File name: Pandora140s1_WashingtonDC_20241208_L2Fit_fout2c10d20200806p1-8.txt File generation date: 20241209T090352.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Luke Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 140 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora140_OF_v3d20200721.txt Instrument calibration file used: Pandora140s1_CF_v10d20200806.txt Level 1 file used: Pandora140s1_WashingtonDC_20241208_L1_smca1c10d20200806p1-8.txt Full location name: McMillan Reservoir Short location name: WashingtonDC Country of location: United States Location latitude [deg]: 38.9218 Location longitude [deg]: -77.0124 Location altitude [m]: 58 Local noon date: 20241208 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0548 305.1956 305.3364 305.4772 305.6179 305.7587 305.8994 306.0401 306.1808 306.3215 306.4622 306.6029 306.7436 306.8842 307.0249 307.1655 307.3061 307.4468 307.5874 307.7279 307.8685 308.0091 308.1496 308.2902 308.4307 308.5712 308.7118 308.8523 308.9927 309.1332 309.2737 309.4141 309.5546 309.6950 309.8354 309.9758 310.1162 310.2566 310.3970 310.5373 310.6777 310.8180 310.9584 311.0987 311.2390 311.3793 311.5196 311.6598 311.8001 311.9403 312.0806 312.2208 312.3610 312.5012 312.6414 312.7816 312.9218 313.0619 313.2021 313.3422 313.4823 313.6224 313.7625 313.9026 314.0427 314.1828 314.3228 314.4629 314.6029 314.7429 314.8829 315.0229 315.1629 315.3029 315.4428 315.5828 315.7227 315.8627 316.0026 316.1425 316.2824 316.4223 316.5621 316.7020 316.8418 316.9817 317.1215 317.2613 317.4011 317.5409 317.6807 317.8205 317.9602 318.1000 318.2397 318.3794 318.5191 318.6588 318.7985 318.9382 319.0779 319.2175 319.3572 319.4968 319.6364 319.7760 319.9156 320.0552 320.1948 320.3343 320.4739 320.6134 320.7529 320.8924 321.0319 321.1714 321.3109 321.4504 321.5898 321.7293 321.8687 322.0081 322.1476 322.2870 322.4263 322.5657 322.7051 322.8444 322.9838 323.1231 323.2624 323.4017 323.5410 323.6803 323.8196 323.9588 324.0981 324.2373 324.3765 324.5158 324.6550 324.7941 324.9333 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241208T125818.1Z 9108.540487 59 1 51.22 2 83.68 126.19 140.03 45.69 0.00 1 0.00 1 0 25 8.452e-01 4.401e-02 5.002e-01 3.518e-02 9.607753e-01 2.031905e-02 1.065947e-02 -6.000000e+00 4.780070e-01 223.25 -2.00 3.47 -2.00 322.20 0.00e+00 1.628556e-02 1.109421e-02 8.715080e-03 -6.000000e+00 2.535018e-02 279.21 -2.00 20.00 -2.00 321.74 0.00e+00 8.199 0.010 302.00 328.00 3 1.4035e+00 7.5686e-02 1.1445e-01 -6.0000e+00 1.1823e+00 1.4819e+00 9.1167e-02 9.9593e-02 -6.0000e+00 1.2935e+00 -1.5627e+00 7.1112e-02 2.8206e-02 -6.0000e+00 7.6408e-01 5.7220e-01 3.6060e-02 1.8146e-02 -6.0000e+00 3.2916e-01 1.1614e-05 -2.3995e-03 9.3076e-04 1.3919e-04 -6.0000e+00 2.3883e-02 -5.1448e-03 -1.9161e-04 12 8 8 10 0 0 99.91 18.41 0.38 -0.00514 -0.02318 27 5 1 5 0 1896.730 26.51 20.00 18.41 11.12 29.3 1016.33 -105727 140119 -48397 53274 900000 -132111 82355 -81911 -133872 900000 900000 900000 158848 900000 180717 143504 62731 -8492 64039 76086 188022 -38687 2280 -76737 -15521 -33563 29776 -19375 900000 -57797 -9882 -89658 -55940 900000 13104 13785 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8088 977 1130 1827 2609 -5426 -467 976 -2018 2372 -2604 1680 -487 2803 -341 7017 -4436 -98 1484 950 1030 -878 -1173 -4363 3384 -3996 1871 -5964 2733 -4803 8941 -7077 -1577 -2749 -3095 -3219 -1091 251 -1442 3584 7041 -7614 -440 4075 -5068 -1447 -3904 3851 1963 202 -1930 506 2875 6168 -1283 -2603 -3259 6632 6540 5286 1380 -2963 1225 -3556 -1618 116 1607 513 -3335 2558 -3979 SS 20241208T130900.6Z 9108.547923 62 1 50.57 2 82.02 128.03 138.52 48.83 0.00 1 0.00 1 0 25 7.326e-01 1.663e-02 2.555e-01 5.769e-03 8.148105e-01 3.193242e-03 8.931076e-03 -6.000000e+00 4.097002e-01 223.25 -2.00 3.47 -2.00 322.01 0.00e+00 6.271078e-03 1.817339e-03 1.202022e-03 -6.000000e+00 1.902564e-02 279.21 -2.00 20.00 -2.00 321.56 0.00e+00 6.737 0.005 302.00 328.00 3 6.7292e-01 1.2177e-02 7.9724e-02 -6.0000e+00 1.0093e+00 4.5130e-01 1.7655e-02 4.5937e-02 -6.0000e+00 1.0995e+00 -6.4267e-01 1.8128e-02 2.5133e-02 -6.0000e+00 6.5554e-01 2.6471e-01 8.3159e-03 1.0086e-02 -6.0000e+00 2.8247e-01 1.5492e-04 -1.1559e-03 1.6012e-04 1.3306e-04 -6.0000e+00 1.9587e-02 -9.1449e-03 4.2004e-05 12 8 8 10 0 0 54.02 18.42 0.22 -0.00914 -0.01783 182 34 1 5 0 277.740 26.51 19.99 18.42 11.52 29.3 1019.46 -227324 -130672 -190799 -154678 -150591 -166173 -220504 -192033 -90452 -224266 900000 -226164 -105771 -88832 -70876 80266 -96578 27717 -81015 466310 -59273 44923 -79282 682 -3291 -14448 13185 -46700 186587 -69507 36909 -14198 45999 29765 31275 -12776 -16449 89732 2244 41730 6827 52652 16983 25015 33005 10748 31769 8640 50247 3061 35934 4689 27154 27815 22873 32642 6820 26783 1473 16220 6059 2095 7368 11231 16672 11423 12932 1446 14000 3313 11382 7050 5835 9134 2428 3392 -6413 1388 -5826 1747 40 -275 546 -805 852 -1176 1619 -1246 1113 -975 642 -1226 -2269 -383 -4350 276 -2632 -441 -2495 -433 -775 -1827 -2320 -2734 -674 -3159 -800 -2266 -1477 -526 627 487 474 662 -836 894 -1388 -195 -440 406 762 689 1320 609 1924 124 1863 -562 691 1154 717 768 97 102 -650 153 57 20 -271 243 -388 -563 -711 -4257 -1172 -3221 -1821 -1527 -1835 -4132 -2978 -587 -5346 900000 -6278 -1244 -1168 -1009 452 -2403 242 -2075 2623 -1299 365 -2051 9 -48 -240 172 -1028 1050 -2003 491 -365 801 657 656 -383 -544 1291 85 1309 328 1798 837 1178 1460 594 1495 523 2222 221 2150 417 2156 2382 2179 2948 798 2603 174 1624 675 263 1008 1701 2609 1880 2107 273 