e-02 1.4824e-02 -6.0000e+00 3.5734e-01 7.4684e-02 1.1858e-02 4.1919e-03 -6.0000e+00 1.5250e-01 5.5801e-05 -2.3351e-03 3.7377e-04 5.3596e-05 -6.0000e+00 1.0216e-02 -9.5310e-03 -2.7720e-04 12 9 9 12 1 1 -2604.22 18.48 0.32 -0.00953 -0.02708 3 3 1 5 0 3258.270 26.62 20.00 18.48 29.22 30.7 998.76 -184010 -132667 -73490 -49011 7075 -143580 -41013 -49618 -125251 -108205 -82101 -48898 47725 87899 3741 1243 9809 194678 44872 25752 -35084 33744 142592 -1447 27951 4501 22195 22352 -11102 25696 -11009 -103 -7560 8452 -14483 21288 -12532 20835 3745 -5903 9106 7585 11602 13559 21393 -5678 -17301 2154 5144 3682 -2008 13925 19670 9459 12474 -660 -4203 762 912 2227 1093 8166 6531 -1740 13158 -302 -3428 418 5612 3552 3855 2016 2710 3009 1755 -120 374 -3521 -5489 -485 -5856 -4200 -1713 -3532 -133 -4210 -38 101 -350 731 -454 515 -3511 -271 -2417 2323 247 2208 -504 385 442 -3352 -862 333 -1977 -885 -528 -264 -1942 -959 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