File name: Pandora177s1_WestportCT_20230909_L2Fit_fout2c7d20230401p1-8.txt File generation date: 20241124T030931.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 177 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora177_OF_v3d20201002.txt Instrument calibration file used: Pandora177s1_CF_v7d20230401.txt Level 1 file used: Pandora177s1_WestportCT_20230909_L1_smca1c7d20230401p1-8.txt Full location name: Westport - Sherwood Island State Park CTDEEP (USEPA AQS ID 09-001-9003) Short location name: WestportCT Country of location: USA Location latitude [deg]: 41.1183 Location longitude [deg]: -73.3367 Location altitude [m]: 4 Local noon date: 20230909 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 218 359 Nominal wavelengths inside fitting window [nm]: 305.1028 305.2437 305.3847 305.5256 305.6665 305.8074 305.9483 306.0891 306.2300 306.3709 306.5117 306.6525 306.7934 306.9342 307.0750 307.2157 307.3565 307.4973 307.6380 307.7788 307.9195 308.0602 308.2009 308.3416 308.4823 308.6230 308.7637 308.9043 309.0450 309.1856 309.3262 309.4668 309.6074 309.7480 309.8886 310.0291 310.1697 310.3102 310.4508 310.5913 310.7318 310.8723 311.0128 311.1533 311.2937 311.4342 311.5746 311.7151 311.8555 311.9959 312.1363 312.2767 312.4170 312.5574 312.6978 312.8381 312.9784 313.1188 313.2591 313.3994 313.5396 313.6799 313.8202 313.9604 314.1007 314.2409 314.3811 314.5213 314.6615 314.8017 314.9419 315.0821 315.2222 315.3623 315.5025 315.6426 315.7827 315.9228 316.0629 316.2030 316.3430 316.4831 316.6231 316.7631 316.9031 317.0432 317.1831 317.3231 317.4631 317.6031 317.7430 317.8829 318.0229 318.1628 318.3027 318.4426 318.5825 318.7223 318.8622 319.0020 319.1419 319.2817 319.4215 319.5613 319.7011 319.8409 319.9807 320.1204 320.2602 320.3999 320.5396 320.6793 320.8190 320.9587 321.0984 321.2381 321.3777 321.5174 321.6570 321.7966 321.9362 322.0758 322.2154 322.3550 322.4946 322.6341 322.7736 322.9132 323.0527 323.1922 323.3317 323.4712 323.6107 323.7501 323.8896 324.0290 324.1684 324.3079 324.4473 324.5867 324.7260 324.8654 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230909T131422.9Z 8652.551654 299 1 4.45 2 59.97 111.31 14.48 199.02 0.00 1 0.00 1 0 25 1.863e-02 1.222e-02 4.016e-03 1.611e-03 2.485731e-01 8.510514e-04 3.007738e-03 -6.000000e+00 1.121374e-02 229.76 -2.00 3.51 -2.00 316.78 0.00e+00 1.208978e-03 1.084911e-04 3.824056e-04 -6.000000e+00 5.002627e-04 288.27 -2.00 20.00 -2.00 315.97 0.00e+00 1.990 0.000 302.00 328.00 3 2.3449e+00 2.2310e-03 2.3691e-02 -6.0000e+00 2.7931e-02 -1.5079e-02 2.4895e-03 1.2808e-02 -6.0000e+00 3.0107e-02 1.1500e-03 1.4599e-03 6.2297e-03 -6.0000e+00 1.7966e-02 -5.7659e-03 6.9955e-04 1.7646e-03 -6.0000e+00 7.7100e-03 5.2344e-03 -1.0978e-05 4.9179e-05 