File name: Pandora247s1_WhittierCA_20230630_L2Fit_fout2c2d20221229p1-8.txt File generation date: 20230705T134152.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Peter Peterson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 247 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora247_OF_v2d20221027.txt Instrument calibration file used: Pandora247s1_CF_v2d20221229.txt Level 1 file used: Pandora247s1_WhittierCA_20230630_L1_smca1c2d20221229p1-8.txt Full location name: Whittier College SLC Short location name: WhittierCA Country of location: United States Location latitude [deg]: 33.9768 Location longitude [deg]: -118.0299 Location altitude [m]: 130 Local noon date: 20230630 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 194 336 Nominal wavelengths inside fitting window [nm]: 305.0208 305.1616 305.3025 305.4433 305.5842 305.7250 305.8658 306.0066 306.1474 306.2881 306.4289 306.5696 306.7104 306.8511 306.9918 307.1325 307.2732 307.4139 307.5546 307.6952 307.8359 307.9765 308.1171 308.2577 308.3983 308.5389 308.6795 308.8201 308.9607 309.1012 309.2417 309.3823 309.5228 309.6633 309.8038 309.9443 310.0847 310.2252 310.3656 310.5061 310.6465 310.7869 310.9273 311.0677 311.2081 311.3484 311.4888 311.6291 311.7695 311.9098 312.0501 312.1904 312.3307 312.4710 312.6112 312.7515 312.8917 313.0320 313.1722 313.3124 313.4526 313.5928 313.7330 313.8731 314.0133 314.1534 314.2936 314.4337 314.5738 314.7139 314.8540 314.9941 315.1341 315.2742 315.4142 315.5542 315.6943 315.8343 315.9743 316.1142 316.2542 316.3942 316.5341 316.6740 316.8140 316.9539 317.0938 317.2337 317.3736 317.5134 317.6533 317.7931 317.9330 318.0728 318.2126 318.3524 318.4922 318.6320 318.7717 318.9115 319.0512 319.1910 319.3307 319.4704 319.6101 319.7498 319.8894 320.0291 320.1687 320.3084 320.4480 320.5876 320.7272 320.8668 321.0064 321.1460 321.2855 321.4251 321.5646 321.7041 321.8436 321.9831 322.1226 322.2621 322.4016 322.5410 322.6804 322.8199 322.9593 323.0987 323.2381 323.3775 323.5168 323.6562 323.7955 323.9349 324.0742 324.2135 324.3528 324.4921 324.6314 324.7706 324.9099 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230630T152457.1Z 8581.642327 184 1 15.37 2 59.41 81.23 155.02 289.85 0.00 1 0.00 1 0 17 1.595e-02 7.319e-03 8.765e-03 3.706e-03 2.696626e-01 1.991024e-03 3.112847e-03 -6.000000e+00 9.767752e-03 232.08 -2.00 3.36 -2.00 316.52 0.00e+00 7.409518e-04 2.443030e-04 6.003356e-05 -6.000000e+00 4.425813e-04 291.11 -2.00 20.00 -2.00 315.68 0.00e+00 1.957 0.000 302.00 328.00 3 4.9440e+00 5.2284e-03 2.3684e-02 -6.0000e+00 2.4427e-02 2.7598e-02 5.8227e-03 1.3604e-02 -6.0000e+00 2.6313e-02 -8.1742e-03 3.3672e-03 6.5698e-03 -6.0000e+00 1.5715e-02 1.8505e-03 1.5710e-03 1.8652e-03 -6.0000e+00 6.6109e-03 3.8697e-04 -1.2051e-03 1.1621e-04 2.5193e-05 -6.0000e+00 4.9529e-04 -1.5341e-03 -1.2881e-04 12 9 1 12 9 1 -19.39 24.99 0.39 -0.00153 -0.01059 3 2 1 5 0 2551.927 33.00 20.00 24.99 27.62 10.1 998.71 6127 -3029 -4350 -2302 -6241 -1086 4114 -2715 1209 -3880 -6741 5362 -2864 33 -84 1720 -16 650 1104 1358 1305 -445 545 3153 1606 623 533 -265 676 210 1371 751 889 -1216 -2098 -3229 137 -1189 687 -1261 -881 -2021 -468 -3229 -451 236 344 -1342 946 -461 472 1382 161 954 