File name: Pandora53s1_WestportCT_20190511_L2Fit_fwvt1c4d20180510p1-8.txt File generation date: 20250226T153953.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c4p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 53 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora53_OF_v2d20171213.txt Instrument calibration file used: Pandora53s1_CF_v4d20180510.txt Level 1 file used: Pandora53s1_WestportCT_20190511_L1_smca1c4d20180510p1-8.txt Full location name: Westport - Sherwood Island State Park CTDEEP (USEPA AQS ID 09-001-9003) Short location name: WestportCT Country of location: USA Location latitude [deg]: 41.1183 Location longitude [deg]: -73.3367 Location altitude [m]: 4 Local noon date: 20190511 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1690 1839 Nominal wavelengths inside fitting window [nm]: 492.1116 492.2321 492.3526 492.4731 492.5936 492.7140 492.8345 492.9549 493.0753 493.1957 493.3161 493.4365 493.5568 493.6771 493.7974 493.9177 494.0380 494.1583 494.2785 494.3988 494.5190 494.6392 494.7593 494.8795 494.9996 495.1198 495.2399 495.3600 495.4800 495.6001 495.7201 495.8402 495.9602 496.0802 496.2001 496.3201 496.4400 496.5600 496.6799 496.7998 496.9196 497.0395 497.1593 497.2792 497.3990 497.5188 497.6385 497.7583 497.8780 497.9977 498.1174 498.2371 498.3568 498.4765 498.5961 498.7157 498.8353 498.9549 499.0745 499.1940 499.3136 499.4331 499.5526 499.6721 499.7915 499.9110 500.0304 500.1498 500.2692 500.3886 500.5080 500.6273 500.7466 500.8660 500.9853 501.1045 501.2238 501.3430 501.4623 501.5815 501.7007 501.8198 501.9390 502.0582 502.1773 502.2964 502.4155 502.5346 502.6536 502.7726 502.8917 503.0107 503.1297 503.2486 503.3676 503.4865 503.6055 503.7244 503.8432 503.9621 504.0810 504.1998 504.3186 504.4374 504.5562 504.6750 504.7937 504.9124 505.0312 505.1499 505.2685 505.3872 505.5058 505.6245 505.7431 505.8617 505.9803 506.0988 506.2174 506.3359 506.4544 506.5729 506.6914 506.8098 506.9283 507.0467 507.1651 507.2835 507.4018 507.5202 507.6385 507.7569 507.8752 507.9934 508.1117 508.2300 508.3482 508.4664 508.5846 508.7028 508.8210 508.9391 509.0572 509.1753 509.2934 509.4115 509.5296 509.6476 509.7656 509.8837 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190511T094512.0Z 7070.406389 1 1 36.01 2 89.87 66.11 119.42 345.80 0.00 1 0.00 1 0 83 1.279e+00 7.034e-01 7.567e-01 4.866e-01 -3.257732e+04 3.323962e+04 2.880491e+02 -6.000000e+00 7.330403e+04 283.06 -2.00 20.00 -2.00 505.18 0.00e+00 7.742194e-03 1.392737e-02 6.038325e-04 -6.000000e+00 3.816892e-02 283.06 -2.00 20.00 -2.00 499.97 0.00e+00 1.698860e+01 1.173530e+01 1.066483e-01 -6.000000e+00 2.746180e+01 230.75 -2.00 3.51 -2.00 501.51 0.00e+00 20.256 0.154 489.00 513.00 1 9.6324e+00 8.7949e-01 3.9772e-02 -6.0000e+00 2.0880e+00 -7.5075e-02 2.3498e-01 2.3064e-03 -6.0000e+00 5.7100e-01 1.0437e-06 -4.4852e-02 3.6785e-02 2.4897e-04 -6.0000e+00 1.4431e-01 2.1233e-01 -2.5399e-03 12 8 8 10 0 0 -1.86 23.30 57.85 0.21233 -0.09879 9 1 1 4 0 4000.000 27.45 20.00 23.30 900000 175532 -36778 900000 -18290 255921 900000 29641 99443 -29380 33109 -469 214440 113245 134357 -41376 900000 45739 900000 62632 188044 132001 23995 155097 -23870 63602 -67965 900000 -8863 900000 75106 71883 20175 900000 258784 70537 117453 213636 68049 -2644 900000 7724 900000 64383 900000 62544 51575 900000 15872 130359 158160 33991 -10862 486289 -40234 900000 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16296 -29532 135715 -63139 65542 12328 10041 41812 186 900000 13414 40957 -110695 107342 -35397 900000 36690 8865 900000 59785 40247 9064 36186 -33108 168257 -23384 38334 -68481 89967 -43130 45089 55000 105843 25452 51005 35575 123157 900000 47272 113585 -83380 44583 46988 76022 71404 33388 19432 22597 -52901 -88018 126778 36309 111326 3752 45599 -44698 -17813 35277 39992 43211 40089 93858 -38222 900000 33752 47783 -28393 900000 -29716 900000 -100080 900000 31347 900000 74165 900000 -6385 36401 181569 29870 900000 69427 900000 -139646 42392 39365 109780 32223 10824 -17384 75109 SO 20190511T094707.0Z 7070.407720 3 1 36.02 2 89.54 66.42 119.51 346.28 0.00 1 0.00 1 0 52 9.159e-01 4.811e-01 6.342e-01 4.405e-01 -8.176152e+04 1.937147e+04 7.540646e+03 -6.000000e+00 5.164222e+04 283.06 -2.00 20.00 -2.00 504.83 0.00e+00 3.226217e-03 1.331396e-02 7.372685e-04 -6.000000e+00 2.706137e-02 283.06 -2.00 20.00 -2.00 500.70 0.00e+00 1.364762e+01 9.048883e+00 4.997957e-01 -6.000000e+00 1.897473e+01 230.75 -2.00 3.51 -2.00 502.27 0.00e+00 19.758 0.143 489.00 513.00 1 1.0086e+01 7.0728e-01 4.8657e-02 -6.0000e+00 1.4511e+00 4.4238e-03 1.7582e-01 3.5461e-03 -6.0000e+00 3.7956e-01 1.4322e-06 2.9522e-02 1.7344e-02 3.2954e-03 -6.0000e+00 9.4517e-02 1.1407e-01 -4.0143e-05 12 8 8 10 0 0 21.67 23.30 25.43 0.11407 0.31885 9 1 1 4 0 4000.000 27.45 20.00 23.30 114496 900000 79512 -15840 144675 3030 900000 -46042 -10279 33172 119669 3458 -746 35898 78563 900000 -4805 108816 -47266 128092 11121 20679 2510 45417 -4413 -17057 -16464 34143 -24310 93176 243727 -24023 27105 10150 900000 16303 900000 54090 552292 6010 28524 76283 2943 359740 7710 165737 4700 10195 -45200 90288 57518 5246 900000 1906 -22851 31157 88500 80182 5710 -25762 -14876 73579 90652 -14760 -8109 -11099 900000 18585 900000 84848 -43131 110476 156555 50003 -35657 13454 -9755 45872 61108 900000 58057 -13015 -32322 -37878 -55856 37935 57736 189 70869 13589 103876 -16463 24954 44206 9785 -34262 -23299 98439 114300 61623 92763 29469 59556 111849 127153 243391 -16736 -19486 900000 -30580 44402 900000 900000 31759 46903 3972 -1271 33720 145714 -1887 91976 117446 -22499 10739 12292 839 64160 67179 50276 75192 77522 189255 29432 900000 19929 228665 -26082 -39704 18349 2183 34857 -540 -17398 -26176 77425 90830 17416 -31769 900000 -30336 49311 900000 44085 -21713 62309 3504 900000 -82031 -12901 27462 51539 3707 -829 29032 43947 900000 -5945 47410 -88000 55167 12000 20619 2944 35681 -5459 -23120 -21497 27470 -33614 44281 104969 -35458 25250 10882 900000 16156 900000 37532 237862 6554 25362 44297 3336 154933 8231 71380 4931 9809 -71244 39769 34405 5168 900000 2014 -30539 25250 41970 41129 5773 -34887 -18153 39083 40358 -17150 -8658 -12000 900000 14731 900000 36543 -61225 47580 67426 29494 -45914 11034 -9978 28560 33548 900000 32342 -13869 -41193 -50917 -90933 26593 34758 199 39811 13454 48179 -25950 30158 49151 15606 -81374 -47516 61338 59393 49209 51980 26954 37110 48171 54762 104824 -17946 -21956 900000 -43684 34462 900000 900000 28752 34509 4026 -1299 25263 62757 -2138 45575 50582 -32205 11305 12727 972 41737 42797 37502 43633 42267 81509 23023 900000 17686 98482 -36562 -61925 16284 2247 26961 -595 -22699 -36228 39313 39119 14244 -40914 900000 -40210 SO 20190511T094859.0Z 7070.409016 5 1 35.99 2 89.22 66.73 119.59 346.76 0.00 1 0.00 1 0 22 1.086e+00 6.326e-01 7.152e-01 4.926e-01 -9.226350e+04 3.179920e+04 4.825309e+03 -6.000000e+00 7.253128e+04 283.06 -2.00 20.00 -2.00 505.73 0.00e+00 1.554447e-02 1.563452e-02 5.791658e-04 -6.000000e+00 3.226430e-02 283.06 -2.00 20.00 -2.00 500.70 0.00e+00 3.035460e+01 1.095507e+01 9.072758e-01 -6.000000e+00 2.278344e+01 230.75 -2.00 3.51 -2.00 502.37 0.00e+00 19.121 0.130 489.00 513.00 1 8.8769e+00 8.3758e-01 7.9965e-02 -6.0000e+00 1.7416e+00 -4.2608e-01 2.0908e-01 1.9125e-02 -6.0000e+00 4.6636e-01 1.1631e-06 -4.2091e-02 1.8459e-02 5.7269e-04 -6.0000e+00 1.1946e-01 -1.2441e-01 8.1045e-04 12 8 8 10 0 0 11.15 23.30 18.95 -0.12441 -0.41637 9 1 1 4 0 4000.000 27.45 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