File name: Pandora140s1_WashingtonDC_20250721_L2Fit_fout2c14d20220101p1-8.txt
File generation date: 20250722T052840.6Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c14p1-8
Local principal investigator: Luke Valin
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 140
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora140_OF_v3d20200721.txt
Instrument calibration file used: Pandora140s1_CF_v14d20220101.txt
Level 1 file used: Pandora140s1_WashingtonDC_20250721_L1_smca1c14d20220101p1-8.txt
Full location name: McMillan Reservoir
Short location name: WashingtonDC
Country of location: United States
Location latitude [deg]: 38.9218
Location longitude [deg]: -77.0124
Location altitude [m]: 58
Local noon date: 20250721
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: Modification of session 10 "Based on session 8 "Modif only on SO2 (WashingtonDC)"""
First and last pixel inside fitting window: 215 357
Nominal wavelengths inside fitting window [nm]: 305.0439 305.1847 305.3255 305.4663 305.6071 305.7478 305.8885 306.0293 306.1700 306.3107 306.4514 306.5921 306.7328 306.8734 307.0141 307.1547 307.2954 307.4360 307.5766 307.7172 307.8578 307.9983 308.1389 308.2794 308.4200 308.5605 308.7010 308.8415 308.9820 309.1225 309.2630 309.4034 309.5439 309.6843 309.8247 309.9652 310.1056 310.2459 310.3863 310.5267 310.6670 310.8074 310.9477 311.0881 311.2284 311.3687 311.5089 311.6492 311.7895 311.9297 312.0700 312.2102 312.3504 312.4906 312.6308 312.7710 312.9112 313.0514 313.1915 313.3316 313.4718 313.6119 313.7520 313.8921 314.0322 314.1722 314.3123 314.4523 314.5924 314.7324 314.8724 315.0124 315.1524 315.2924 315.4324 315.5723 315.7123 315.8522 315.9921 316.1320 316.2719 316.4118 316.5517 316.6915 316.8314 316.9712 317.1111 317.2509 317.3907 317.5305 317.6703 317.8100 317.9498 318.0895 318.2293 318.3690 318.5087 318.6484 318.7881 318.9278 319.0675 319.2071 319.3468 319.4864 319.6260 319.7656 319.9052 320.0448 320.1844 320.3239 320.4635 320.6030 320.7426 320.8821 321.0216 321.1611 321.3006 321.4400 321.5795 321.7189 321.8584 321.9978 322.1372 322.2766 322.4160 322.5554 322.6947 322.8341 322.9734 323.1128 323.2521 323.3914 323.5307 323.6700 323.8093 323.9485 324.0878 324.2270 324.3662 324.5054 324.6446 324.7838 324.9230
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20250721T142007.5Z 9333.597309 316 1 51.40 2 41.70 103.58 11.48 191.73 0.00 1 0.00 1 0 17 7.680e-03 5.388e-03 3.347e-04 1.698e-04 1.792183e-01 8.695858e-05 2.140998e-03 -6.000000e+00 4.445274e-03 232.50 -2.00 3.47 -2.00 316.16 0.00e+00 2.531610e-04 9.596789e-06 7.063467e-05 -6.000000e+00 1.991515e-04 290.56 -2.00 20.00 -2.00 315.35 0.00e+00 1.338 0.000 302.00 328.00 3 8.8691e-01 2.2819e-04 1.6322e-02 -6.0000e+00 1.1145e-02 -1.4934e-03 2.5417e-04 9.3221e-03 -6.0000e+00 1.2035e-02 -1.9025e-03 1.4576e-04 4.5033e-03 -6.0000e+00 7.1751e-03 -2.2760e-03 6.7397e-05 1.2288e-03 -6.0000e+00 3.0551e-03 4.8319e-02 -2.0118e-07 4.7960e-06 1.4808e-05 -6.0000e+00 2.0413e-04 4.6920e-03 0.0000e+00 10 0 0 10 0 0 99.96 18.53 0.21 0.00469 0.00469 3109 588 1 5 0 16.220 26.73 20.00 18.53 34.21 32.8 1015.21 -538 -443 -405 -1498 -2704 -2198 -1700 108 837 348 -867 -1376 -836 -439 535 324 227 199 655 877 910 527 585 590 241 624 362 -232 -418 19 499 