File name: Pandora177s1_WestportCT_20240307_L2Fit_fwvt1c5d20230401p1-8.txt File generation date: 20240829T173431.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 177 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora177_OF_v3d20201002.txt Instrument calibration file used: Pandora177s1_CF_v5d20230401.txt Level 1 file used: Pandora177s1_WestportCT_20240307_L1_smca1c5d20230401p1-8.txt Full location name: Westport - Sherwood Island State Park CTDEEP (USEPA AQS ID 09-001-9003) Short location name: WestportCT Country of location: USA Location latitude [deg]: 41.1183 Location longitude [deg]: -73.3367 Location altitude [m]: 4 Local noon date: 20240307 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1637 1786 Nominal wavelengths inside fitting window [nm]: 492.0731 492.1942 492.3153 492.4364 492.5575 492.6786 492.7996 492.9206 493.0417 493.1626 493.2836 493.4046 493.5255 493.6464 493.7674 493.8882 494.0091 494.1300 494.2508 494.3716 494.4924 494.6132 494.7340 494.8547 494.9755 495.0962 495.2169 495.3376 495.4582 495.5789 495.6995 495.8201 495.9407 496.0613 496.1818 496.3024 496.4229 496.5434 496.6639 496.7844 496.9048 497.0253 497.1457 497.2661 497.3865 497.5068 497.6272 497.7475 497.8678 497.9881 498.1084 498.2287 498.3489 498.4692 498.5894 498.7096 498.8297 498.9499 499.0700 499.1901 499.3103 499.4303 499.5504 499.6705 499.7905 499.9105 500.0305 500.1505 500.2705 500.3904 500.5103 500.6302 500.7501 500.8700 500.9899 501.1097 501.2295 501.3493 501.4691 501.5889 501.7086 501.8284 501.9481 502.0678 502.1875 502.3071 502.4268 502.5464 502.6660 502.7856 502.9052 503.0248 503.1443 503.2638 503.3833 503.5028 503.6223 503.7417 503.8612 503.9806 504.1000 504.2194 504.3387 504.4581 504.5774 504.6967 504.8160 504.9353 505.0545 505.1738 505.2930 505.4122 505.5314 505.6505 505.7697 505.8888 506.0079 506.1270 506.2461 506.3652 506.4842 506.6032 506.7223 506.8412 506.9602 507.0792 507.1981 507.3170 507.4359 507.5548 507.6737 507.7925 507.9114 508.0302 508.1490 508.2677 508.3865 508.5052 508.6240 508.7427 508.8614 508.9800 509.0987 509.2173 509.3359 509.4545 509.5731 509.6917 509.8102 509.9288 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240307T144633.6Z 8832.615667 185 1 30.70 2 55.76 137.06 64.77 181.74 0.00 1 0.00 1 0 15 3.570e-03 3.550e-03 1.424e-03 1.418e-03 2.517563e+03 9.461596e+01 1.640593e+02 -6.000000e+00 2.155003e+02 276.49 -2.00 20.00 -2.00 505.26 0.00e+00 3.765800e-04 4.035286e-05 2.321602e-05 -6.000000e+00 1.034703e-04 276.49 -2.00 20.00 -2.00 500.27 0.00e+00 2.065834e-02 2.998613e-02 2.444777e-02 -6.000000e+00 7.492151e-02 225.84 -2.00 3.51 -2.00 501.90 0.00e+00 1.772 0.000 489.00 513.00 1 7.6178e+00 2.3124e-03 3.2827e-03 -6.0000e+00 5.7752e-03 1.7001e-02 5.7325e-04 5.4932e-04 -6.0000e+00 1.4467e-03 7.4131e-04 -5.2812e-04 1.9062e-04 9.1863e-06 -6.0000e+00 5.0402e-04 1.0374e-02 -7.8593e-05 12 1 1 12 1 1 99.83 23.05 1.92 0.01037 0.00671 9 4 1 4 0 3069.600 26.41 19.98 23.05 14.65 23.4 962.53 -642 -492 -359 -158 -192 -55 270 220 317 193 220 -272 29 -480 -568 -119 -299 -2 -169 -70 68 227 402 486 609 229 302 37 -18 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179 -54 235 277 574 688 419 211 175 209 219 599 626 462 355 241 118 472 289 -107 -365 -501 -166 -351 83 117 -376 -467 -554 -240 162 349 408 204 -102 -552 -455 -357 -278 SQ 20240307T151010.3Z 8832.632063 200 1 49.14 2 52.91 143.40 65.05 187.56 0.00 1 0.00 1 0 15 3.179e-03 3.166e-03 8.299e-04 8.256e-04 2.540886e+03 5.413952e+01 1.636063e+02 -6.000000e+00 1.919059e+02 276.49 -2.00 20.00 -2.00 505.15 0.00e+00 2.606631e-04 2.338033e-05 1.976106e-05 -6.000000e+00 