File name: Pandora140s1_WashingtonDC_20250810_L2Fit_fnvs5c14d20220101p1-8.txt File generation date: 20250811T052736.7Z Data description: Level 2 spectral fitting results file Data file version: fnvs5c14p1-8 Local principal investigator: Luke Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 140 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora140_OF_v3d20200721.txt Instrument calibration file used: Pandora140s1_CF_v14d20220101.txt Level 1 file used: Pandora140s1_WashingtonDC_20250810_L1_smca1c14d20220101p1-8.txt Full location name: McMillan Reservoir Short location name: WashingtonDC Country of location: United States Location latitude [deg]: 38.9218 Location longitude [deg]: -77.0124 Location altitude [m]: 58 Local noon date: 20250810 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 10 "Based on session 8 "Modif only on SO2 (WashingtonDC)""" First and last pixel inside fitting window: 911 1456 Nominal wavelengths inside fitting window [nm]: 400.1208 400.2528 400.3849 400.5169 400.6489 400.7809 400.9129 401.0449 401.1768 401.3088 401.4407 401.5726 401.7045 401.8364 401.9683 402.1001 402.2320 402.3638 402.4956 402.6274 402.7592 402.8910 403.0227 403.1545 403.2862 403.4179 403.5496 403.6813 403.8130 403.9446 404.0763 404.2079 404.3395 404.4711 404.6027 404.7343 404.8658 404.9974 405.1289 405.2604 405.3919 405.5234 405.6549 405.7864 405.9178 406.0492 406.1807 406.3121 406.4434 406.5748 406.7062 406.8375 406.9689 407.1002 407.2315 407.3628 407.4940 407.6253 407.7565 407.8878 408.0190 408.1502 408.2814 408.4126 408.5437 408.6749 408.8060 408.9371 409.0682 409.1993 409.3304 409.4614 409.5925 409.7235 409.8545 409.9855 410.1165 410.2475 410.3784 410.5094 410.6403 410.7712 410.9021 411.0330 411.1639 411.2948 411.4256 411.5564 411.6872 411.8180 411.9488 412.0796 412.2104 412.3411 412.4718 412.6025 412.7332 412.8639 412.9946 413.1253 413.2559 413.3865 413.5171 413.6477 413.7783 413.9089 414.0395 414.1700 414.3005 414.4310 414.5615 414.6920 414.8225 414.9529 415.0834 415.2138 415.3442 415.4746 415.6050 415.7354 415.8657 415.9960 416.1264 416.2567 416.3870 416.5173 416.6475 416.7778 416.9080 417.0382 417.1684 417.2986 417.4288 417.5590 417.6891 417.8193 417.9494 418.0795 418.2096 418.3397 418.4697 418.5998 418.7298 418.8598 418.9898 419.1198 419.2498 419.3797 419.5097 419.6396 419.7695 419.8994 420.0293 420.1592 420.2891 420.4189 420.5487 420.6785 420.8083 420.9381 421.0679 421.1976 421.3274 421.4571 421.5868 421.7165 421.8462 421.9759 422.1055 422.2352 422.3648 422.4944 422.6240 422.7536 422.8831 423.0127 423.1422 423.2717 423.4012 423.5307 423.6602 423.7897 423.9191 424.0486 424.1780 424.3074 424.4368 424.5661 424.6955 424.8248 424.9542 425.0835 425.2128 425.3421 425.4713 425.6006 425.7298 425.8591 425.9883 426.1175 426.2467 426.3758 426.5050 426.6341 426.7632 426.8924 427.0214 427.1505 427.2796 427.4086 427.5377 427.6667 427.7957 427.9247 428.0537 428.1826 428.3116 428.4405 428.5694 428.6983 428.8272 428.9561 429.0849 429.2138 429.3426 429.4714 429.6002 429.7290 429.8578 429.9865 430.1153 430.2440 430.3727 430.5014 430.6301 430.7587 430.8874 431.0160 431.1446 431.2732 431.4018 431.5304 431.6590 431.7875 431.9160 432.0446 432.1731 432.3015 432.4300 432.5585 432.6869 432.8153 432.9437 433.0721 433.2005 433.3289 433.4572 433.5856 433.7139 433.8422 433.9705 434.0988 434.2270 434.3553 434.4835 434.6117 434.7399 434.8681 434.9963 435.1244 435.2526 435.3807 435.5088 435.6369 435.7650 435.8931 436.0211 436.1492 436.2772 436.4052 436.5332 436.6612 436.7891 436.9171 437.0450 437.1729 437.3008 437.4287 437.5566 437.6844 437.8123 437.9401 438.0679 438.1957 438.3235 438.4513 438.5790 438.7068 438.8345 438.9622 439.0899 439.2176 439.3452 439.4729 439.6005 439.7281 439.8557 439.9833 440.1109 440.2384 440.3660 440.4935 440.6210 440.7485 440.8760 441.0034 441.1309 441.2583 441.3857 441.5131 441.6405 441.7679 441.8953 442.0226 442.1499 442.2773 442.4046 442.5318 442.6591 442.7864 442.9136 443.0408 443.1680 443.2952 443.4224 443.5496 443.6767 443.8038 443.9310 444.0581 444.1851 444.3122 444.4393 444.5663 444.6933 444.8203 444.9473 445.0743 445.2013 445.3282 445.4552 445.5821 445.7090 445.8359 445.9628 446.0896 446.2165 446.3433 446.4701 446.5969 446.7237 446.8504 446.9772 447.1039 447.2306 447.3573 447.4840 447.6107 447.7374 447.8640 447.9906 448.1173 448.2439 448.3704 448.4970 448.6236 448.7501 448.8766 449.0031 449.1296 449.2561 449.3825 449.5090 449.6354 449.7618 449.8882 450.0146 450.1410 450.2673 450.3937 450.5200 450.6463 450.7726 450.8989 451.0251 451.1514 451.2776 451.4038 451.5300 451.6562 451.7824 451.9085 452.0347 452.1608 452.2869 452.4130 452.5391 452.6651 452.7912 452.9172 453.0432 453.1692 453.2952 453.4212 453.5471 453.6730 453.7990 453.9249 454.0508 454.1766 454.3025 454.4283 454.5542 454.6800 454.8058 454.9316 455.0573 455.1831 455.3088 455.4345 455.5602 455.6859 455.8116 455.9373 456.0629 456.1885 456.3141 456.4397 456.5653 456.6909 456.8164 456.9420 457.0675 457.1930 457.3185 457.4439 457.5694 457.6948 457.8202 457.9457 458.0711 458.1964 458.3218 458.4471 458.5725 458.6978 458.8231 458.9484 459.0736 459.1989 459.3241 459.4493 459.5745 459.6997 459.8249 459.9501 460.0752 460.2003 460.3255 460.4506 460.5756 460.7007 460.8257 460.9508 461.0758 461.2008 461.3258 461.4508 461.5757 461.7007 461.8256 461.9505 462.0754 462.2003 462.3251 462.4500 462.5748 462.6996 462.8244 