File name: Pandora177s1_WestportCT_20240909_L2Fit_fout2c7d20230401p1-8.txt File generation date: 20241124T070534.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 177 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora177_OF_v3d20201002.txt Instrument calibration file used: Pandora177s1_CF_v7d20230401.txt Level 1 file used: Pandora177s1_WestportCT_20240909_L1_smca1c7d20230401p1-8.txt Full location name: Westport - Sherwood Island State Park CTDEEP (USEPA AQS ID 09-001-9003) Short location name: WestportCT Country of location: USA Location latitude [deg]: 41.1183 Location longitude [deg]: -73.3367 Location altitude [m]: 4 Local noon date: 20240909 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 218 359 Nominal wavelengths inside fitting window [nm]: 305.1028 305.2437 305.3847 305.5256 305.6665 305.8074 305.9483 306.0891 306.2300 306.3709 306.5117 306.6525 306.7934 306.9342 307.0750 307.2157 307.3565 307.4973 307.6380 307.7788 307.9195 308.0602 308.2009 308.3416 308.4823 308.6230 308.7637 308.9043 309.0450 309.1856 309.3262 309.4668 309.6074 309.7480 309.8886 310.0291 310.1697 310.3102 310.4508 310.5913 310.7318 310.8723 311.0128 311.1533 311.2937 311.4342 311.5746 311.7151 311.8555 311.9959 312.1363 312.2767 312.4170 312.5574 312.6978 312.8381 312.9784 313.1188 313.2591 313.3994 313.5396 313.6799 313.8202 313.9604 314.1007 314.2409 314.3811 314.5213 314.6615 314.8017 314.9419 315.0821 315.2222 315.3623 315.5025 315.6426 315.7827 315.9228 316.0629 316.2030 316.3430 316.4831 316.6231 316.7631 316.9031 317.0432 317.1831 317.3231 317.4631 317.6031 317.7430 317.8829 318.0229 318.1628 318.3027 318.4426 318.5825 318.7223 318.8622 319.0020 319.1419 319.2817 319.4215 319.5613 319.7011 319.8409 319.9807 320.1204 320.2602 320.3999 320.5396 320.6793 320.8190 320.9587 321.0984 321.2381 321.3777 321.5174 321.6570 321.7966 321.9362 322.0758 322.2154 322.3550 322.4946 322.6341 322.7736 322.9132 323.0527 323.1922 323.3317 323.4712 323.6107 323.7501 323.8896 324.0290 324.1684 324.3079 324.4473 324.5867 324.7260 324.8654 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240909T120108.3Z 9018.500791 80 1 48.82 2 73.44 97.97 141.41 76.49 0.00 1 0.00 1 0 25 1.185e-01 1.094e-02 1.913e-02 8.142e-04 4.782816e-01 4.395483e-04 6.230283e-03 -6.000000e+00 7.111573e-02 229.68 -2.00 3.51 -2.00 320.28 0.00e+00 2.534830e-03 1.592614e-04 4.183576e-03 -6.000000e+00 3.181719e-03 288.20 -2.00 20.00 -2.00 319.57 0.00e+00 3.452 0.001 302.00 328.00 3 8.1700e-01 1.3422e-03 4.6444e-02 -6.0000e+00 1.7709e-01 -2.8247e-02 1.6627e-03 3.5099e-02 -6.0000e+00 1.9109e-01 3.3005e-03 1.4222e-03 1.5939e-02 -6.0000e+00 1.1403e-01 -1.0867e-02 7.1947e-04 3.6818e-03 -6.0000e+00 4.8769e-02 4.2935e-03 9.0519e-04 2.5350e-05 8.0522e-05 -6.0000e+00 3.4918e-03 1.2861e-02 0.0000e+00 12 8 8 10 0 0 99.79 22.87 0.32 0.01286 0.01966 637 147 1 5 0 76.620 26.21 20.00 22.87 16.32 25.6 964.38 -41658 -17801 -34673 -29776 -58602 -38365 -38359 -41523 -26912 -45594 -28586 -31651 -18551 -17656 -12544 -11135 -9832 -1119 -8836 -1368 -7770 -3537 -6090 -4710 -6270 -6490 -7238 -11011 -7390 -6165 -841 -3740 -2141 -7160 -9275 -8998 -7172 -1925 -1655 56 -32 600 386 819 1249 833 456 -329 9 466 1975 1067 1906 1672 1224 2050 323 -236 -673 817 1351 3348 3958 3168 703 -941 -1002 -116 2492 1739 1902 1685 1337 803 -1059 -2471 -4044 -3738 -2362 -2068 -2112 -2124 -2483 -972 217 965 2001 1773 2124 1204 268 -1726 -2222 -1271 -962 -128 904 1481 334 -767 -2159 -2246 -761 -448 -1704 -1887 -1009 -478 1222 1474 1318 733 167 -554 -900 -398 163 524 1018 450 782 944 1385 635 317 -1478 -804 211 -224 -642 -1349 -1336 -669 -134 100 176 