File name: Pandora140s1_WashingtonDC_20250820_L2Fit_fwvt1c14d20220101p1-8.txt
File generation date: 20250821T052032.2Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c14p1-8
Local principal investigator: Luke Valin
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 140
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora140_OF_v3d20200721.txt
Instrument calibration file used: Pandora140s1_CF_v14d20220101.txt
Level 1 file used: Pandora140s1_WashingtonDC_20250820_L1_smca1c14d20220101p1-8.txt
Full location name: McMillan Reservoir
Short location name: WashingtonDC
Country of location: United States
Location latitude [deg]: 38.9218
Location longitude [deg]: -77.0124
Location altitude [m]: 58
Local noon date: 20250820
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: Modification of session 10 "Based on session 8 "Modif only on SO2 (WashingtonDC)"""
First and last pixel inside fitting window: 1637 1786
Nominal wavelengths inside fitting window [nm]: 492.0699 492.1908 492.3117 492.4326 492.5535 492.6743 492.7952 492.9160 493.0368 493.1576 493.2784 493.3991 493.5199 493.6406 493.7613 493.8820 494.0027 494.1233 494.2440 494.3646 494.4852 494.6058 494.7264 494.8469 494.9675 495.0880 495.2085 495.3290 495.4495 495.5699 495.6904 495.8108 495.9312 496.0516 496.1720 496.2923 496.4127 496.5330 496.6533 496.7736 496.8939 497.0141 497.1344 497.2546 497.3748 497.4950 497.6152 497.7353 497.8555 497.9756 498.0957 498.2158 498.3359 498.4559 498.5759 498.6960 498.8160 498.9360 499.0559 499.1759 499.2958 499.4157 499.5356 499.6555 499.7754 499.8953 500.0151 500.1349 500.2547 500.3745 500.4943 500.6140 500.7338 500.8535 500.9732 501.0929 501.2125 501.3322 501.4518 501.5714 501.6910 501.8106 501.9302 502.0497 502.1693 502.2888 502.4083 502.5278 502.6472 502.7667 502.8861 503.0055 503.1249 503.2443 503.3637 503.4830 503.6023 503.7216 503.8409 503.9602 504.0795 504.1987 504.3180 504.4372 504.5564 504.6755 504.7947 504.9138 505.0330 505.1521 505.2712 505.3902 505.5093 505.6283 505.7474 505.8664 505.9854 506.1043 506.2233 506.3422 506.4611 506.5801 506.6989 506.8178 506.9367 507.0555 507.1743 507.2931 507.4119 507.5307 507.6494 507.7682 507.8869 508.0056 508.1243 508.2429 508.3616 508.4802 508.5988 508.7174 508.8360 508.9546 509.0731 509.1916 509.3102 509.4287 509.5471 509.6656 509.7840 509.9025
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250820T154447.7Z 9363.656108 340 1 50.02 2 32.90 138.41 16.38 214.01 0.00 1 0.00 1 0 22 3.207e-03 3.183e-03 1.139e-03 1.136e-03 3.992661e+03 7.273609e+01 2.796504e+02 -6.000000e+00 1.821123e+02 290.79 -2.00 20.00 -2.00 505.28 0.00e+00 6.296565e-04 3.178012e-05 3.795117e-05 -6.000000e+00 9.146415e-05 290.79 -2.00 20.00 -2.00 500.40 0.00e+00 3.358304e-02 2.246724e-02 2.555805e-02 -6.000000e+00 6.351452e-02 231.28 -2.00 3.47 -2.00 502.02 0.00e+00 1.190 0.000 489.00 513.00 1 7.9496e+00 1.7210e-03 2.8989e-03 -6.0000e+00 4.8749e-03 3.9445e-03 4.4693e-04 6.1808e-04 -6.0000e+00 1.2741e-03 5.7410e-04 1.2694e-03 1.0841e-04 3.0632e-05 -6.0000e+00 3.1581e-04 3.7985e-03 -5.3653e-05 10 0 0 10 0 0 49.27 18.51 0.90 0.00380 0.01260 13 2 1 4 0 3846.080 26.73 20.00 18.51 30.97 32.8 1037.97 -1210 -385 -107 148 0 522 614 409 398 150 235 -236 -290 -432 -157 -475 -93 -15 218 -86 -15 326 -77 214 76 356 256 346 -137 -277 -99 -634 -65 