9.213795e-05 276.49 -2.00 20.00 -2.00 500.22 0.00e+00 -6.158744e-02 1.748884e-02 2.382777e-02 -6.000000e+00 6.670830e-02 225.84 -2.00 3.51 -2.00 501.81 0.00e+00 1.654 0.000 489.00 513.00 1 7.0701e+00 1.3489e-03 3.1109e-03 -6.0000e+00 5.1422e-03 1.8304e-02 3.3813e-04 5.3286e-04 -6.0000e+00 1.2878e-03 1.3138e-03 -3.9760e-04 1.1174e-04 9.8048e-06 -6.0000e+00 4.4881e-04 8.9254e-03 -5.5070e-05 10 0 0 10 0 0 99.97 23.04 1.96 0.00893 0.00617 30 7 1 4 0 1637.770 26.41 20.00 23.04 15.90 23.4 970.84 -280 -330 -195 -266 -211 16 310 345 178 260 213 -67 -87 -505 -455 -442 -257 -4 1 -43 -155 179 272 408 540 452 137 70 -257 -464 -132 -123 419 302 20 -162 -382 -135 5 303 450 190 249 573 387 236 319 84 174 -167 -557 -573 -590 -170 33 -303 -389 -393 -237 112 349 429 332 315 36 217 93 68 65 40 -1 -68 141 159 -49 -355 -640 -274 -146 -65 -258 -319 -513 -552 -272 -350 -348 -151 -88 219 467 431 616 230 -82 -63 55 -61 -446 -359 -310 -135 -141 -98 -350 -601 -626 -371 314 112 211 64 148 118 462 435 473 508 464 328 319 220 490 687 431 368 192 90 166 95 14 -499 -417 -399 -91 11 87 -210 -425 -297 -41 230 180 80 154 -39 -460 -372 -384 -116 -267 -318 -192 -269 -218 17 330 370 191 276 224 -70 -89 -516 -463 -451 -266 -5 1 -46 -169 194 295 444 586 490 148 74 -269 -477 -134 -125 431 317 21 -175 -413 -144 5 319 473 201 265 612 416 254 341 88 180 -169 -556 -563 -576 -167 32 -308 -402 -410 -248 118 365 449 347 329 37 222 94 68 64 40 -1 -66 138 157 -49 -351 -629 -266 -140 -62 -248 -309 -501 -544 -269 -349 -349 -152 -89 221 472 440 630 236 -84 -63 54 -59 -425 -339 -293 -129 -138 -98 -355 -571 -593 -349 315 105 199 61 143 115 450 426 463 496 450 315 303 208 458 640 402 344 180 84 154 88 13 -455 -376 -359 -82 10 80 -196 -402 -284 -39 221 174 78 148 -38 -434 -347 -354 -107 SQ 20240307T151928.0Z 8832.638518 204 1 5.96 2 51.89 146.03 65.27 189.83 0.00 1 0.00 1 0 15 2.957e-03 2.967e-03 1.082e-04 1.079e-04 2.146872e+03 7.029879e+00 1.407564e+02 -6.000000e+00 1.784781e+02 276.50 -2.00 20.00 -2.00 505.28 0.00e+00 1.955486e-04 3.063621e-06 1.615103e-05 -6.000000e+00 8.569250e-05 276.50 -2.00 20.00 -2.00 500.43 0.00e+00 -3.032638e-02 2.256904e-03 2.082406e-02 -6.000000e+00 6.204506e-02 225.84 -2.00 3.51 -2.00 502.03 0.00e+00 1.617 0.000 489.00 513.00 1 1.2454e+00 1.7358e-04 2.9050e-03 -6.0000e+00 4.7827e-03 8.5937e-03 4.3395e-05 4.7129e-04 -6.0000e+00 1.1979e-03 4.4689e-01 -5.6041e-04 1.4675e-05 6.9957e-06 -6.0000e+00 4.1742e-04 1.0470e-02 -7.1254e-05 10 0 0 10 0 0 94.92 23.03 1.87 0.01047 0.00658 882 203 1 4 0 6.600 26.41 19.99 23.03 16.34 23.6 974.40 -308 -193 -152 -258 -171 79 341 429 314 155 128 34 -97 -232 -322 -348 -166 38 25 -111 -70 168 419 589 535 366 216 66 -264 -434 -286 -54 181 264 -16 -325 -303 -124 5 82 187 279 289 413 478 416 303 170 -36 -256 -437 -565 -564 -353 -189 -216 -376 -450 -264 61 361 444 439 327 229 71 64 87 57 -96 -104 -47 69 166 -70 -403 -502 -292 -168 -150 -265 -379 -404 -341 -272 -289 -277 -161 -13 115 322 529 517 314 62 -14 -106 -168 -302 -390 -352 -199 -61 -111 -446 -696 -620 -301 -1 229 242 117 112 129 237 393 558 477 366 291 299 387 560 505 358 183 122 132 189 161 -73 -292 -351 -254 -126 54 -81 -195 -223 -108 17 113 207 170 57 -156 -346 -390 -188 33 -301 -189 -153 -266 -181 84 350 443 324 159 130 36 -102 -242 -335 -364 -175 39 26 -116 -74 177 440 619 563 384 226 68 -268 -433 -299 -56 181 268 -17 -341 -318 -129 5 84 191 286 299 429 498 434 314 175 -36 -253 -449 -571 -567 -356 -183 -214 -378 -458 -269 62 367 452 447 332 231 71 63 85 55 -91 -99 -45 66 160 -67 -389 -480 -276 -166 -149 -249 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