913 995 616 6 -476 -1072 -502 -187 -440 -343 -849 -459 -510 -651 -401 -863 -486 -637 -401 -467 -376 -373 -357 -40 -366 -55 -340 -151 -281 -232 -336 -358 -398 -615 -400 -356 -53 -279 -172 -611 -791 -791 -707 -218 -225 9 -5 106 71 152 235 160 89 -66 2 102 466 279 533 496 381 654 106 -77 -218 265 463 1244 1616 1389 316 -412 -429 -52 1216 957 1119 1014 786 447 -549 -1181 -1870 -1788 -1253 -1265 -1470 -1632 -1896 -778 183 861 1845 1659 1941 1057 221 -1462 -1838 -1094 -850 -127 1004 1797 426 -957 -2507 -2404 -786 -483 -1991 -2334 -1303 -656 1796 2351 2067 1169 278 -877 -1350 -580 242 820 1676 766 1316 1536 2167 965 463 -2107 -1131 312 -368 -1157 -2403 -2476 -1291 -273 216 393 2066 2267 1391 13 -992 -2166 SS 20240909T120715.3Z 9018.505038 84 1 48.77 2 72.30 99.03 140.34 77.78 0.00 1 0.00 1 0 25 9.581e-02 1.071e-02 1.046e-02 5.804e-04 4.493901e-01 3.087891e-04 5.621138e-03 -6.000000e+00 5.748048e-02 229.68 -2.00 3.51 -2.00 320.00 0.00e+00 2.578374e-03 1.022181e-04 3.046646e-03 -6.000000e+00 2.571632e-03 288.20 -2.00 20.00 -2.00 319.25 0.00e+00 3.243 0.001 302.00 328.00 3 5.1907e-01 9.1611e-04 4.1909e-02 -6.0000e+00 1.4314e-01 -2.6229e-02 1.1135e-03 2.8688e-02 -6.0000e+00 1.5445e-01 4.7962e-03 9.1780e-04 1.4060e-02 -6.0000e+00 9.2164e-02 -1.0671e-02 4.7061e-04 3.7143e-03 -6.0000e+00 3.9420e-02 7.2877e-03 8.4021e-04 1.8071e-05 6.0376e-05 -6.0000e+00 2.8222e-03 1.2600e-02 0.0000e+00 12 8 8 10 0 0 99.63 22.85 0.30 0.01260 0.01891 841 193 1 5 0 57.980 26.21 20.00 22.85 16.92 25.6 968.11 -33312 -30433 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-263 90 676 1290 1699 1336 234 -402 -461 -163 1221 983 1008 1135 758 523 -539 -1199 -1884 -2032 -1421 -1438 -1542 -1587 -1907 -974 28 894 1752 1729 1770 1243 369 -978 -1500 -802 -713 -207 940 1716 421 -1062 -2243 -2455 -801 -436 -2120 -2312 -1549 -791 1641 2135 1886 1014 196 -871 -1225 -561 199 773 1569 730 1322 1581 2369 1120 530 -1923 -1036 501 -251 -907 -2250 -2316 -985 -124 465 250 1859 1959 1360 -67 -1057 -2359 SS 20240909T121248.5Z 9018.508895 87 1 48.77 2 71.27 100.00 139.37 78.92 0.00 1 0.00 1 0 25 7.684e-02 1.097e-02 7.664e-03 5.004e-04 4.281607e-01 2.654406e-04 5.420097e-03 -6.000000e+00 4.609686e-02 229.68 -2.00 3.51 -2.00 319.74 0.00e+00 2.263174e-03 8.086512e-05 2.693340e-03 -6.000000e+00 2.062332e-03 288.20 -2.00 20.00 -2.00 318.98 0.00e+00 3.075 0.000 302.00 328.00 3 4.5660e-01 7.6576e-04 3.9445e-02 -6.0000e+00 1.1479e-01 -2.9984e-02 9.1688e-04 2.6392e-02 -6.0000e+00 1.2386e-01 8.3497e-03 7.3068e-04 1.2859e-02 -6.0000e+00 7.3912e-02 -1.1593e-02 3.7942e-04 3.3941e-03 -6.0000e+00 3.1613e-02 9.3596e-03 8.5279e-04 1.5593e-05 4.7772e-05 -6.0000e+00 2.2633e-03 1.2556e-02 0.0000e+00 12 8 8 10 0 0 30.87 22.84 0.33 0.01256 0.01896 951 219 1 5 0 51.270 26.21 19.99 22.84 17.53 25.7 971.73 -19944 -16184 -26090 -16398 -30437 -27527 -31782 -23223 -25227 -24443 -22649 -22399 -8652 -9605 -3675 -6977 -1777 -4051 -940 -983 -2908 -1092 -2459 403 -3277 -3549 -7474 -6564 -8011 -5202 -1775 -1645 -854 -6508 -7189 -8160 -5034 -2584 -626 -552 -817 904 481 1239 1272 1000 -302 -499 -533 384 1809 1492 2145 1375 1196 1465 424 -381 -500 282 1880 3382 3781 2944 150 -944 -1502 -372 2119 1704 1718 1765 1428 841 -665 -2336 -3386 -3843 -2281 -2250 -2089 -2010 -2544 -1055 -161 886 1632 1572 1700 1383 481 -1253 -1735 -1029 -765 -341 759 1334 356 -778 -1981 -2125 -910 -346 -1834 -1772 -1073 -566 1126 1449 1351 705 282 -553 -792 -493 121 516 1013 557 890 1088 1414 720 381 -1220 -712 382 -163 -496 -1150 -1274 -463 -97 195 142 884 948 591 33 -476 -1106 -349 -300 -541 -292 -585 -517 -688 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