File name: Pandora140s1_WashingtonDC_20241005_L2Fit_fout2c10d20200806p1-8.txt File generation date: 20241006T050147.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Luke Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 140 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora140_OF_v3d20200721.txt Instrument calibration file used: Pandora140s1_CF_v10d20200806.txt Level 1 file used: Pandora140s1_WashingtonDC_20241005_L1_smca1c10d20200806p1-8.txt Full location name: McMillan Reservoir Short location name: WashingtonDC Country of location: United States Location latitude [deg]: 38.9218 Location longitude [deg]: -77.0124 Location altitude [m]: 58 Local noon date: 20241005 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0548 305.1956 305.3364 305.4772 305.6179 305.7587 305.8994 306.0401 306.1808 306.3215 306.4622 306.6029 306.7436 306.8842 307.0249 307.1655 307.3061 307.4468 307.5874 307.7279 307.8685 308.0091 308.1496 308.2902 308.4307 308.5712 308.7118 308.8523 308.9927 309.1332 309.2737 309.4141 309.5546 309.6950 309.8354 309.9758 310.1162 310.2566 310.3970 310.5373 310.6777 310.8180 310.9584 311.0987 311.2390 311.3793 311.5196 311.6598 311.8001 311.9403 312.0806 312.2208 312.3610 312.5012 312.6414 312.7816 312.9218 313.0619 313.2021 313.3422 313.4823 313.6224 313.7625 313.9026 314.0427 314.1828 314.3228 314.4629 314.6029 314.7429 314.8829 315.0229 315.1629 315.3029 315.4428 315.5828 315.7227 315.8627 316.0026 316.1425 316.2824 316.4223 316.5621 316.7020 316.8418 316.9817 317.1215 317.2613 317.4011 317.5409 317.6807 317.8205 317.9602 318.1000 318.2397 318.3794 318.5191 318.6588 318.7985 318.9382 319.0779 319.2175 319.3572 319.4968 319.6364 319.7760 319.9156 320.0552 320.1948 320.3343 320.4739 320.6134 320.7529 320.8924 321.0319 321.1714 321.3109 321.4504 321.5898 321.7293 321.8687 322.0081 322.1476 322.2870 322.4263 322.5657 322.7051 322.8444 322.9838 323.1231 323.2624 323.4017 323.5410 323.6803 323.8196 323.9588 324.0981 324.2373 324.3765 324.5158 324.6550 324.7941 324.9333 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241005T121004.6Z 9044.506998 66 1 50.49 2 79.05 105.73 108.91 99.47 0.00 1 0.00 1 0 25 4.643e-01 8.455e-03 8.944e-02 2.614e-03 6.573332e-01 1.404284e-03 7.456886e-03 -6.000000e+00 2.636716e-01 227.15 -2.00 3.47 -2.00 321.38 0.00e+00 2.230105e-03 7.193078e-04 2.043646e-03 -6.000000e+00 1.183405e-02 286.52 -2.00 20.00 -2.00 320.81 0.00e+00 5.073 0.002 302.00 328.00 3 1.3496e+00 5.0389e-03 6.1563e-02 -6.0000e+00 6.5351e-01 6.2087e-02 6.9775e-03 3.6806e-02 -6.0000e+00 7.0877e-01 -1.4143e-01 6.8157e-03 1.9379e-02 -6.0000e+00 4.2341e-01 5.4318e-02 3.2177e-03 5.8934e-03 -6.0000e+00 1.8181e-01 4.6309e-04 -6.9959e-04 7.3730e-05 8.4715e-05 -6.0000e+00 1.2318e-02 -1.0966e-02 6.2862e-05 11 9 0 11 8 0 94.21 18.43 0.20 -0.01097 -0.01622 258 49 1 5 0 195.650 26.62 20.00 18.43 26.35 31.4 999.70 -203240 -153619 -177417 -129646 -146534 -158981 -146747 -129107 -83546 -130036 -149227 -127128 -98704 -78314 -43345 -45615 -5982 -22952 -49302 -3202 -40791 -15846 -46703 -27142 -28693 -28636 -5542 -13234 -10871 -32114 -10393 -22783 -16463 -7069 -5905 -8050 -15733 -5236 -5514 2709 -130 1894 2801 1946 2954 6128 7247 3361 4766 983 4693 3540 6333 6240 3323 7137 4160 4111 11734 2667 3375 1643 5333 5408 5556 4398 3082 -334 931 1786 2369 1940 712 1781 271 358 -1631 -1153 -2759 -1563 -907 -1159 -1140 -1263 -1236 -142 -123 -71 696 30 142 -362 -685 -1088 -1716 -101 -624 228 -128 65 -571 -1319 -1703 -1305 -1020 -973 -577 -869 -441 145 664 778 838 451 -385 -238 -257 -121 27 251 28 448 288 458 555 208 48 -78 83 520 411 391 -222 -82 -293 -149 -150 154 29 73 -50 -217 -367 -2779 -1531 -2467 -1223 -1494 -1783 -1571 -1317 -618 -1691 -2248 -1709 -1384 -1053 -575 -687 -76 -351 -1074 -51 -898 -272 -1137 -598 -698 -743 -118 -298 -232 -901 -279 -834 -664 -287 -230 -312 -718 -254 -302 167 -9 146 227 164 250 514 616 307 451 103 527 454 871 941 554 1196 746 742 1907 464 596 322 1148 1326 1349 1063 803 -92 256 563 833 724 269 633 90 115 -493 -346 -927 -569 -387 -571 -624 -736 -770 -94 -86 -51 501 21 93 -223 -404 -653 -1149 -77 -556 233 -146 75 -626 -1322 -1544 -1158 -973 -986 -612 -993 -547 200 1019 1279 1395 732 -597 -351 -377 -185 44 426 48 734 455 700 811 295 66 -109 130 916 800 761 -458 -177 -683 -370 -380 398 74 184 -119 -484 -784 SS 20241005T121542.1Z 9044.510904 69 1 50.48 2 78.00 106.68 107.88 100.28 0.00 1 0.00 1 0 25 3.506e-01 6.803e-03 6.266e-02 1.918e-03 6.126448e-01 1.017371e-03 6.922183e-03 -6.000000e+00 1.990700e-01 227.15 -2.00 3.47 -2.00 321.15 0.00e+00 7.352091e-04 4.819332e-04 1.203584e-03 -6.000000e+00 8.934762e-03 286.52 -2.00 20.00 -2.00 320.55 0.00e+00 4.664 0.002 302.00 328.00 3 1.3215e+00 3.4879e-03 5.6401e-02 -6.0000e+00 4.9340e-01 1.8120e-02 4.7097e-03 3.3081e-02 -6.0000e+00 5.3513e-01 -8.2426e-02 4.5501e-03 1.6891e-02 -6.0000e+00 3.1968e-01 3.0219e-02 2.1880e-03 4.9094e-03 -6.0000e+00 1.3726e-01 7.3801e-04 -6.8302e-04 5.4614e-05 6.3494e-05 -6.0000e+00 9.3006e-03 -1.0831e-02 5.2455e-05 11 8 0 10 0 0 99.67 18.45 0.16 -0.01083 -0.01596 329 62 1 5 0 153.390 26.62 20.00 18.45 26.40 31.4 1000.72 -151000 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697 570 527 500 439 386 404 292 491 696 765 1237 977 610 266 -191 172 561 612 496 321 309 -38 -267 -832 -835 -541 -231 -567 -553 -629 -951 -798 -288 110 12 917 525 340 154 -285 -530 -613 -105 -238 588 51 36 -586 -1169 -1327 -1248 -1427 -783 -508 -817 -355 312 1450 1344 841 596 -75 -188 -619 204 -493 315 -109 -87 594 597 684 402 146 -184 261 646 592 262 -212 -604 -697 -134 -221 594 224 400 16 -694 -732 SS 20241005T125002.9Z 9044.534756 88 1 50.79 2 71.72 112.70 101.65 105.26 0.00 1 0.00 1 0 17 5.979e-02 4.560e-03 3.081e-02 1.944e-03 4.321261e-01 9.995859e-04 4.987011e-03 -6.000000e+00 3.395518e-02 227.15 -2.00 3.47 -2.00 320.12 0.00e+00 4.977917e-04 3.296363e-04 2.521004e-04 -6.000000e+00 1.523913e-03 286.52 -2.00 20.00 -2.00 319.39 0.00e+00 3.146 0.000 302.00 328.00 3 2.3864e+00 2.9770e-03 3.8332e-02 -6.0000e+00 8.4158e-02 -3.6934e-02 3.6122e-03 2.2279e-02 -6.0000e+00 9.1271e-02 2.8552e-02 2.9431e-03 1.1138e-02 -6.0000e+00 5.4524e-02 -1.7667e-02 1.5161e-03 3.2552e-03 -6.0000e+00 2.3415e-02 1.2915e-03 -3.9780e-04 5.7639e-05 3.7595e-05 -6.0000e+00 1.5861e-03 -1.1373e-02 7.1194e-05 11 1 0 11 8 0 99.99 18.43 0.12 -0.01137 -0.01436 1096 207 1 5 0 46.040 26.62 20.00 18.43 25.51 31.3 995.24 -10226 -27575 -6570 -28853 -25287 -24031 -16927 -2791 -22004 7395 -16746 -3261 -19886 3280 -4976 -497 3208 -6917 5809 -4906 1836 -427 -62 -3573 -2297 -74 -682 -1446 -3096 6529 -2211 3732 -3572 1486 -1999 -6043 -3116 -2453 1921 23 -472 -1321 -645 -537 -341 248 -857 2327 -1311 586 621 2004 122 158 804 171 1344 440 3141 -146 1019 496 1836 2099 1555 913 -584 -152 -743 573 121 299 2 -55 -110 -524 -322 -1461 -880 -1014 -571 -944 -1737 -1207 -1034 -382 10 423 554 898 428 454 103 -611 369 144 580 617 641 68 -187 -799 -1204 -862 -848 -409 -468 -420 -310 365 516 556 427 109 -86 -352 -178 -303 -61 -11 17 36 22 272 58 195 -15 211 246 254 128 59 -285 -272 -59 -35 84 198 104 97 -17 -123 -381 -165 -575 -127 -639 -521 -471 -332 -54 -553 162 -448 -81 -645 102 -203 -23 146 -374 296 -293 106 -25 -4 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