2.0919e-05 -6.0000e+00 5.4833e-04 -8.5448e-03 0.0000e+00 12 9 9 12 1 1 96.80 23.12 0.37 -0.00854 -0.00863 21 55 1 5 0 201.880 26.41 20.01 23.12 31.91 22.4 1059.75 3347 69 -566 -5812 -3603 -4824 194 -265 -1125 -4088 -6765 -4723 -3009 -705 603 1113 779 2025 2688 2194 1242 -22 1286 1680 2931 920 -551 -254 -1036 -628 510 910 328 -3374 -6281 -5113 -3416 -1739 425 -878 -447 -591 574 352 691 842 -236 -373 -985 -207 1041 1022 1253 1242 711 1380 305 -478 -467 118 1070 2471 2871 2574 448 -1181 -1454 -624 1922 1720 1141 1614 1058 1157 183 -1647 -2558 -3317 -2140 -2697 -2524 -2603 -2728 -1554 -376 570 1218 1510 1734 1528 343 -810 -2000 -1089 -395 -306 640 1385 623 -551 -1341 -2370 -920 -641 -1459 -1727 -909 -963 970 1661 1450 1074 719 -31 -437 -535 83 219 975 432 665 725 1347 904 935 -661 -881 256 -186 -191 -875 -1119 -523 -65 322 172 703 763 614 -108 -545 -1553 476 11 -90 -906 -502 -658 27 -42 -193 -744 -1269 -829 -584 -154 147 292 215 573 784 664 385 -7 407 557 1012 331 -196 -86 -336 -202 172 333 118 -1254 -2307 -2029 -1350 -801 209 -497 -273 -378 371 230 451 546 -152 -235 -615 -130 684 667 863 891 527 1038 235 -368 -355 90 842 1929 2405 2252 393 -976 -1205 -513 1567 1566 1054 1530 999 1113 164 -1361 -2096 -2676 -1822 -2418 -2365 -2661 -2969 -1664 -425 683 1440 1816 2056 1840 387 -893 -2076 -1118 -430 -347 794 1752 826 -721 -1644 -2887 -1085 -790 -1834 -2304 -1258 -1321 1381 2492 2149 1592 1074 -43 -600 -704 109 304 1364 639 998 1069 1911 1236 1288 -879 -1136 334 -261 -270 -1296 -1698 -812 -100 521 277 1159 1275 1027 -177 -912 -2541 SS 20230909T131926.4Z 8652.555166 302 1 48.75 2 59.09 112.35 14.82 203.16 0.00 1 0.00 1 0 25 1.829e-02 1.164e-02 2.373e-03 7.076e-04 2.428857e-01 3.730720e-04 2.975439e-03 -6.000000e+00 1.100753e-02 229.76 -2.00 3.51 -2.00 317.62 0.00e+00 1.269292e-03 5.819907e-05 6.023333e-04 -6.000000e+00 4.910792e-04 288.27 -2.00 20.00 -2.00 316.79 0.00e+00 1.939 0.000 302.00 328.00 3 2.6337e+00 9.9143e-04 2.3163e-02 -6.0000e+00 2.7418e-02 -5.9860e-03 1.1122e-03 1.2658e-02 -6.0000e+00 2.9554e-02 3.4120e-03 6.7262e-04 6.1782e-03 -6.0000e+00 1.7636e-02 -9.5803e-03 3.3376e-04 1.7467e-03 -6.0000e+00 7.5680e-03 4.1434e-03 -4.5690e-05 2.2053e-05 2.0003e-05 -6.0000e+00 5.3826e-04 -8.3389e-03 0.0000e+00 12 8 8 10 0 0 99.39 23.08 0.31 -0.00834 -0.00868 215 49 1 5 0 226.700 26.41 20.00 23.08 32.63 22.4 1065.29 1362 -1270 -322 -4015 -3556 -4097 -2333 -1071 -1254 -5819 -7608 -4681 -2045 355 257 475 -274 1400 1299 2210 708 535 1947 1600 1839 134 -960 -1745 -1266 -1128 649 1372 466 -3616 -5911 -4601 -3910 -1351 -70 -801 -387 -30 370 390 1091 735 -29 -413 -912 -80 946 1165 1230 1227 572 1356 453 -292 -502 33 1300 2377 3059 2552 410 -1372 -1504 -978 1618 1671 1064 1730 1274 1312 -4 -1420 -2748 -3444 -2236 -2167 -2414 -2443 -2755 -1578 -265 311 1345 1374 1711 1374 519 -822 -1867 -797 -630 -314 570 1413 526 -527 -1564 -2268 -1135 -587 -1555 -1890 -1085 -932 771 1543 1519 1083 553 -50 -526 -585 -135 108 899 578 663 785 1238 814 809 -656 -959 423 47 -225 -885 -1264 -515 -25 294 104 621 835 610 22 -389 -1509 139 -142 -36 -430 -346 -388 -232 -118 -151 -751 -1002 -628 -300 59 48 95 -58 303 292 508 168 127 464 402 485 37 -259 -451 -310 -275 165 376 137 -1104 -1770 -1362 -1270 -506 -31 -401 -190 -15 192 205 569 382 -16 -229 -500 -44 546 717 727 754 364 874 298 -191 -326 21 873 1701 2340 2042 328 -1037 -1061 -686 1203 1384 953 1588 1164 1146 -3 -1064 -2102 -2590 -1610 -1749 -2179 -2404 -2890 -1729 -306 350 1576 1642 2014 1695 598 -872 -1859 -782 -659 -362 719 1762 689 -680 -1893 -2802 -1362 -735 -1929 -2490 -1483 -1328 1142 2406 2456 1752 858 -72 -707 -754 -175 147 1300 884 1029 1198 1820 1154 1093 -932 -1323 588 64 -328 -1353 -1980 -824 -42 515 191 1077 1466 1073 38 -706 -2680 SS 20230909T132420.7Z 8652.558573 305 1 4.84 2 58.24 113.38 15.21 206.99 0.00 1 0.00 1 0 17 1.803e-02 1.250e-02 3.597e-03 1.542e-03 2.402112e-01 8.164926e-04 2.902822e-03 -6.000000e+00 1.084945e-02 229.76 -2.00 3.51 -2.00 316.58 0.00e+00 1.133098e-03 9.988527e-05 3.542367e-04 -6.000000e+00 4.840194e-04 288.27 -2.00 20.00 -2.00 315.79 0.00e+00 1.893 0.000 302.00 328.00 3 2.4505e+00 2.1355e-03 2.2632e-02 -6.0000e+00 2.7024e-02 8.4700e-04 2.3780e-03 1.2346e-02 -6.0000e+00 2.9129e-02 -3.7612e-03 1.3849e-03 5.9941e-03 -6.0000e+00 1.7382e-02 -5.6125e-03 6.5809e-04 1.6803e-03 -6.0000e+00 7.4594e-03 5.2215e-03 -1.6568e-04 4.7059e-05 2.0762e-05 -6.0000e+00 5.3053e-04 -8.4340e-03 0.0000e+00 12 9 9 12 1 1 96.30 23.10 0.37 -0.00843 -0.00968 21 51 1 5 0 220.010 26.41 20.01 23.10 33.27 22.4 1068.47 2554 2403 154 -3870 -5607 -3454 -1839 343 -1038 -4301 -5827 -3959 -1729 -125 741 343 283 1889 816 2794 1455 687 1218 1715 1419 607 -697 -1363 -1104 -1294 1465 2005 1073 -3401 -6177 -4731 -4191 -1417 -258 -22 -580 35 381 340 1052 602 -303 -616 -1071 -184 1023 921 1379 1235 549 1417 690 -18 -873 129 729 2760 3009 2281 175 -1345 -1691 -935 1532 1783 797 1597 1195 1744 -335 -1207 -2702 -3570 -2108 -2334 -2448 -2274 -2696 -1635 -133 438 1421 1539 1676 1545 687 -849 -1922 -963 -701 -512 677 1386 647 -600 -1433 -2379 -1061 -643 -1491 -2173 -903 -980 815 1557 1615 1116 676 -28 -217 -331 -137 256 874 538 830 849 1332 781 936 -706 -640 449 172 -78 -924 -1134 -664 -69 141 102 691 877 500 114 -649 -1704 382 385 25 -614 -907 -528 -295 61 -183 -806 -1110 -775 -371 -30 201 100 87 590 267 926 495 235 423 623 499 219 -249 -507 -390 -454 529 718 411 -1359 -2433 -1838 -1786 -696 -137 -13 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