File name: Pandora53s1_WestportCT_20190813_L2Fit_fwvt1c4d20180510p1-8.txt File generation date: 20250226T153831.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c4p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 53 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora53_OF_v2d20171213.txt Instrument calibration file used: Pandora53s1_CF_v4d20180510.txt Level 1 file used: Pandora53s1_WestportCT_20190813_L1_smca1c4d20180510p1-8.txt Full location name: Westport - Sherwood Island State Park CTDEEP (USEPA AQS ID 09-001-9003) Short location name: WestportCT Country of location: USA Location latitude [deg]: 41.1183 Location longitude [deg]: -73.3367 Location altitude [m]: 4 Local noon date: 20190813 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1690 1839 Nominal wavelengths inside fitting window [nm]: 492.1116 492.2321 492.3526 492.4731 492.5936 492.7140 492.8345 492.9549 493.0753 493.1957 493.3161 493.4365 493.5568 493.6771 493.7974 493.9177 494.0380 494.1583 494.2785 494.3988 494.5190 494.6392 494.7593 494.8795 494.9996 495.1198 495.2399 495.3600 495.4800 495.6001 495.7201 495.8402 495.9602 496.0802 496.2001 496.3201 496.4400 496.5600 496.6799 496.7998 496.9196 497.0395 497.1593 497.2792 497.3990 497.5188 497.6385 497.7583 497.8780 497.9977 498.1174 498.2371 498.3568 498.4765 498.5961 498.7157 498.8353 498.9549 499.0745 499.1940 499.3136 499.4331 499.5526 499.6721 499.7915 499.9110 500.0304 500.1498 500.2692 500.3886 500.5080 500.6273 500.7466 500.8660 500.9853 501.1045 501.2238 501.3430 501.4623 501.5815 501.7007 501.8198 501.9390 502.0582 502.1773 502.2964 502.4155 502.5346 502.6536 502.7726 502.8917 503.0107 503.1297 503.2486 503.3676 503.4865 503.6055 503.7244 503.8432 503.9621 504.0810 504.1998 504.3186 504.4374 504.5562 504.6750 504.7937 504.9124 505.0312 505.1499 505.2685 505.3872 505.5058 505.6245 505.7431 505.8617 505.9803 506.0988 506.2174 506.3359 506.4544 506.5729 506.6914 506.8098 506.9283 507.0467 507.1651 507.2835 507.4018 507.5202 507.6385 507.7569 507.8752 507.9934 508.1117 508.2300 508.3482 508.4664 508.5846 508.7028 508.8210 508.9391 509.0572 509.1753 509.2934 509.4115 509.5296 509.6476 509.7656 509.8837 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190813T100612.0Z 7164.420972 1 1 36.00 2 89.86 70.46 112.37 259.59 0.00 1 0.00 1 0 58 1.014e+00 4.738e-01 5.740e-01 3.582e-01 3.253151e+04 3.100018e+04 5.398614e+02 -6.000000e+00 5.798069e+04 290.10 -2.00 20.00 -2.00 505.00 0.00e+00 -1.485256e-02 1.067300e-02 6.406833e-04 -6.000000e+00 2.953561e-02 290.10 -2.00 20.00 -2.00 499.74 0.00e+00 -6.062176e+00 7.392900e+00 1.358422e-01 -6.000000e+00 2.051433e+01 231.92 -2.00 3.51 -2.00 501.42 0.00e+00 20.039 0.149 489.00 513.00 1 1.1270e+01 5.7602e-01 4.0253e-02 -6.0000e+00 1.5693e+00 2.8372e-01 1.4016e-01 2.4768e-03 -6.0000e+00 4.1633e-01 1.8691e-06 4.6970e-02 2.2370e-02 2.8866e-04 -6.0000e+00 1.0231e-01 -2.7210e-02 1.1833e-03 12 8 8 10 0 0 18.38 24.10 27.97 -0.02721 0.29859 9 1 1 4 0 4000.000 28.21 20.00 24.10 173220 -2727 53074 -50558 900000 -19293 900000 59323 57969 -14933 41059 -14870 6843 35593 15170 34104 -22846 556 105651 145376 -36447 900000 131992 11102 21872 34209 39759 41396 48889 -21382 114999 -8447 36187 -7470 109344 -4337 47822 7022 344892 39286 25281 48489 -13714 240984 -840 57513 -38439 222896 -53029 140146 43057 36297 42385 32080 71857 38795 20163 247002 -12835 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14733 15459 55689 -73236 14944 39521 -17874 3179 34615 33506 30990 -6886 36233 -56681 32640 3280 41118 46313 58840 32062 -49278 27323 -62054 19539 22581 25631 9128 -11765 19203 85029 1738 -69283 27936 18156 48968 -32815 68747 22840 43248 46179 17052 44116 44473 28789 38732 29390 -4458 -17777 -16609 47420 -96307 900000 30701 900000 38859 38447 39414 198655 46512 74200 -51558 34095 37056 1012 900000 13330 40244 -76104 55889 -21531 15027 -50556 -1110 43346 2862 16910 34841 900000 -1675 63973 -57865 92030 900000 SO 20190813T100806.0Z 7164.422292 3 1 36.01 2 89.52 70.78 112.70 259.87 0.00 1 0.00 1 0 49 1.058e+00 4.989e-01 5.980e-01 3.705e-01 1.794855e+05 5.213202e+04 8.792603e+03 -6.000000e+00 6.014231e+04 290.10 -2.00 20.00 -2.00 505.53 0.00e+00 -4.180851e-02 1.067371e-02 3.152103e-03 -6.000000e+00 3.208589e-02 290.10 -2.00 20.00 -2.00 500.07 0.00e+00 -2.448497e+01 7.643898e+00 9.394322e-01 -6.000000e+00 2.178212e+01 231.92 -2.00 3.51 -2.00 501.77 0.00e+00 19.540 0.139 489.00 513.00 1 1.2926e+01 5.6272e-01 1.1018e-01 -6.0000e+00 1.6772e+00 3.8788e-01 1.4356e-01 2.0681e-02 -6.0000e+00 4.5029e-01 1.7610e-06 1.0024e-02 1.0146e-02 1.0506e-03 -6.0000e+00 1.0932e-01 -6.6394e-02 -4.1447e-04 12 8 8 10 0 0 0.33 24.10 28.90 -0.06639 0.00313 9 1 1 4 0 4000.000 28.21 20.00 24.10 900000 28603 -49303 207945 -49622 152003 20290 -35431 38687 20872 31630 128881 62302 -10650 14163 -12305 92378 -11700 520749 -17736 900000 -11936 900000 13127 217799 123177 -3160 -12783 84448 226355 -14457 237782 -5762 125429 -16431 29653 107140 39819 25839 168061 87048 -3744 30822 -39796 241 14168 20803 -5260 23410 -30479 118412 113645 279491 -15661 900000 900000 34260 900000 -24060 35662 -32145 39985 -20016 69028 60852 900000 7436 117339 15993 52371 196142 8485 39504 19966 90921 -634 32735 -13358 52873 13693 27825 126489 20206 136279 -32127 41464 47054 71260 -26511 30439 88902 43424 74443 900000 -36692 20865 196541 -33564 981 136083 342650 37890 50038 20840 54611 15109 164235 -47695 226668 67258 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