File name: Pandora53s1_WestportCT_20190730_L2Fit_fwvt1c4d20180510p1-8.txt File generation date: 20250226T154248.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c4p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 53 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora53_OF_v2d20171213.txt Instrument calibration file used: Pandora53s1_CF_v4d20180510.txt Level 1 file used: Pandora53s1_WestportCT_20190730_L1_smca1c4d20180510p1-8.txt Full location name: Westport - Sherwood Island State Park CTDEEP (USEPA AQS ID 09-001-9003) Short location name: WestportCT Country of location: USA Location latitude [deg]: 41.1183 Location longitude [deg]: -73.3367 Location altitude [m]: 4 Local noon date: 20190730 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1690 1839 Nominal wavelengths inside fitting window [nm]: 492.1116 492.2321 492.3526 492.4731 492.5936 492.7140 492.8345 492.9549 493.0753 493.1957 493.3161 493.4365 493.5568 493.6771 493.7974 493.9177 494.0380 494.1583 494.2785 494.3988 494.5190 494.6392 494.7593 494.8795 494.9996 495.1198 495.2399 495.3600 495.4800 495.6001 495.7201 495.8402 495.9602 496.0802 496.2001 496.3201 496.4400 496.5600 496.6799 496.7998 496.9196 497.0395 497.1593 497.2792 497.3990 497.5188 497.6385 497.7583 497.8780 497.9977 498.1174 498.2371 498.3568 498.4765 498.5961 498.7157 498.8353 498.9549 499.0745 499.1940 499.3136 499.4331 499.5526 499.6721 499.7915 499.9110 500.0304 500.1498 500.2692 500.3886 500.5080 500.6273 500.7466 500.8660 500.9853 501.1045 501.2238 501.3430 501.4623 501.5815 501.7007 501.8198 501.9390 502.0582 502.1773 502.2964 502.4155 502.5346 502.6536 502.7726 502.8917 503.0107 503.1297 503.2486 503.3676 503.4865 503.6055 503.7244 503.8432 503.9621 504.0810 504.1998 504.3186 504.4374 504.5562 504.6750 504.7937 504.9124 505.0312 505.1499 505.2685 505.3872 505.5058 505.6245 505.7431 505.8617 505.9803 506.0988 506.2174 506.3359 506.4544 506.5729 506.6914 506.8098 506.9283 507.0467 507.1651 507.2835 507.4018 507.5202 507.6385 507.7569 507.8752 507.9934 508.1117 508.2300 508.3482 508.4664 508.5846 508.7028 508.8210 508.9391 509.0572 509.1753 509.2934 509.4115 509.5296 509.6476 509.7656 509.8837 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190730T095236.0Z 7150.411528 1 1 35.99 2 89.87 65.18 70.48 77.62 0.00 1 0.00 1 0 85 3.462e-01 2.581e-01 2.886e-01 2.413e-01 1.095474e+04 1.736452e+04 7.076215e+02 -6.000000e+00 1.958681e+04 289.78 -2.00 20.00 -2.00 505.41 0.00e+00 1.152089e-02 6.825639e-03 7.657031e-04 -6.000000e+00 9.837088e-03 289.78 -2.00 20.00 -2.00 500.45 0.00e+00 4.724617e+00 4.904458e+00 9.475091e-02 -6.000000e+00 6.856139e+00 232.42 -2.00 3.51 -2.00 502.06 0.00e+00 20.048 0.150 489.00 513.00 1 9.7917e+00 3.8320e-01 4.0541e-02 -6.0000e+00 5.2608e-01 1.3061e-02 9.1579e-02 2.1236e-03 -6.0000e+00 1.3748e-01 3.3177e-06 2.7116e-02 2.1698e-02 2.5573e-04 -6.0000e+00 3.4254e-02 2.4782e-02 7.5202e-05 12 8 8 10 0 0 6.78 24.12 15.45 0.02478 0.21287 9 1 1 4 0 4000.000 28.21 20.00 24.12 -11220 9939 -3931 23140 14432 -15330 -13848 -12399 18199 3058 16832 5367 35871 12958 40513 -20692 -8629 -9801 33231 -32201 4281 41770 61405 69492 -13077 -2938 16128 -11576 20915 16796 -5143 18044 -14105 9631 -11436 -37867 2865 59141 75438 -25336 45958 25767 22048 24317 15302 40664 25215 37997 -3517 14977 56940 -22462 20705 -12244 -46295 31470 43950 74684 40715 28351 11502 -12788 9458 3166 33002 -15856 -2305 -31350 29231 4657 24613 -18305 5104 20108 12243 -14462 6873 34756 -15016 3350 -31630 75431 15157 5713 6476 -17376 -8511 58014 37344 61581 23251 45270 10405 30463 10947 -18822 -22733 -11515 34853 3454 49192 34207 -37446 53145 51392 79267 2569 48779 -18236 63212 -8749 40401 -15618 55730 -908 16814 73758 -14982 -34691 -16541 77619 -10342 18173 -22573 31050 9572 4366 -32706 8400 23493 140476 9996 1350 58656 -20698 30758 99245 24266 -6380 26167 -8857 27897 3393 17930 -5156 -3611 21889 -8403 49466 -29928 -12544 9426 -4355 20202 13949 -19605 -17322 -15037 16314 3105 14826 5187 26011 11623 28631 -26389 -10048 -11637 26249 -46966 4452 30823 38073 40432 -16414 -3289 14680 -13337 17524 14763 -5654 16470 -17834 9763 -14062 -59411 3034 36881 40828 -35819 33899 23453 20908 22693 15589 32153 22643 29658 -3966 13901 35268 -29875 18802 -15621 -83215 27389 34193 43662 32466 25474 12153 -17020 10087 3540 27477 -20523 -2594 -45534 23897 4760 20951 -23648 5292 17967 11489 -17204 6585 25529 -17534 3292 -43270 37804 13365 5487 6141 -20500 -9191 33482 26118 35071 19127 30309 9536 22509 9446 -21027 -25724 -11391 22121 2964 28336 23499 -51443 31349 30699 36276 2399 29988 -21516 35242 -9800 28957 -19019 35002 -986 15619 40020 -18563 -51003 -20182 38638 -11860 16016 -29594 24722 9396 4480 -47765 8263 19807 39421 9430 1376 35174 -26629 24830 43188 21502 -7603 23124 -10841 24208 3726 17086 -5976 -4074 18995 -9642 33537 -43696 SO 20190730T095430.0Z 7150.412847 3 1 36.01 2 89.54 65.50 70.14 77.89 0.00 1 0.00 1 0 74 4.663e-01 2.728e-01 2.940e-01 2.117e-01 3.637455e+02 1.418374e+04 4.844201e+02 -6.000000e+00 2.637576e+04 289.78 -2.00 20.00 -2.00 505.35 0.00e+00 -1.076918e-03 6.207314e-03 1.722174e-04 -6.000000e+00 1.328364e-02 289.78 -2.00 20.00 -2.00 499.98 0.00e+00 8.216908e+00 4.505841e+00 6.467772e-02 -6.000000e+00 9.314274e+00 232.42 -2.00 3.51 -2.00 501.66 0.00e+00 19.573 0.139 489.00 513.00 1 9.6479e+00 3.4867e-01 3.4999e-02 -6.0000e+00 7.1325e-01 -1.2537e-02 8.5896e-02 2.0383e-03 -6.0000e+00 1.8866e-01 3.7390e-06 7.9348e-03 2.0821e-02 7.9562e-05 -6.0000e+00 4.6184e-02 -3.1999e-03 -4.5290e-04 12 8 8 10 0 0 -7.49 24.12 8.23 -0.00320 0.05184 9 1 1 4 0 4000.000 28.21 20.00 24.12 22421 141936 64202 -22533 3081 48164 32126 11502 28241 -26570 5838 -15554 -22963 -2407 -2495 -20333 16975 -3510 15396 -29664 11686 -2093 18716 3156 20938 67138 -9335 6368 -3864 121667 8769 84954 34101 53336 116798 7642 52160 -4797 94280 -28881 37347 -33968 43964 -25527 23549 -31078 34143 27146 98533 -29471 13450 46588 36320 24252 -12924 -6353 18716 40608 6565 -11272 3042 37555 13050 19634 34175 -496 -8277 -10503 44372 -16571 26317 -21286 40103 -11487 4121 -11762 -5966 12478 49874 67626 -14985 121985 -33141 64623 -4413 101691 -13141 25141 -10811 46269 -16176 3915 35111 -28285 12667 -2436 107841 19617 6592 19269 64729 23789 -10395 -22789 9227 3147 62670 187778 -7466 25475 610 26331 13423 -5845 -13322 -5266 -21834 63211 14946 39131 12257 6460 -32689 37991 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41259 3736 9285 28845 11302 -70046 37376 -22809 -7906 1827 23838 32549 10191 SO 20190730T095622.0Z 7150.414144 5 1 36.00 2 89.22 65.80 69.81 78.16 0.00 1 0.00 1 0 48 2.747e-01 2.221e-01 2.224e-01 1.958e-01 1.781903e+04 1.646969e+04 1.564326e+03 -6.000000e+00 1.554663e+04 289.78 -2.00 20.00 -2.00 505.30 0.00e+00 -4.773947e-03 5.455743e-03 2.417986e-04 -6.000000e+00 7.820400e-03 289.78 -2.00 20.00 -2.00 499.87 0.00e+00 9.436746e-01 4.059432e+00 4.549308e-02 -6.000000e+00 5.474005e+00 232.42 -2.00 3.51 -2.00 501.53 0.00e+00 18.961 0.127 489.00 513.00 1 1.0247e+01 3.0867e-01 3.3528e-02 -6.0000e+00 4.1952e-01 1.3785e-01 8.0334e-02 2.5013e-03 -6.0000e+00 1.1045e-01 4.1744e-06 -5.3087e-04 1.6512e-02 1.3024e-04 -6.0000e+00 2.7233e-02 -1.4562e-01 6.7793e-04 12 8 8 10 0 0 7.84 24.12 20.41 -0.14562 -0.14930 9 1 1 4 0 4000.000 28.21 20.00 24.12 36820 -312 13154 20736 7401 -7707 -22432 17396 -13933 37446 6748 -12433 2694 -20270 50012 29359 17583 -1490 21770 -12091 57114 10463 31626 6298 7226 14877 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