File name: Pandora177s1_WestportCT_20231227_L2Fit_fwvt1c3d20221101p1-8.txt File generation date: 20240313T200053.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 177 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora177_OF_v3d20201002.txt Instrument calibration file used: Pandora177s1_CF_v3d20221101.txt Level 1 file used: Pandora177s1_WestportCT_20231227_L1_smca1c3d20221101p1-8.txt Full location name: Westport - Sherwood Island State Park CTDEEP (USEPA AQS ID 09-001-9003) Short location name: WestportCT Country of location: USA Location latitude [deg]: 41.1183 Location longitude [deg]: -73.3367 Location altitude [m]: 4 Local noon date: 20231227 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1637 1786 Nominal wavelengths inside fitting window [nm]: 492.0444 492.1655 492.2866 492.4076 492.5286 492.6497 492.7707 492.8916 493.0126 493.1336 493.2545 493.3754 493.4963 493.6172 493.7381 493.8589 493.9797 494.1005 494.2213 494.3421 494.4629 494.5836 494.7043 494.8251 494.9457 495.0664 495.1871 495.3077 495.4283 495.5489 495.6695 495.7901 495.9107 496.0312 496.1517 496.2722 496.3927 496.5132 496.6336 496.7541 496.8745 496.9949 497.1152 497.2356 497.3560 497.4763 497.5966 497.7169 497.8372 497.9574 498.0777 498.1979 498.3181 498.4383 498.5585 498.6786 498.7988 498.9189 499.0390 499.1591 499.2792 499.3992 499.5192 499.6393 499.7593 499.8792 499.9992 500.1192 500.2391 500.3590 500.4789 500.5988 500.7186 500.8385 500.9583 501.0781 501.1979 501.3177 501.4374 501.5572 501.6769 501.7966 501.9163 502.0360 502.1556 502.2752 502.3949 502.5145 502.6340 502.7536 502.8732 502.9927 503.1122 503.2317 503.3512 503.4706 503.5901 503.7095 503.8289 503.9483 504.0677 504.1870 504.3064 504.4257 504.5450 504.6643 504.7835 504.9028 505.0220 505.1412 505.2604 505.3796 505.4988 505.6179 505.7371 505.8562 505.9753 506.0943 506.2134 506.3324 506.4515 506.5705 506.6894 506.8084 506.9274 507.0463 507.1652 507.2841 507.4030 507.5219 507.6407 507.7595 507.8783 507.9971 508.1159 508.2347 508.3534 508.4721 508.5908 508.7095 508.8282 508.9468 509.0655 509.1841 509.3027 509.4213 509.5398 509.6584 509.7769 509.8954 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20231227T133417.0Z 8761.565475 312 1 49.26 2 79.38 134.29 93.91 311.75 0.00 1 0.00 1 0 22 3.324e-03 3.316e-03 4.932e-04 4.922e-04 5.513980e+03 3.446843e+01 3.734428e+02 -6.000000e+00 2.000752e+02 276.31 -2.00 20.00 -2.00 505.28 0.00e+00 7.230093e-04 1.405783e-05 4.739098e-05 -6.000000e+00 9.624835e-05 276.31 -2.00 20.00 -2.00 500.47 0.00e+00 4.566179e-01 1.028828e-02 4.548145e-02 -6.000000e+00 6.942882e-02 223.12 -2.00 3.51 -2.00 502.06 0.00e+00 5.221 0.003 489.00 513.00 1 5.4274e+00 7.9253e-04 8.4658e-03 -6.0000e+00 5.3534e-03 2.5279e-04 1.9526e-04 1.1275e-03 -6.0000e+00 1.3396e-03 3.8843e-03 -7.8062e-04 6.5556e-05 2.9626e-05 -6.0000e+00 4.6975e-04 4.7590e-02 -2.5353e-05 10 0 0 10 0 0 98.74 23.05 1.57 0.04759 0.04217 47 11 1 4 0 1047.920 26.41 20.00 23.05 11.86 22.5 935.32 -308 -166 -79 -235 -52 50 461 409 349 213 185 -28 -251 -237 -454 -257 -98 115 52 -46 -48 129 424 513 493 363 181 32 -326 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125 299 389 555 631 518 459 285 376 433 655 561 458 367 84 88 267 134 -122 -343 -334 -369 -214 -73 5 -272 -235 -69 57 163 206 260 127 -44 -374 -302 -347 25 SQ 20231227T134006.5Z 8761.569520 315 1 26.81 2 78.61 135.40 94.69 312.72 0.00 1 0.00 1 0 15 3.269e-03 3.266e-03 1.681e-04 1.679e-04 5.174588e+03 1.155246e+01 3.565954e+02 -6.000000e+00 1.967573e+02 276.31 -2.00 20.00 -2.00 505.28 0.00e+00 6.473953e-04 4.788416e-06 4.346885e-05 -6.000000e+00 