File name: Pandora140s1_WashingtonDC_20240918_L2Fit_fout2c10d20200806p1-8.txt File generation date: 20240919T051754.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Luke Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 140 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora140_OF_v3d20200721.txt Instrument calibration file used: Pandora140s1_CF_v10d20200806.txt Level 1 file used: Pandora140s1_WashingtonDC_20240918_L1_smca1c10d20200806p1-8.txt Full location name: McMillan Reservoir Short location name: WashingtonDC Country of location: United States Location latitude [deg]: 38.9218 Location longitude [deg]: -77.0124 Location altitude [m]: 58 Local noon date: 20240918 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0548 305.1956 305.3364 305.4772 305.6179 305.7587 305.8994 306.0401 306.1808 306.3215 306.4622 306.6029 306.7436 306.8842 307.0249 307.1655 307.3061 307.4468 307.5874 307.7279 307.8685 308.0091 308.1496 308.2902 308.4307 308.5712 308.7118 308.8523 308.9927 309.1332 309.2737 309.4141 309.5546 309.6950 309.8354 309.9758 310.1162 310.2566 310.3970 310.5373 310.6777 310.8180 310.9584 311.0987 311.2390 311.3793 311.5196 311.6598 311.8001 311.9403 312.0806 312.2208 312.3610 312.5012 312.6414 312.7816 312.9218 313.0619 313.2021 313.3422 313.4823 313.6224 313.7625 313.9026 314.0427 314.1828 314.3228 314.4629 314.6029 314.7429 314.8829 315.0229 315.1629 315.3029 315.4428 315.5828 315.7227 315.8627 316.0026 316.1425 316.2824 316.4223 316.5621 316.7020 316.8418 316.9817 317.1215 317.2613 317.4011 317.5409 317.6807 317.8205 317.9602 318.1000 318.2397 318.3794 318.5191 318.6588 318.7985 318.9382 319.0779 319.2175 319.3572 319.4968 319.6364 319.7760 319.9156 320.0552 320.1948 320.3343 320.4739 320.6134 320.7529 320.8924 321.0319 321.1714 321.3109 321.4504 321.5898 321.7293 321.8687 322.0081 322.1476 322.2870 322.4263 322.5657 322.7051 322.8444 322.9838 323.1231 323.2624 323.4017 323.5410 323.6803 323.8196 323.9588 324.0981 324.2373 324.3765 324.5158 324.6550 324.7941 324.9333 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240918T142949.5Z 9027.604045 239 1 18.03 2 51.01 127.57 123.77 303.24 0.00 1 0.00 1 0 17 1.020e-02 6.967e-03 6.363e-03 2.946e-03 2.136427e-01 1.491171e-03 2.547423e-03 -6.000000e+00 5.824981e-03 228.88 -2.00 3.47 -2.00 316.37 0.00e+00 2.591942e-04 1.738999e-04 1.209750e-04 -6.000000e+00 2.620325e-04 288.49 -2.00 20.00 -2.00 315.57 0.00e+00 1.586 0.000 302.00 328.00 3 5.3636e+00 3.8906e-03 1.9190e-02 -6.0000e+00 1.4486e-02 2.9916e-02 4.3517e-03 1.0882e-02 -6.0000e+00 1.5689e-02 1.1972e-03 2.5210e-03 5.3143e-03 -6.0000e+00 9.3704e-03 -4.1780e-03 1.1890e-03 1.4759e-03 -6.0000e+00 4.0140e-03 3.9955e-04 -3.8094e-05 8.2789e-05 1.7209e-05 -6.0000e+00 2.7070e-04 -6.8371e-03 6.4210e-05 12 9 1 12 1 1 99.70 18.78 0.27 -0.00684 -0.00712 6 4 1 5 0 2574.500 26.94 19.46 18.78 24.42 35.5 1013.02 -1795 -764 986 -1494 -4116 -755 -4332 954 -65 1227 -149 -1942 757 199 863 237 -789 -681 813 739 1210 830 -131 1225 -434 178 -232 387 -1323 115 340 2254 1806 -244 -2033 -2303 -1937 -1673 -449 112 271 -78 -933 -230 55 104 -1093 -183 -816 -623 -90 303 920 749 472 784 233 1014 -1083 429 590 1098 1704 1911 1122 72 -888 -1043 -122 440 1066 680 1125 223 544 320 -1346 -2558 -1079 -764 -1185 -927 -1832 -1507 -1203 -720 330 689 946 666 426 0 -937 -718 -338 301 191 676 911 -115 -271 -553 -1284 -716 -915 -1071 -286 -389 -117 442 620 445 607 212 -481 -220 26 168 417 335 -219 268 171 612 250 462 236 315 354 455 -75 335 -551 -295 -185 44 -73 464 -18 362 -134 -599 -789 -323 -148 193 -283 -711 -120 -742 172 -13 258 -31 -414 172 51 245 73 -255 -225 274 257 427 291 -47 454 -169 72 -94 148 -479 40 122 841 721 -103 -818 -896 -805 -781 -241 68 177 -53 -651 -161 38 72 -755 -122 -537 -406 -61 214 672 569 368 618 187 810 -866 337 472 919 1505 1766 1045 64 -743 -848 -102 398 1034 685 1135 222 516 283 -1111 -2023 -856 -656 -1111 -931 -1942 -1642 -1370 -860 406 867 1197 828 504 1 -984 -724 -349 330 224 849 1194 -151 -342 -666 -1485 -837 -1137 -1387 -379 -532 -164 641 930 675 901 302 -648 -282 33 218 565 478 -320 390 245 854 338 604 298 394 460 616 -105 477 -797 -434 -282 70 -117 756 -30 588 -214 -941 -1221 SS 20240918T143418.3Z 9027.607157 242 1 50.48 2 50.33 128.72 124.44 304.24 0.00 1 0.00 1 0 17 8.204e-03 5.256e-03 9.185e-04 3.966e-04 2.076059e-01 1.996556e-04 2.482339e-03 -6.000000e+00 4.685833e-03 228.88 -2.00 3.47 -2.00 316.62 0.00e+00 2.661021e-04 2.462267e-05 7.573547e-05 -6.000000e+00 2.108415e-04 288.49 -2.00 20.00 -2.00 315.80 0.00e+00 1.563 0.000 302.00 328.00 3 2.4233e+00 5.2288e-04 1.8843e-02 -6.0000e+00 1.1653e-02 9.0776e-03 5.8653e-04 1.0615e-02 -6.0000e+00 1.2621e-02 -4.9704e-04 3.4080e-04 5.1886e-03 -6.0000e+00 7.5384e-03 -3.0571e-03 1.6178e-04 1.4457e-03 -6.0000e+00 3.2283e-03 7.8992e-03 -1.0024e-04 1.1179e-05 1.6528e-05 -6.0000e+00 2.1783e-04 -5.8741e-03 3.4584e-05 10 0 0 10 0 0 99.97 18.66 0.19 -0.00587 -0.00663 553 105 1 5 0 91.270 26.83 20.07 18.66 26.17 33.9 1019.85 -816 -1104 -613 -2156 -3033 -2709 -2157 65 494 134 -1346 -1295 -1120 -677 294 165 291 71 777 667 1032 391 706 298 230 427 296 -30 -542 94 466 990 1154 145 -1842 -2422 -2245 -1451 -335 -258 -363 -459 -502 -536 -349 -82 -479 -311 -708 -297 289 740 957 913 726 782 930 728 615 563 690 1134 1584 1682 908 62 -617 -816 -325 331 466 301 93 165 72 -316 -656 -1279 -1127 -840 -717 -979 -1535 -1435 -993 -548 -294 121 324 366 229 59 -195 -294 34 132 483 759 432 134 -197 -648 -930 -427 -530 -398 -507 -449 -164 217 567 514 369 91 -168 -197 -181 -16 61 266 -31 172 137 337 400 381 271 350 433 410 328 163 -207 -131 -103 15 19 134 64 -95 -221 -364 -617 -135 -200 -113 -379 -472 -395 -328 11 90 26 -261 -250 -237 -161 78 48 88 22 247 219 345 129 236 105 85 163 114 -11 -181 30 155 348 434 57 -690 -875 -876 -647 -177 -146 -226 -298 -335 -362 -234 -54 -313 -196 -435 -180 181 493 668 671 551 601 727 569 472 429 538 940 1413 1474 802 55 -504 -640 -264 302 432 294 92 157 69 -277 -517 -945 -847 -702 -671 -936 -1579 -1538 -1132 -670 -352 150 403 441 276 65 -195 -301 34 142 570 990 561 172 -258 -789 -1064 -496 -674 -499 -662 -615 -234 326 892 767 569 131 -221 -259 -235 -21 82 382 -46 255 199 470 566 514 346 440 575 581 453 232 -300 -195 -162 25 30 220 107 -154 -374 -597 -986 SS 20240918T145145.9Z 9027.619281 254 1 15.33 2 47.77 133.40 126.99 308.31 0.00 1 0.00 1 0 17 1.271e-02 7.649e-03 7.230e-03 3.605e-03 2.028628e-01 1.826043e-03 2.409608e-03 -6.000000e+00 7.258177e-03 228.87 -2.00 3.47 -2.00 316.16 0.00e+00 3.890438e-04 2.029632e-04 1.103425e-04 -6.000000e+00 3.266242e-04 288.49 -2.00 20.00 -2.00 315.38 0.00e+00 1.485 0.000 302.00 328.00 3 5.6437e+00 4.7510e-03 1.8036e-02 -6.0000e+00 1.8049e-02 3.2720e-02 5.3084e-03 1.0288e-02 -6.0000e+00 1.9551e-02 -1.4877e-03 3.0629e-03 5.0230e-03 -6.0000e+00 1.1677e-02 -1.6363e-03 1.4290e-03 1.3970e-03 -6.0000e+00 5.0003e-03 3.3933e-04 -2.8782e-04 1.0120e-04 1.6354e-05 -6.0000e+00 3.3745e-04 -6.5073e-03 -1.3267e-05 12 9 1 12 9 1 90.27 18.46 0.21 -0.00651 -0.00867 4 3 1 5 0 3065.220 26.62 20.01 18.46 29.08 32.0 1032.16 -3243 1840 -745 -1849 -4644 -4222 -431 -399 3756 -530 -137 -4765 45 565 893 1725 797 1549 1191 1587 12 1791 704 1353 -1188 758 1295 -1310 -561 -161 1681 238 365 -495 -2534 -2872 -3268 -667 -1289 27 -1556 706 -944 -490 669 -149 -735 -1571 -1535 -200 352 395 889 1620 685 1081 -135 355 1157 959 875 1482 1785 1906 946 -116 34 -1876 -239 13 1132 502 539 1009 -656 -499 -1437 -2261 -2388 -789 -1359 -809 -1407 -1666 -585 -181 591 329 593 759 901 -397 -758 -726 -701 -19 -220 796 451 744 -432 -246 -1257 -1390 -362 -416 -261 -394 18 865 416 845 554 -9 -406 180 -499 -304 -179 617 132 457 526 285 393 -190 -45 -297 312 148 142 -201 -563 -304 3 143 331 423 229 177 -130 -739 -564 -663 389 -165 -390 -893 -765 -79 -80 805 -124 -31 -1138 11 156 274 568 273 538 429 585 5 665 267 532 -495 321 548 -538 -213 -59 630 95 155 -218 -1068 -1173 -1433 -322 -723 17 -1068 492 -680 -355 478 -107 -522 -1096 -1046 -133 242 285 665 1249 545 867 -110 291 927 765 712 1260 1604 1791 895 -104 29 -1551 -201 12 1108 510 552 1007 -634 -447 -1196 -1798 -1925 -682 -1282 -815 -1493 -1824 -665 -216 728 416 754 946 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