462.9492 463.0739 463.1987 463.3234 463.4482 463.5729 463.6975 463.8222 463.9469 464.0715 464.1961 464.3207 464.4453 464.5699 464.6945 464.8190 464.9436 465.0681 465.1926 465.3170 465.4415 465.5660 465.6904 465.8148 465.9392 466.0636 466.1880 466.3123 466.4367 466.5610 466.6853 466.8096 466.9339 467.0581 467.1824 467.3066 467.4308 467.5550 467.6792 467.8034 467.9275 468.0516 468.1758 468.2999 468.4240 468.5480 468.6721 468.7961 468.9201 469.0441 469.1681 469.2921 469.4161 469.5400 469.6639 469.7878 469.9117 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Molecular iodine slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of molecular iodine slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Molecular iodine effective temperature [K] Column 39: Independent uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective molecular iodine fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for molecular iodine [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Nitrogen dioxide effective temperature [K] Column 50: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Oxygen dimer slant column amount [moles squared per meter to the 5th], -9e99=fitting not successful Column 56: Independent uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 57: Structured uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 58: Common uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 59: rms-based uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 60: Oxygen dimer effective temperature [K] Column 61: Independent uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 62: Structured uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 63: Common uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 64: Effective oxygen dimer fitting wavelength [nm], -9=fitting not successful Column 65: Diffuse correction applied before fitting at effective fitting wavelength for oxygen dimer [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 66: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 67: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 68: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 69: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 70: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 71: Ozone effective temperature [K] Column 72: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 73: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 74: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 75: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 76: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 77: Iodine dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 78: Independent uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 79: Structured uncertainty of iodine dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 80: Common uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 81: rms-based uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 82: Iodine dioxide effective temperature [K] Column 83: Independent uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 84: Structured uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 85: Common uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 86: Effective iodine dioxide fitting wavelength [nm], -9=fitting not successful Column 87: Diffuse correction applied before fitting at effective fitting wavelength for iodine dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 88: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 89: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 90: Lower limit used for wavelength scaling [nm] Column 91: Upper limit used for wavelength scaling [nm] Column 92: Order of smoothing polynomial Column 93: Smoothing polynomial coefficient, order 0 Column 94: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 95: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 96: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 97: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 98: Smoothing polynomial coefficient, order 1 Column 99: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 100: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 101: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 102: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 103: Smoothing polynomial coefficient, order 2 Column 104: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 105: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 106: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 107: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 108: Smoothing polynomial coefficient, order 3 Column 109: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 110: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 111: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 112: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 113: Smoothing polynomial coefficient, order 4 Column 114: Independent uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 115: Structured uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 116: Common uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 117: rms-based uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 118: Mean value of measured data inside fitting window [same units as measurements] Column 119: Offset polynomial coefficient, order 0 Column 120: Independent uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 