File name: Pandora140s1_WashingtonDC_20240928_L2Fit_fout2c10d20200806p1-8.txt File generation date: 20240929T050933.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Luke Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 140 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora140_OF_v3d20200721.txt Instrument calibration file used: Pandora140s1_CF_v10d20200806.txt Level 1 file used: Pandora140s1_WashingtonDC_20240928_L1_smca1c10d20200806p1-8.txt Full location name: McMillan Reservoir Short location name: WashingtonDC Country of location: United States Location latitude [deg]: 38.9218 Location longitude [deg]: -77.0124 Location altitude [m]: 58 Local noon date: 20240928 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0548 305.1956 305.3364 305.4772 305.6179 305.7587 305.8994 306.0401 306.1808 306.3215 306.4622 306.6029 306.7436 306.8842 307.0249 307.1655 307.3061 307.4468 307.5874 307.7279 307.8685 308.0091 308.1496 308.2902 308.4307 308.5712 308.7118 308.8523 308.9927 309.1332 309.2737 309.4141 309.5546 309.6950 309.8354 309.9758 310.1162 310.2566 310.3970 310.5373 310.6777 310.8180 310.9584 311.0987 311.2390 311.3793 311.5196 311.6598 311.8001 311.9403 312.0806 312.2208 312.3610 312.5012 312.6414 312.7816 312.9218 313.0619 313.2021 313.3422 313.4823 313.6224 313.7625 313.9026 314.0427 314.1828 314.3228 314.4629 314.6029 314.7429 314.8829 315.0229 315.1629 315.3029 315.4428 315.5828 315.7227 315.8627 316.0026 316.1425 316.2824 316.4223 316.5621 316.7020 316.8418 316.9817 317.1215 317.2613 317.4011 317.5409 317.6807 317.8205 317.9602 318.1000 318.2397 318.3794 318.5191 318.6588 318.7985 318.9382 319.0779 319.2175 319.3572 319.4968 319.6364 319.7760 319.9156 320.0552 320.1948 320.3343 320.4739 320.6134 320.7529 320.8924 321.0319 321.1714 321.3109 321.4504 321.5898 321.7293 321.8687 322.0081 322.1476 322.2870 322.4263 322.5657 322.7051 322.8444 322.9838 323.1231 323.2624 323.4017 323.5410 323.6803 323.8196 323.9588 324.0981 324.2373 324.3765 324.5158 324.6550 324.7941 324.9333 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240928T130515.2Z 9037.545314 227 1 5.32 2 67.51 113.03 25.13 140.63 0.00 1 0.00 1 0 17 2.933e-02 8.347e-03 2.439e-02 5.908e-03 3.028586e-01 2.964468e-03 3.555529e-03 -6.000000e+00 1.669754e-02 227.86 -2.00 3.47 -2.00 317.77 0.00e+00 2.568229e-04 4.942732e-04 1.396131e-04 -6.000000e+00 7.501018e-04 287.33 -2.00 20.00 -2.00 316.95 0.00e+00 2.592 0.000 302.00 328.00 3 4.3748e+00 7.9090e-03 2.9978e-02 -6.0000e+00 4.1442e-02 2.5125e-02 8.9539e-03 1.5469e-02 -6.0000e+00 4.4919e-02 5.8360e-03 5.5817e-03 7.5535e-03 -6.0000e+00 2.6833e-02 -7.2502e-03 2.8468e-03 2.1212e-03 -6.0000e+00 1.1510e-02 3.5318e-04 4.6453e-04 1.6725e-04 2.2458e-05 -6.0000e+00 