957 1225 94 -1728 -2403 -2188 -1376 -376 -129 -354 -483 -608 -559 -489 -221 -513 -522 -819 -517 294 681 955 928 761 742 853 700 495 451 631 1066 1465 1663 902 101 -640 -899 -242 416 561 352 213 178 135 -281 -670 -1222 -1188 -826 -782 -987 -1548 -1392 -969 -543 -210 203 387 347 260 46 -225 -374 -6 130 440 743 424 140 -258 -631 -956 -477 -490 -426 -432 -451 -140 217 575 509 350 88 -251 -195 -223 24 50 350 12 252 168 325 411 394 290 267 406 385 339 123 -221 -115 -72 61 35 125 12 -60 -257 -398 -653 -112 -100 -93 -325 -519 -434 -349 22 188 82 -203 -321 -211 -124 167 110 79 71 239 330 348 200 224 237 101 269 157 -95 -156 7 183 369 502 40 -699 -938 -922 -662 -213 -86 -236 -335 -433 -401 -348 -157 -354 -347 -575 -356 209 470 688 701 593 585 683 560 390 353 505 906 1337 1606 874 90 -525 -705 -196 377 561 370 226 183 130 -246 -527 -977 -964 -680 -720 -1001 -1686 -1456 -1079 -649 -265 265 508 442 306 49 -237 -372 -6 145 499 928 567 186 -322 -735 -1136 -534 -600 -554 -585 -639 -191 311 862 772 511 129 -336 -241 -272 31 68 512 17 354 249 463 553 504 351 318 508 512 473 176 -321 -172 -106 94 55 204 19 -98 -407 -612 -980
SS 20250721T142533.2Z 9333.601079 319 1 50.47 2 40.68 104.72 11.73 197.41 0.00 1 0.00 1 0 17 7.490e-03 5.407e-03 8.210e-04 4.162e-04 1.776491e-01 2.122783e-04 2.116798e-03 -6.000000e+00 4.335371e-03 232.50 -2.00 3.47 -2.00 316.20 0.00e+00 2.009061e-04 2.352368e-05 7.123414e-05 -6.000000e+00 1.942251e-04 290.56 -2.00 20.00 -2.00 315.36 0.00e+00 1.317 0.000 302.00 328.00 3 2.5502e+00 5.5738e-04 1.6097e-02 -6.0000e+00 1.0870e-02 2.2449e-03 6.2077e-04 9.2198e-03 -6.0000e+00 1.1737e-02 -2.2301e-03 3.5608e-04 4.4527e-03 -6.0000e+00 6.9977e-03 -2.1930e-03 1.6439e-04 1.2116e-03 -6.0000e+00 2.9796e-03 9.3611e-03 -2.3389e-05 1.1841e-05 1.4650e-05 -6.0000e+00 1.9908e-04 4.5883e-03 0.0000e+00 10 0 0 10 0 0 99.95 18.53 0.19 0.00459 0.00441 780 147 1 5 0 64.700 26.73 20.00 18.53 34.84 32.8 1019.68 -819 -469 -248 -1386 -2362 -1950 -1158 147 1081 379 -639 -1149 -720 -430 543 379 -15 202 517 732 737 532 555 642 277 520 399 -471 -384 -13 683 816 1188 247 -1700 -2299 -2377 -1299 -594 -79 -470 -523 -621 -537 -502 -275 -572 -616 -814 -601 255 733 937 914 669 771 797 730 514 535 673 1102 1549 1649 919 -23 -714 -923 -293 365 579 450 252 201 163 -249 -726 -1282 -1285 -799 -752 -928 -1533 -1373 -970 -549 -180 145 401 342 315 80 -250 -437 -78 177 434 758 460 134 -210 -678 -934 -507 -520 -454 -473 -448 -143 233 576 533 372 90 -273 -259 -266 14 -2 343 15 270 207 279 398 336 298 196 391 386 311 145 -223 -100 -92 108 28 147 80 -31 -235 -378 -638 -175 -108 -58 -306 -460 -355 -218 30 246 91 -152 -272 -185 -123 172 130 -5 73 192 279 286 204 215 260 117 227 175 -195 -145 -5 253 317 491 106 -692 -902 -1010 -628 -312 -49 -315 -364 -444 -387 -359 -195 -397 -411 -526 -381 166 507 677 692 522 608 639 585 405 418 539 936 1413 1593 890 -20 -585 -723 -237 331 577 435 246 206 157 -217 -569 -937 -953 -655 -689 -937 -1661 -1428 -1075 -652 -225 188 524 433 368 85 -262 -432 -80 196 489 940 609 176 -261 -784 -1102 -564 -632 -585 -636 -630 -208 331 856 801 539 130 -361 -319 -322 17 -3 497 23 405 305 394 530 426 387 251 485 508 428 205 -320 -147 -143 178 44 237 131 -50 -367 -618 -1018
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