File name: Pandora177s1_WestportCT_20240515_L2Fit_fout2c7d20230401p1-8.txt File generation date: 20241124T055313.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 177 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora177_OF_v3d20201002.txt Instrument calibration file used: Pandora177s1_CF_v7d20230401.txt Level 1 file used: Pandora177s1_WestportCT_20240515_L1_smca1c7d20230401p1-8.txt Full location name: Westport - Sherwood Island State Park CTDEEP (USEPA AQS ID 09-001-9003) Short location name: WestportCT Country of location: USA Location latitude [deg]: 41.1183 Location longitude [deg]: -73.3367 Location altitude [m]: 4 Local noon date: 20240515 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 218 359 Nominal wavelengths inside fitting window [nm]: 305.1028 305.2437 305.3847 305.5256 305.6665 305.8074 305.9483 306.0891 306.2300 306.3709 306.5117 306.6525 306.7934 306.9342 307.0750 307.2157 307.3565 307.4973 307.6380 307.7788 307.9195 308.0602 308.2009 308.3416 308.4823 308.6230 308.7637 308.9043 309.0450 309.1856 309.3262 309.4668 309.6074 309.7480 309.8886 310.0291 310.1697 310.3102 310.4508 310.5913 310.7318 310.8723 311.0128 311.1533 311.2937 311.4342 311.5746 311.7151 311.8555 311.9959 312.1363 312.2767 312.4170 312.5574 312.6978 312.8381 312.9784 313.1188 313.2591 313.3994 313.5396 313.6799 313.8202 313.9604 314.1007 314.2409 314.3811 314.5213 314.6615 314.8017 314.9419 315.0821 315.2222 315.3623 315.5025 315.6426 315.7827 315.9228 316.0629 316.2030 316.3430 316.4831 316.6231 316.7631 316.9031 317.0432 317.1831 317.3231 317.4631 317.6031 317.7430 317.8829 318.0229 318.1628 318.3027 318.4426 318.5825 318.7223 318.8622 319.0020 319.1419 319.2817 319.4215 319.5613 319.7011 319.8409 319.9807 320.1204 320.2602 320.3999 320.5396 320.6793 320.8190 320.9587 321.0984 321.2381 321.3777 321.5174 321.6570 321.7966 321.9362 322.0758 322.2154 322.3550 322.4946 322.6341 322.7736 322.9132 323.0527 323.1922 323.3317 323.4712 323.6107 323.7501 323.8896 324.0290 324.1684 324.3079 324.4473 324.5867 324.7260 324.8654 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240515T205114.0Z 8901.868912 497 1 32.03 2 55.43 265.81 43.63 115.57 0.00 1 0.00 1 0 25 4.049e-02 1.497e-02 3.540e-02 7.852e-03 2.737375e-01 4.156923e-03 3.364987e-03 -6.000000e+00 2.448732e-02 231.19 -2.00 3.51 -2.00 318.17 0.00e+00 1.474424e-03 7.388889e-04 9.994437e-04 -6.000000e+00 1.066226e-03 283.65 -2.00 20.00 -2.00 317.41 0.00e+00 1.757 0.000 302.00 328.00 3 6.0534e+00 1.1194e-02 2.2884e-02 -6.0000e+00 6.1308e-02 4.9134e-02 1.2623e-02 1.4508e-02 -6.0000e+00 6.6076e-02 1.5835e-02 7.9762e-03 7.1648e-03 -6.0000e+00 3.9268e-02 -1.7274e-02 4.0446e-03 2.0611e-03 -6.0000e+00 1.6718e-02 1.4648e-04 1.0288e-03 2.4758e-04 