2562 769 2724 1838 1525 2183 564 700 -1355 279 -1407 472 13 -104 228 -362 401 -601 843 -687 603 -524 319 -585 -1068 -184 -2450 175 -2010 -384 -2470 -430 -735 -1590 -1812 -2084 -538 -2737 -715 -2212 -1581 -634 850 718 721 994 -1226 1242 -1977 -286 -683 651 1205 1046 1912 865 2608 167 2396 -763 1059 2019 1405 1631 221 245 -1685 415 158 57 -766 660 -993 -1354 -1637 SS 20241208T131914.8Z 9108.555033 65 1 50.47 2 80.47 129.83 137.02 51.68 0.00 1 0.00 1 0 25 5.218e-01 8.669e-03 1.083e-01 2.455e-03 7.149871e-01 1.324674e-03 7.935336e-03 -6.000000e+00 2.917790e-01 223.25 -2.00 3.47 -2.00 321.63 0.00e+00 4.343851e-03 6.895779e-04 8.264580e-04 -6.000000e+00 1.289450e-02 279.21 -2.00 20.00 -2.00 321.13 0.00e+00 5.760 0.003 302.00 328.00 3 3.6218e-01 4.7125e-03 6.8506e-02 -6.0000e+00 7.1861e-01 1.4308e-01 6.7444e-03 3.9929e-02 -6.0000e+00 7.8264e-01 -2.1005e-01 7.1637e-03 2.1302e-02 -6.0000e+00 4.6687e-01 8.4166e-02 3.3596e-03 8.3573e-03 -6.0000e+00 2.0066e-01 6.0598e-04 -1.0875e-03 6.9296e-05 9.7897e-05 -6.0000e+00 1.3829e-02 -8.9213e-03 3.7630e-05 11 8 0 10 0 0 72.63 18.42 0.19 -0.00892 -0.01709 483 91 1 5 0 104.470 26.51 20.01 18.42 12.24 29.6 1025.92 -108501 -185577 -104088 -198719 -183056 -227042 -160893 -172883 -174275 -93849 -148290 -76532 -130782 -93867 -94732 -84973 -58628 -52392 -34832 -38447 -15398 -32129 -44700 -38083 -58624 -21009 -32756 -21881 -40309 -26284 -24226 3103 181 -109 -14437 -19755 -5235 1823 -1106 7060 13719 2470 7008 -74 2642 5535 658 3999 2288 12205 6978 7784 5169 6747 7488 5213 6018 3969 11827 2220 4999 1297 4357 5172 4914 3542 3236 3133 2122 4119 2192 2478 1194 778 194 -1814 -1036 -1842 -3661 -1499 13 -1621 -1052 -1420 -1712 -265 -460 1180 770 1009 836 -565 -772 -799 -1048 -1234 108 38 13 -208 -325 -880 -1406 -1781 -1801 -894 -1149 -748 -190 448 458 492 455 207 -129 -34 -286 -362 -259 152 101 259 342 467 497 541 358 238 1 700 302 490 -189 -101 -146 -143 35 -83 96 20 42 -181 -514 -468 -1898 -573 -2552 -1833 -3409 -1464 -1806 -2086 -607 -1581 -495 -1708 -1124 -1484 -1498 -919 -867 -531 -644 -211 -517 -846 -738 -1505 -393 -713 -419 -912 -561 -617 74 5 -4 -478 -670 -182 64 -49 349 728 159 459 -5 190 399 51 315 194 1010 630 790 595 840 993 738 876 591 1577 318 712 210 787 1067 1101 798 726 728 544 1200 729 866 421 261 60 -510 -267 -484 -1093 -526 5 -782 -523 -752 -971 -159 -290 756 498 633 490 -338 -446 -473 -646 -891 90 37 14 -229 -338 -833 -1198 -1488 -1616 -844 -1146 -800 -221 586 676 783 738 329 -195 -48 -413 -546 -412 253 168 411 521 688 702 740 472 323 1 1225 590 1032 -423 -239 -347 -361 91 -218 253 51 107 -432 -1174 SS 20241208T132828.7Z 9108.561444 70 1 50.46 2 79.11 131.49 135.62 54.12 0.00 1 0.00 1 0 25 3.950e-01 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