File name: Pandora140s1_WashingtonDC_20250821_L2Fit_fwvt1c14d20220101p1-8.txt
File generation date: 20250822T051802.0Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c14p1-8
Local principal investigator: Luke Valin
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 140
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora140_OF_v3d20200721.txt
Instrument calibration file used: Pandora140s1_CF_v14d20220101.txt
Level 1 file used: Pandora140s1_WashingtonDC_20250821_L1_smca1c14d20220101p1-8.txt
Full location name: McMillan Reservoir
Short location name: WashingtonDC
Country of location: United States
Location latitude [deg]: 38.9218
Location longitude [deg]: -77.0124
Location altitude [m]: 58
Local noon date: 20250821
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: Modification of session 10 "Based on session 8 "Modif only on SO2 (WashingtonDC)"""
First and last pixel inside fitting window: 1637 1786
Nominal wavelengths inside fitting window [nm]: 492.0699 492.1908 492.3117 492.4326 492.5535 492.6743 492.7952 492.9160 493.0368 493.1576 493.2784 493.3991 493.5199 493.6406 493.7613 493.8820 494.0027 494.1233 494.2440 494.3646 494.4852 494.6058 494.7264 494.8469 494.9675 495.0880 495.2085 495.3290 495.4495 495.5699 495.6904 495.8108 495.9312 496.0516 496.1720 496.2923 496.4127 496.5330 496.6533 496.7736 496.8939 497.0141 497.1344 497.2546 497.3748 497.4950 497.6152 497.7353 497.8555 497.9756 498.0957 498.2158 498.3359 498.4559 498.5759 498.6960 498.8160 498.9360 499.0559 499.1759 499.2958 499.4157 499.5356 499.6555 499.7754 499.8953 500.0151 500.1349 500.2547 500.3745 500.4943 500.6140 500.7338 500.8535 500.9732 501.0929 501.2125 501.3322 501.4518 501.5714 501.6910 501.8106 501.9302 502.0497 502.1693 502.2888 502.4083 502.5278 502.6472 502.7667 502.8861 503.0055 503.1249 503.2443 503.3637 503.4830 503.6023 503.7216 503.8409 503.9602 504.0795 504.1987 504.3180 504.4372 504.5564 504.6755 504.7947 504.9138 505.0330 505.1521 505.2712 505.3902 505.5093 505.6283 505.7474 505.8664 505.9854 506.1043 506.2233 506.3422 506.4611 506.5801 506.6989 506.8178 506.9367 507.0555 507.1743 507.2931 507.4119 507.5307 507.6494 507.7682 507.8869 508.0056 508.1243 508.2429 508.3616 508.4802 508.5988 508.7174 508.8360 508.9546 509.0731 509.1916 509.3102 509.4287 509.5471 509.6656 509.7840 509.9025
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250821T135421.8Z 9364.579419 214 1 49.77 2 51.17 108.05 31.42 115.54 0.00 1 0.00 1 0 15 3.056e-03 3.038e-03 9.512e-04 9.491e-04 4.261606e+03 6.058143e+01 3.000319e+02 -6.000000e+00 1.735308e+02 290.73 -2.00 20.00 -2.00 505.27 0.00e+00 6.150595e-04 2.660775e-05 3.786265e-05 -6.000000e+00 8.715608e-05 290.73 -2.00 20.00 -2.00 500.43 0.00e+00 1.065765e-01 1.876027e-02 2.684688e-02 -6.000000e+00 6.051253e-02 231.21 -2.00 3.47 -2.00 502.03 0.00e+00 1.591 0.000 489.00 513.00 1 7.6924e+00 1.4415e-03 3.3454e-03 -6.0000e+00 4.6447e-03 2.1059e-03 3.7176e-04 6.6257e-04 -6.0000e+00 1.2134e-03 6.9743e-04 8.2368e-04 8.9992e-05 3.2574e-05 -6.0000e+00 3.0094e-04 3.0201e-03 -2.1007e-05 10 0 0 10 0 0 99.80 18.48 0.83 0.00302 0.00873 14 3 1 4 0 3554.420 26.62 20.00 18.48 26.03 32.2 997.45 -1003 -329 -348 380 15 416 448 589 574 208 239 -175 -339 -376 -248 -354 -258 58 170 64 161 330 216 269 138 486 221 153 -121 -491 -204 -375 -316 335 365 218 128 145 -273 -168 -63 -173 -180 218 151 233 247 103 24 -293 -523 -681 -762 -616 -93 69 346 304 32 111 265 248 104 255 186 -14 373 -151 -33 -69 -113 -302 -185 4 73 297 -123 -150 -508 -411 -349 -239 -156 -342 45 -281 -200 -1 -137 198 -34 162 226 310 281 272 285 20 -386 -517 -543 -452 -452 8 168 -135 80 -109 -422 -217 -128 -129 68 398 191 356 419 388 177 334 364 -66 -202 250 248 251 289 -19 173 60 296 -53 -338 -205 -453 -25 101 -79 5 257 250 -19 202 120 486 306 -271 -291 -601 -523 -953 -316 -345 388 15 445 487 606 588 224 254 -184 -351 -385 -253 -362 -268 62 174 66 167 342 224 280 145 506 229 157 -128 -507 -207 -383 -329 338 378 227 133 149 -277 -169 -64 -175 -185 225 158 243 256 105 24 -287 -530 -675 -748 -610 -94 68 346 307 33 112 267 251 106 259 187 -14 363 -146 -34 -69 -113 -302 -187 4 70 284 -124 -149 -498 -402 -342 -237 -155 -324 43 -271 -193 -1 -132 191 -34 159 226 309 276 263 268 19 -369 -487 -511 -433 -421 8 166 -135 79 -106 -407 -210 -126 -128 68 402 194 364 430 400 181 336 360 -65 -197 244 243 246 283 -19 169 59 286 -50 -318 -191 -422 -24 97 -78 5 257 252 -20 206 123 495 309 -270 -284 -578 -500
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SQ 20250821T142901.3Z 9364.603487 239 1 50.53 2 44.92 115.77 25.85 127.30 0.00 1 0.00 1 0 15 3.002e-03 2.969e-03 1.039e-03 1.036e-03 3.450583e+03 6.549802e+01 2.374144e+02 -6.000000e+00 1.704556e+02 290.73 -2.00 20.00 -2.00 505.28 0.00e+00 6.154786e-04 2.888703e-05 3.632884e-05 -6.000000e+00 8.561579e-05 290.73 -2.00 20.00 -2.00 500.45 0.00e+00 9.708017e-02 2.042823e-02 2.318975e-02 -6.000000e+00 5.944841e-02 231.21 -2.00 3.47 -2.00 502.04 0.00e+00 1.410 0.000 489.00 513.00 1 7.8467e+00 1.5639e-03 2.9361e-03 -6.0000e+00 4.5629e-03 3.7256e-03 4.0784e-04 5.4996e-04 -6.0000e+00 1.1922e-03 6.1466e-04 9.2369e-04 9.9144e-05 2.7385e-05 -6.0000e+00 2.9563e-04 4.4414e-03 -3.8419e-05 10 0 0 10 0 0 97.74 18.47 0.93 0.00444 0.01085 15 3 1 4 0 3368.250 26.62 19.99 18.47 26.88 32.4 1003.50 -651 -526 -385 111 163 307 588 440 487 151 333 -198 -342 -199 -391 -353 -125 39 157 216 0 270 145 165 293 458 90 153 -19 -498 -85 -408 -249 363 406 340 149 -65 -397 -273 -51 -323 -10 132 285 176 98 207 189 -124 -488 -729 -581 -539 -184 211 319 321 -137 2 119 162 115 171 283 250 174 59 -252 -236 -221 -261 -289 119 59 330 -272 -417 -274 -492 -280 -330 -273 -232 36 -219 -340 25 -245 57 74 86 104 439 98 113 310 -85 -338 -495 -673 -563 -362 83 41 -192 74 -44 -217 50 -471 1 364 184 271 553 465 428 336 14 179 89 -22 143 201 337 455 272 151 223 237 -161 -168 -316 -419 43 21 -171 57 155 217 -130 421 -39 330 203 -273 -261 -422 -597 -636 -521 -394 110 165 316 614 464 512 157 341 -200 -342 -195 -383 -348 -125 40 164 228 0 286 153 176 312 487 96 160 -19 -495 -83 -400 -250 374 429 362 158 -69 -412 -280 -52 -335 -11 139 303 187 104 216 193 -124 -475 -694 -547 -512 -179 210 326 331 -142 2 123 168 120 178 291 252 173 58 -245 -227 -211 -250 -280 117 59 322 -263 -396 -257 -461 -263 -313 -262 -224 35 -216 -336 25 -241 56 73 87 106 447 98 112 299 -81 -312 -450 -612 -521 -346 81 41 -195 74 -44 -213 49 -473 1 373 191 282 576 457 421 328 14 181 89 -22 143 201 336 453 271 151 222 233 -157 -160 -299 -397 41 21 -171 58 149 209 -126 408 -38 322 196 -260 -259 -412 -581
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