308 592 231 258 -27 -53 -17 -196 -189 -27 194 114 588 495 141 114 -374 -543 -529 -719 -744 -127 41 369 483 -49 59 -38 213 -72 202 206 151 345 -72 -498 -324 -198 -213 72 193 301 204 -278 -190 -503 -389 -421 -315 -306 -91 -36 -368 -332 270 -124 74 -96 77 425 266 334 324 223 22 -376 -524 -644 -560 -412 13 43 -99 7 48 -342 -300 -163 -51 304 299 145 397 312 274 185 230 287 328 -63 369 294 143 515 -93 -44 155 108 52 -262 -166 -321 151 -128 131 -80 211 57 206 169 -50 364 -67 -58 -234 -627 -643 -1162 -373 -107 152 0 561 636 427 415 154 251 -251 -303 -445 -161 -491 -97 -15 226 -90 -15 342 -81 226 80 377 269 358 -138 -287 -101 -653 -65 314 620 244 270 -28 -55 -17 -199 -194 -28 202 120 619 518 146 116 -372 -525 -526 -710 -741 -123 40 373 492 -50 60 -39 219 -74 207 210 152 340 -70 -483 -309 -187 -202 69 187 293 198 -267 -179 -470 -362 -393 -296 -291 -87 -34 -360 -325 263 -121 73 -94 77 428 268 333 317 213 21 -343 -497 -610 -512 -389 12 43 -99 7 47 -333 -294 -162 -51 308 305 149 409 325 285 191 234 287 323 -62 362 290 141 507 -92 -43 153 106 50 -248 -155 -301 143 -124 129 -80 212 58 200 165 -49 355 -65 -58 -229 -606 -619
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SQ 20250820T160036.9Z 9363.667094 352 1 52.04 2 30.99 144.77 18.31 223.85 0.00 1 0.00 1 0 22 2.997e-03 2.984e-03 8.853e-04 8.831e-04 3.506591e+03 5.569233e+01 2.460487e+02 -6.000000e+00 1.701926e+02 290.79 -2.00 20.00 -2.00 505.29 0.00e+00 6.766742e-04 2.473754e-05 3.886647e-05 -6.000000e+00 8.547552e-05 290.79 -2.00 20.00 -2.00 500.44 0.00e+00 5.901509e-02 1.741539e-02 2.321534e-02 -6.000000e+00 5.934451e-02 231.28 -2.00 3.47 -2.00 502.05 0.00e+00 1.166 0.000 489.00 513.00 1 7.6409e+00 1.3358e-03 2.7351e-03 -6.0000e+00 4.5551e-03 4.0804e-03 3.4542e-04 5.5771e-04 -6.0000e+00 1.1901e-03 7.8315e-04 1.1504e-03 8.4567e-05 2.7693e-05 -6.0000e+00 2.9510e-04 3.4201e-03 -3.2111e-05 10 0 0 10 0 0 97.68 18.51 0.92 0.00342 0.01140 16 3 1 4 0 3251.640 26.73 19.99 18.51 31.80 32.8 1042.99 -933 -227 -308 -48 97 258 386 415 478 145 210 -214 -414 -202 -305 -237 -103 118 179 118 260 276 255 73 367 459 201 137 -380 -344 -374 -257 -251 270 333 361 -53 85 -116 -297 -29 -120 176 307 150 181 460 201 260 -353 -648 -511 -719 -785 -302 137 311 700 -1 227 -71 343 84 191 154 91 182 -134 -290 -117 -72 -191 -211 21 57 258 -381 -203 -230 -378 -221 -447 -286 -188 -82 -250 -184 174 -119 123 106 178 63 409 245 240 274 -65 -247 -414 -632 -550 -431 -126 131 -177 -1 -313 -201 -112 -333 191 79 328 390 300 456 456 314 191 262 60 -162 309 214 99 431 60 101 171 223 -98 -278 -90 -400 -45 -94 -92 142 270 71 43 152 117 254 57 -231 -283 -476 -620 -901 -222 -311 -49 104 263 399 432 496 150 213 -229 -436 -209 -315 -246 -109 119 185 123 272 289 267 77 386 483 211 142 -384 -359 -384 -266 -248 275 349 379 -56 88 -119 -302 -30 -123 181 319 158 190 479 207 263 -349 -623 -512 -714 -789 -291 135 313 709 -1 231 -73 350 86 195 156 91 179 -130 -279 -111 -68 -181 -202 20 55 249 -364 -190 -228 -373 -205 -419 -271 -179 -79 -243 -179 169 -116 119 105 177 64 411 244 234 260 -61 -240 -396 -605 -502 -406 -123 130 -178 -1 -306 -195 -109 -329 191 80 335 400 309 471 472 323 193 261 59 -159 303 211 98 424 59 99 167 216 -94 -262 -84 -374 -42 -91 -90 141 271 72 44 156 120 260 57 -231 -277 -457 -595
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