121: Structured uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 122: Common uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 123: rms-based uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 124: Wavelength change polynomial coefficient, order 0 Column 125: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 126: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 127: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 128: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 129: Wavelength change polynomial coefficient, order 1 Column 130: Independent uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 131: Structured uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 132: Common uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 133: rms-based uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 134: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 135: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 136: Resolution change polynomial coefficient, order 0 Column 137: Independent uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 138: Structured uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 139: Common uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 140: rms-based uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 141: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 142: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 143: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 144: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 145: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 146: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 147: Atmospheric variability [%], 999=no atmospheric variability was determined Column 148: Wavelength effective temperature [°C], 999=no effective temperature given Column 149: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 150: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 151: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 152: Number of bright count cycles Column 153: Number of dark count cycles Column 154: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 155: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 156: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 157: Integration time [ms] Column 158: Temperature at electronics board [°C], 999=no temperature signal Column 159: Spectrometer control temperature [°C], 999=no temperature signal Column 160: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 161: Temperature in head sensor [°C], 999=no temperature signal Column 162: Humidity in head sensor [%], -9=no humidity signal Column 163: Pressure in head sensor [hPa], -9=no pressure signal Columns 164-709: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 710-1255: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250810T103608.6Z 9353.441766 206 1 9.73 2 87.39 72.23 81.09 245.58 0.00 1 0.00 1 0 81 1.066e-02 6.504e-03 5.382e-03 3.859e-03 1.313591e+04 7.964898e+02 1.119223e+03 3.215917e+02 2.226598e+03 291.00 -2.00 20.00 -2.00 451.14 0.00e+00 -1.810967e-03 4.910246e-04 1.475865e-05 2.020864e-05 1.127102e-03 291.00 -2.00 20.00 -2.00 458.98 0.00e+00 1.859208e-03 3.592049e-05 1.339829e-05 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81.71 246.19 0.00 1 0.00 1 0 81 2.008e-03 1.240e-03 4.179e-04 2.811e-04 1.278745e+04 5.742508e+01 1.091141e+03 3.216115e+02 4.191930e+02 291.00 -2.00 20.00 -2.00 451.38 0.00e+00 -8.373676e-04 3.659588e-05 1.781978e-05 2.074029e-05 2.122898e-04 291.00 -2.00 20.00 -2.00 459.09 0.00e+00 1.717489e-03 2.597309e-06 1.211174e-05 2.558530e-06 1.845481e-05 229.65 -2.00 2.13 -2.00 448.17 0.00e+00 5.881391e+06 3.839644e+04 1.555809e+05 1.885672e+05 2.915687e+05 272.21 -2.00 11.12 -2.00 460.44 0.00e+00 1.486193e+00 6.619934e-03 1.488970e-02 7.218667e-03 6.258421e-02 231.83 -2.00 3.47 -2.00 458.37 0.00e+00 -3.816678e-06 8.432186e-07 1.681844e-06 9.578196e-07 7.626511e-06 291.00 -2.00 20.00 -2.00 458.63 0.00e+00 12.844 0.037 397.00 473.00 4 1.7041e+00 3.3562e-04 3.3903e-02 3.5728e-04 2.1067e-03 -1.1680e-01 4.6879e-04 7.0814e-03 3.6712e-04 2.8911e-03 2.8941e-02 2.2089e-04 9.3548e-04 1.3355e-04 1.2619e-03 1.0774e-03 1.0936e-04 1.6487e-04 4.8401e-05 5.0043e-04 -3.2856e-03 5.1067e-05 1.0232e-04 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20250810T190937.9Z 9353.798356 454 6 6.07 2 34.74 235.32 149.88 21.19 0.00 1 0.00 1 0 33 2.401e-04 2.360e-04 1.017e-04 1.001e-04 7.082950e+02 1.990551e+01 5.900041e+01 3.213431e+02 5.002111e+01 291.01 -2.00 20.00 -2.00 444.97 0.00e+00 8.108766e-05 1.088847e-05 1.103878e-06 1.461937e-05 2.603964e-05 291.01 -2.00 20.00 -2.00 454.15 0.00e+00 1.499760e-04 8.903578e-07 9.923173e-07 2.707295e-06 2.179681e-06 229.17 -2.00 2.13 -2.00 435.23 0.00e+00 3.276210e+05 1.383896e+04 7.858998e+03 1.886298e+05 3.476558e+04 272.21 -2.00 11.12 -2.00 456.81 0.00e+00 1.721113e-01 2.883831e-03 8.204734e-04 7.802740e-03 7.517357e-03 231.81 -2.00 3.47 -2.00 453.45 0.00e+00 1.249930e-06 3.551777e-07 1.302484e-07 9.388865e-07 9.123653e-07 291.01 -2.00 20.00 -2.00 454.79 0.00e+00 1.216 0.000 397.00 473.00 4 -1.7571e-02 1.0469e-04 3.0835e-03 3.3888e-04 2.4348e-04 -6.4789e-04 1.2552e-04 6.4401e-04 2.1338e-04 3.0094e-04 -1.0105e-03 7.1965e-05 8.4947e-05 1.2690e-04 1.7191e-04 -7.2848e-04 2.4177e-05 1.0337e-05 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