2.2009e-05 -6.0000e+00 1.1919e-03 -6.7841e-03 0.0000e+00 12 9 9 12 9 1 99.99 23.19 0.95 -0.00678 0.00095 10 4 1 5 0 2911.430 26.51 20.00 23.19 19.26 24.6 998.43 -4079 -10181 2254 -22739 -1605 -7483 13506 10288 -4446 -9389 -11789 668 -6371 8979 -2608 4244 -3393 7597 7715 -2559 8622 -633 1151 -609 5814 -3679 1764 -677 -712 4936 -4076 6138 -3598 -4634 -9050 -2621 6426 -4180 2499 -3192 -3754 -1975 -2075 -1668 2556 -318 2499 1730 -3489 609 1456 781 -176 1399 1094 1925 421 2519 374 -1464 2026 1798 4510 1140 3242 -2247 -1470 -768 1574 1433 -229 2547 664 2314 237 -1752 -1805 -5341 -1232 -1796 -2696 -2962 -1679 -1257 858 460 1316 767 1492 1021 -708 -856 -1616 -285 -97 -871 359 974 1572 -1000 -1473 -5033 -1746 90 216 -1933 -1617 -971 318 1797 1209 2077 -642 188 -334 -704 -13 -463 1803 -280 1876 516 1977 1315 1314 -295 -2267 500 -1270 -796 -716 -716 -551 409 63 -228 1532 901 321 -170 -672 -1551 -296 -844 164 -1987 -111 -534 840 743 -404 -921 -1196 64 -741 1040 -384 634 -575 1203 1270 -482 1473 -119 217 -123 1163 -824 365 -136 -138 907 -880 1310 -899 -1166 -2286 -626 1559 -1340 886 -1355 -1732 -934 -1005 -811 1194 -152 1141 780 -1643 282 707 409 -98 801 646 1151 257 1494 223 -897 1256 1206 3172 863 2347 -1596 -971 -508 1113 1128 -197 2181 571 1864 180 -1219 -1233 -3724 -887 -1462 -2317 -2777 -1649 -1299 926 531 1580 941 1789 1172 -763 -841 -1594 -279 -102 -955 430 1259 2091 -1326 -1814 -5956 -2096 112 267 -2578 -2244 -1402 480 2836 1989 3368 -1019 274 -453 -984 -18 -646 2623 -435 2885 787 2869 1964 1870 -405 -3078 679 -1880 -1252 -1169 -1194 -886 684 112 -421 2851 1706 609 -316 -1204 -2708 SS 20240515T210551.5Z 8901.879069 510 1 49.24 2 58.18 268.31 41.27 119.34 0.00 1 0.00 1 0 17 2.058e-02 1.116e-02 6.886e-03 1.553e-03 2.832107e-01 8.160480e-04 3.416848e-03 -6.000000e+00 1.244082e-02 231.19 -2.00 3.51 -2.00 318.07 0.00e+00 1.727505e-03 1.429935e-04 6.953907e-04 -6.000000e+00 5.418897e-04 283.65 -2.00 20.00 -2.00 317.32 0.00e+00 1.890 0.000 302.00 328.00 3 3.9583e+00 2.1962e-03 2.4179e-02 -6.0000e+00 3.1147e-02 1.9709e-02 2.4731e-03 1.4821e-02 -6.0000e+00 3.3573e-02 2.2303e-03 1.5613e-03 7.3588e-03 -6.0000e+00 1.9952e-02 -9.3584e-03 7.9306e-04 2.2335e-03 -6.0000e+00 8.4910e-03 1.0506e-03 1.3930e-04 4.8398e-05 2.4788e-05 -6.0000e+00 6.0576e-04 -4.5081e-03 0.0000e+00 12 8 8 10 0 0 99.96 23.18 0.32 -0.00451 -0.00346 53 12 1 5 0 928.960 26.51 19.99 23.18 19.72 24.7 1002.12 -1941 -2766 -2716 -4805 -4614 -5848 -5637 1226 -4108 -7095 -5880 -5929 -2300 -1698 -522 -1368 -1344 1191 1333 3012 191 360 949 483 59 -1604 -531 -2911 -869 759 575 1181 1231 -4477 -6463 -4979 -4286 -520 -94 -797 -238 -331 947 655 1101 592 -58 -225 -827 653 1243 1369 1562 1164 1022 1666 -154 -471 -283 -34 1395 2781 3084 