9.466254e-05 276.31 -2.00 20.00 -2.00 500.51 0.00e+00 4.097824e-01 3.492943e-03 4.196875e-02 -6.000000e+00 6.830359e-02 223.12 -2.00 3.51 -2.00 502.09 0.00e+00 4.894 0.002 489.00 513.00 1 2.9605e+00 2.6905e-04 7.9117e-03 -6.0000e+00 5.2663e-03 -1.3980e-03 6.6521e-05 1.0534e-03 -6.0000e+00 1.3186e-03 4.8217e-02 -3.7993e-04 2.2409e-05 2.9693e-05 -6.0000e+00 4.6203e-04 5.3930e-02 -9.8708e-05 12 1 1 12 1 1 89.96 23.06 1.58 0.05393 0.05130 265 111 1 4 0 100.760 26.41 19.99 23.06 12.01 22.5 936.58 -255 -146 -80 -130 -75 224 440 507 342 160 125 -12 -167 -274 -298 -268 -114 113 49 -66 -22 215 421 576 514 289 168 -56 -374 -479 -290 -53 176 218 -72 -359 -314 -121 30 96 199 260 291 402 482 417 291 124 -101 -332 -560 -654 -617 -407 -243 -257 -372 -415 -196 124 440 495 434 330 216 68 63 85 -17 -157 -183 -89 26 62 -163 -463 -519 -307 -231 -242 -358 -438 -485 -378 -309 -340 -270 -131 42 211 422 627 566 353 142 23 -55 -153 -340 -508 -495 -333 -196 -263 -570 -758 -652 -345 -3 199 204 134 102 194 382 613 678 559 393 294 284 417 612 567 416 250 161 146 223 176 -119 -287 -331 -242 -149 -26 -113 -237 -223 -55 74 169 248 217 113 -101 -317 -374 -212 -13 -250 -144 -79 -131 -76 229 455 528 356 166 128 -12 -167 -273 -304 -268 -116 116 52 -68 -23 223 437 599 534 300 173 -57 -387 -487 -291 -54 180 221 -74 -375 -327 -125 31 98 203 267 300 418 503 435 302 127 -102 -329 -560 -645 -605 -402 -244 -256 -377 -426 -201 127 452 508 446 338 220 69 62 83 -16 -156 -181 -88 25 60 -159 -452 -502 -301 -225 -236 -349 -430 -467 -367 -302 -335 -267 -130 41 210 420 628 569 355 141 22 -53 -148 -324 -481 -469 -321 -188 -258 -557 -748 -643 -338 -3 195 201 134 103 197 380 610 677 558 391 297 284 413 601 558 410 248 159 144 219 173 -116 -278 -317 -232 -143 -25 -111 -237 -220 -54 75 171 251 220 114 -102 -315 -366 -206 -13 SQ 20231227T134505.3Z 8761.572979 318 1 26.89 2 77.95 136.36 95.35 313.55 0.00 1 0.00 1 0 15 3.188e-03 3.179e-03 1.129e-04 1.127e-04 5.020609e+03 7.801130e+00 3.436868e+02 -6.000000e+00 1.918678e+02 276.31 -2.00 20.00 -2.00 505.29 0.00e+00 6.306218e-04 3.210264e-06 4.265124e-05 -6.000000e+00 9.230204e-05 276.31 -2.00 20.00 -2.00 500.47 0.00e+00 3.841858e-01 2.350618e-03 4.154056e-02 -6.000000e+00 6.658580e-02 223.12 -2.00 3.51 -2.00 502.06 0.00e+00 4.648 0.002 489.00 513.00 1 2.1409e+00 1.8093e-04 7.5759e-03 -6.0000e+00 5.1341e-03 7.8321e-04 4.4812e-05 1.0295e-03 -6.0000e+00 1.2849e-03 1.1359e-01 -9.0862e-04 1.5066e-05 2.7233e-05 -6.0000e+00 4.5049e-04 5.2409e-02 -6.0930e-05 10 0 0 10 0 0 98.95 23.05 1.59 0.05241 0.04611 703 162 1 4 0 38.240 26.41 20.02 23.05 12.29 22.6 938.89 -213 -77 -54 -126 -75 185 416 451 322 167 134 19 -141 -261 -324 -284 -123 91 32 -116 -34 200 434 581 504 313 159 -25 -373 -428 -259 2 204 235 -93 -397 -337 -143 -2 103 175 255 303 381 443 387 278 82 -97 -347 -516 -625 -590 -360 -197 -275 -393 -440 -192 118 409 464 399 312 188 54 62 80 -27 -158 -150 -58 61 94 -137 -447 -518 -310 -208 -222 -334 -449 -454 -368 -302 -304 -289 -129 45 220 422 612 552 324 81 12 -67 -121 -323 -479 -504 -305 -196 -263 -572 -773 -643 -346 3 201 236 101 109 208 347 538 668 581 404 279 303 407 585 597 412 225 178 147 239 170 -88 -337 -325 -260 -142 -2 -139 -256 -219 -72 55 175 232 202 110 -68 -283 -341 -205 -5 -207 -76 -55 -125 -77 192 438 462 329 175 139 20 -143 -264 -327 -288 -127 95 33 -121 -36 209 455 609 529 328 165 -25 -379 -427 -264 2 205 240 -97 -418 -354 -149 -3 106 180 264 316 399 466 408 291 85 -99 -347 -506 -624 -586 -360 -194 -276 -402 -455 -199 122 423 480 400 322 193 55 63 79 -26 -154 -146 -57 59 92 -135 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