7.7827e-04 -7.2453e-03 1.4812e-04 12 9 1 12 1 1 99.14 18.43 0.31 -0.00725 -0.00375 3 7 1 5 0 1328.420 26.62 20.00 18.43 30.06 31.3 1008.55 67 -9445 4295 -4775 -4748 -16253 -8385 11647 -9037 7085 -3376 1109 -10588 2867 3636 2766 1609 583 4601 -5 3038 -2459 3608 -3178 913 3257 -3557 -1014 -3919 1568 -2704 5111 184 -1968 -252 -1502 -3681 -856 -467 -311 1658 -1580 51 -301 57 1075 -1102 790 -2867 -9 -1799 1193 1270 2645 8 153 2251 1203 883 -491 1182 -74 2514 1442 779 874 -1459 -1869 -2871 720 692 753 739 344 -376 -793 -1122 -1952 -1017 -908 -702 52 -1637 -1341 -1286 1099 -384 1129 226 772 510 -212 -499 -1116 -1377 -1144 901 1302 825 -153 161 -366 -1027 -141 -533 -182 -979 -460 -164 842 419 864 535 439 -329 -788 118 -304 -99 277 429 -160 -386 166 196 919 -463 777 -50 460 175 356 -754 -1159 430 -245 585 90 -184 83 21 -163 -335 5 -843 352 -408 -364 -1327 -673 869 -912 658 -346 112 -1333 367 530 452 281 107 854 -1 608 -515 731 -727 212 773 -908 -242 -901 339 -647 1235 50 -576 -69 -403 -1086 -280 -179 -137 785 -802 26 -158 30 560 -579 403 -1493 -5 -978 676 755 1628 5 101 1491 806 584 -325 789 -53 1877 1150 632 674 -1086 -1370 -2201 591 614 692 682 311 -326 -638 -841 -1414 -751 -735 -622 49 -1662 -1404 -1410 1247 -456 1363 276 921 580 -229 -509 -1112 -1424 -1268 1061 1649 1099 -204 206 -448 -1202 -166 -665 -236 -1315 -635 -234 1246 649 1355 829 655 -467 -1076 159 -422 -144 418 657 -244 -581 244 278 1264 -622 1031 -70 671 266 553 -1196 -1885 720 -426 1030 161 -332 147 36 -279 -562 SS 20240928T133403.8Z 9037.565322 253 1 16.87 2 62.47 118.71 22.29 155.85 0.00 1 0.00 1 0 33 1.205e-02 5.829e-03 9.156e-03 2.810e-03 2.577140e-01 1.408779e-03 3.080349e-03 -6.000000e+00 6.855095e-03 227.86 -2.00 3.47 -2.00 317.43 0.00e+00 3.304621e-04 2.125165e-04 1.321443e-04 -6.000000e+00 3.081942e-04 287.33 -2.00 20.00 -2.00 316.61 0.00e+00 2.152 0.000 302.00 328.00 3 4.5667e+00 3.7319e-03 2.5097e-02 -6.0000e+00 1.7013e-02 2.4437e-02 4.2092e-03 1.3223e-02 -6.0000e+00 1.8447e-02 8.3857e-04 2.5392e-03 6.4659e-03 -6.0000e+00 1.1019e-02 -4.3566e-03 1.2649e-03 1.8081e-03 -6.0000e+00 4.7219e-03 4.7854e-04 -3.4582e-04 7.9980e-05 2.0173e-05 -6.0000e+00 3.1992e-04 -4.9131e-03 -9.7584e-06 12 1 1 12 1 1 99.99 18.43 0.21 -0.00491 -0.00751 15 9 1 5 0 1053.980 26.62 20.01 18.43 31.41 31.4 1016.45 -2556 -4741 1467 -1641 -2937 -2790 -3722 -2388 -1604 2469 -2869 -250 -3551 251 -489 478 1594 511 -295 -168 1624 -1738 1842 1035 -262 2867 549 1134 -255 -1687 761 759 239 78 -1503 -3326 -2520 -1495 645 -600 130 -1250 -75 -62 -1660 -223 -289 -588 -572 -111 -103 520 870 1258 817 1103 296 -133 415 -39 1615 1120 2026 1814 1348 -280 -553 -844 401 187 528 701 53 410 518 -356 -1076 -1567 -1184 -1057 -910 -848 -1546 -1393 -718 -769 -468 412 326 564 252 49 -266 -458 60 -97 207 911 742 87 -107 -653 -1246 -749 -388 -307 -639 -253 42 446 652 688 548 -26 -362 -139 72 -45 -312 78 -212 30 130 349 348 500 72 -42 453 297 212 57 -120 65 -42 -66 -190 160 168 48 27 -470 -546 -268 -557 168 -184 -297 -268 -381 -269 -200 314 -380 -33 -533 41 -92 98 340 114 -69 -41 395 -432 451 270 -73 800 158 308 -66 -431 200 214 73 25 -458 -997 -810 -543 270 -293 68 -694 -42 -36 -960 -128 -163 -327 -313 -60 -58 313 547 824 554 758 208 -94 288 -27 1125 828 1592 1509 1133 -224 -418 -624 304 157 479 660 51 379 455 -291 -814 -1135 -875 -857 -810 -817 -1579 -1471 -792 -897 -567 509 406 686 291 53 -271 -450 61 -105 243 1154 987 115 -137 -792 -1446 -878 -484 -399 -860 -352 61 665 1011 1082 846 -39 -506 -185 95 -61 -444 117 -324 46 194 507 489 678 95 -55 616 425 315 86 -186 103 -69 -113 -329 282 300 85 46 -792 -903 SS 20240928T140447.1Z 9037.586657 271 1 3.26 2 57.41 125.38 20.90 175.05 0.00 1 0.00 1 0 17 1.411e-02 8.375e-03 1.352e-02 6.701e-03 2.175569e-01 3.384335e-03 2.611140e-03 -6.000000e+00 8.024161e-03 227.86 -2.00 3.47 -2.00 316.16 0.00e+00 2.988047e-04 3.774551e-04 5.615136e-05 -6.000000e+00 3.607482e-04 287.33 -2.00 20.00 -2.00 315.40 0.00e+00 1.850 0.000 302.00 328.00 3 3.6003e+00 8.7870e-03 2.1433e-02 -6.0000e+00 1.9914e-02 9.5360e-04 9.8231e-03 1.1097e-02 -6.0000e+00 2.1592e-02 8.7411e-03 5.6780e-03 5.4248e-03 -6.0000e+00 1.2898e-02 -5.8187e-03 2.6573e-03 1.5200e-03 -6.0000e+00 5.5274e-03 1.8206e-03 -3.0126e-04 1.8782e-04 1.8105e-05 -6.0000e+00 3.7447e-04 -5.7286e-03 -3.3117e-05 12 9 1 12 1 1 999.00 18.43 0.26 -0.00573 -0.00799 1 6 2 5 0 1622.070 26.62 19.99 18.43 31.91 31.4 1018.86 1398 -5342 -1103 3260 -551 91 -2115 -2233 260 4844 -2099 299 266 440 -2076 184 1271 3546 2065 -1317 1262 1850 -563 250 1528 2561 -227 -630 -5780 -275 -2541 1971 2199 -204 -961 -2803 -3693 -3760 -96 -557 -324 -309 -497 -297 443 1040 -178 814 -2101 39 69 -161 1155 881 987 88 1103 981 734 -1609 1343 944 879 821 1396 -281 -317 -636 -335 1523 116 1273 66 -788 402 -626 1302 -523 -1808 -398 -1169 -1032 -2432 -1724 -984 -287 -460 1245 87 1110 373 45 -488 -434 1115 -167 -105 1508 238 24 -556 -403 -1065 -129 -737 -979 315 -461 852 524 186 636 180 88 41 -622 -969 647 178 884 -692 -143 -308 262 -91 1134 -771 539 -641 -3 727 314 -182 365 -603 100 159 343 170 526 -649 -412 -450 267 -1168 -238 645 -101 16 -392 -457 57 1079 -490 69 67 122 -652 61 433 1214 738 -497 475 688 -216 100 625 1071 -97 -259 -2329 -104 -1012 797 942 -91 -412 -1185 -1674 -1898 -54 -351 -218 -214 -352 -212 313 734 -125 557 -1440 26 48 -117 863 682 781 71 894 797 590 -1307 1089 802 787 766 1301 -251 -269 -528 -285 1388 114 1277 67 -790 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