2093 -74 -1110 -1415 -866 2185 1395 875 1498 580 1228 -493 -1533 -2542 -2964 -1841 -2107 -2386 -2717 -2724 -1640 -376 240 1277 1285 1732 1384 477 -1010 -1997 -809 -966 -235 521 1615 387 -450 -1281 -2149 -902 -644 -1627 -2033 -919 -850 974 1438 1331 810 518 -173 -178 -495 -89 299 936 372 603 801 1069 634 856 -635 -472 570 -120 -429 -1044 -1240 -664 79 185 86 694 940 615 10 -478 -1381 -143 -222 -218 -367 -323 -403 -416 95 -365 -667 -552 -593 -253 -216 -75 -215 -223 201 234 539 36 67 180 97 13 -353 -113 -605 -170 147 120 269 299 -1152 -1631 -1245 -1181 -164 -35 -338 -109 -158 458 321 539 290 -28 -107 -395 314 631 744 898 700 633 1048 -100 -303 -179 -22 916 1947 2325 1512 -53 -833 -999 -613 1640 1068 724 1266 488 979 -406 -1149 -1770 -2042 -1349 -1745 -2014 -2510 -2676 -1686 -407 276 1524 1561 2065 1581 509 -996 -1859 -822 -962 -258 627 2094 527 -603 -1602 -2511 -1020 -761 -2078 -2755 -1288 -1247 1490 2327 2054 1253 838 -262 -250 -668 -121 427 1419 594 973 1263 1625 929 1192 -853 -614 754 -171 -659 -1679 -2046 -1123 140 314 153 1258 1720 1125 18 -827 -2543 SS 20240515T211059.5Z 8901.882633 513 1 48.77 2 59.15 269.17 40.46 120.73 0.00 1 0.00 1 0 17 2.074e-02 1.092e-02 5.019e-03 1.102e-03 2.899287e-01 5.862632e-04 3.469377e-03 -6.000000e+00 1.254162e-02 231.19 -2.00 3.51 -2.00 318.09 0.00e+00 1.700543e-03 1.026932e-04 6.513734e-04 -6.000000e+00 5.462836e-04 283.65 -2.00 20.00 -2.00 317.35 0.00e+00 1.942 0.000 302.00 328.00 3 3.3690e+00 1.5767e-03 2.4778e-02 -6.0000e+00 3.1399e-02 1.3632e-02 1.7734e-03 1.5103e-02 -6.0000e+00 3.3845e-02 4.8709e-03 1.1216e-03 7.5226e-03 -6.0000e+00 2.0113e-02 -1.0490e-02 5.7015e-04 2.3101e-03 -6.0000e+00 8.5597e-03 1.7840e-03 9.4162e-05 3.4375e-05 2.4210e-05 -6.0000e+00 6.1067e-04 -4.4728e-03 0.0000e+00 12 8 8 10 0 0 99.81 23.18 0.41 -0.00447 -0.00377 82 19 1 5 0 594.710 26.51 19.99 23.18 19.94 24.6 1003.44 333 -468 -691 -5859 -2530 -8687 -2657 -5415 -3163 -8069 -7069 -5093 -3053 -804 -679 -644 -2478 1195 374 2804 825 1347 1850 826 655 -746 -1972 -2421 -1125 -207 1031 1607 575 -3544 -5933 -4103 -3539 -232 -68 -506 -699 57 687 103 1261 370 407 -643 -454 136 1331 1345 1186 1157 292 1440 -66 -361 -685 169 1783 2628 3061 1996 -26 -1318 -1069 -1080 2041 1349 1009 1539 883 1047 -507 -1519 -2884 -2987 -1917 -1999 -2267 -2459 -2734 -1639 -48 310 1445 1351 1804 1394 623 -751 -1860 -411 -614 -299 533 1311 475 -422 -1457 -1974 -666 -522 -1728 -2050 -1011 -786 757 1402 1354 881 411 -172 -464 -331 -81 184 877 448 726 768 1151 626 735 -669 -557 437 -94 -354 -1020 -1149 -515 -68 254 93 678 811 652 -68 -335 -1440 23 -35 -52 -437 -167 -596 -184 -434 -270 -745 -654 -493 -331 -99 -96 -99 -410 199 66 497 151 246 344 164 137 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