1257 767 1056 862 86 1626 2138 1270 903 1377 477 -995 -842 -131 566 1279 -141 578 -369 -99 -519 -203 -244 367 -634 428 -1080 -664 -1567 -1853 -794 -973 -202 -140 -258 454 -490 910 312 742 1127 237 512 65 104 -586 -136 -377 -335 158 381 -1253 -750 -846 -590 118 389 460 33 1 393 204 518 755 -54 -465 -700 -212 -111 661 658 818 269 478 1139 601 93 -99 -208 -6 19 -165 153 77 274 -615 26 -442 -621 888 -486 -735 -370 -966 -165 604 -466 201 -720 -1315 953 -601 8 -22 496 -4 194 341 434 427 -149 183 1073 585 238 205 -99 237 72 478 283 361 -523 -894 -1361 59 -542 364 -736 -533 -1317 -311 -2242 -306 159 228 -887 601 -298 313 965 113 702 957 602 842 690 69 1269 1694 1011 779 1257 422 -906 -714 -106 472 1167 -135 583 -361 -99 -494 -186 -203 303 -536 368 -1000 -677 -1652 -1971 -888 -1165 -243 -174 -325 553 -568 1003 334 756 1173 257 613 82 134 -771 -170 -461 -404 190 462 -1572 -984 -1163 -813 171 570 689 49 2 528 268 663 990 -76 -666 -997 -314 -160 916 909 1072 355 620 1461 828 130 -144 -310 -8 29 -260 249 128 440 -1026 42 -686 -980 SS 20230630T152953.9Z 8581.645762 187 1 35.53 2 58.40 81.83 155.94 291.24 0.00 1 0.00 1 0 17 1.007e-02 6.440e-03 4.047e-03 1.791e-03 2.629997e-01 9.627657e-04 2.993759e-03 -6.000000e+00 6.173736e-03 232.08 -2.00 3.36 -2.00 316.39 0.00e+00 3.650504e-04 1.151927e-04 6.275411e-05 -6.000000e+00 2.796105e-04 291.11 -2.00 20.00 -2.00 315.57 0.00e+00 1.901 0.000 302.00 328.00 3 4.8944e+00 2.5219e-03 2.2981e-02 -6.0000e+00 1.5439e-02 2.5366e-02 2.8080e-03 1.3132e-02 -6.0000e+00 1.6625e-02 -5.4520e-03 1.6181e-03 6.3361e-03 -6.0000e+00 9.9297e-03 -1.1590e-03 7.4883e-04 1.7379e-03 -6.0000e+00 4.1814e-03 4.3509e-04 -2.3582e-05 5.5970e-05 2.3411e-05 -6.0000e+00 3.1263e-04 -3.2181e-03 7.9829e-05 12 9 1 12 9 1 49.69 25.00 0.22 -0.00322 -0.00340 13 2 1 5 0 2217.068 33.00 20.00 25.00 27.67 10.1 998.38 1392 -838 -1175 -4289 -3985 -3066 1396 -1612 837 324 -2274 1989 222 132 574 1209 -111 46 -174 691 1541 209 1656 230 401 1291 750 -372 -553 807 845 992 1059 -25 -2095 -1648 -312 -126 -195 -101 -1615 -1090 -1102 -2798 -1206 -37 -514 -855 212 -472 284 588 564 935 241 665 1047 629 150 1303 897 1397 1578 999 793 -811 98 69 864 1416 104 426 88 -141 179 142 -180 -342 -170 463 -1022 -1166 -1762 -1961 -1057 -584 -174 192 236 116 317 579 206 402 849 720 255 -63 16 -225 -614 -730 -637 185 101 -1178 -882 -781 -705 198 268 72 121 161 -43 313 814 431 194 154 -271 -370 328 597 604 450 115 695 990 423 76 -163 -281 43 52 144 -226 152 183 -191 -91 -412 -837 211 -144 -211 -770 -661 -474 209 -273 153 63 -467 401 49 33 150 348 -34 15 -59 239 543 75 595 87 147 490 287 -139 -213 296 318 399 423 -11 -880 -674 -132 -60 -103 -58 -1049 -704 -737 -1933 -822 -25 -342 -560 144 -322 187 410 418 726 184 520 830 501 119 1014 715 1171 1344 910 735 -732 87 58 752 1275 99 427 90 -141 168 128 -157 -280 -141 416 -985 -1180 -1840 -2174 -1175 -690 -207 237 293 141 379 635 219 427 874 804 302 -78 20 -291 -799 -883 -761 220 122 -1530 -1148 -1064 -965 285 390 107 177 232 -60 405 1070 559 267 217 -396 -543 467 818 823 584 149 886 1311 575 106 -234 -413 62 79 222 -363 249 303 -314 -145 -633 -1309 SS 20230630T154006.5Z 8581.652853 190 1 54.59 2 56.30 83.08 157.81 294.37 0.00 1 0.00 1 0 17 8.472e-03 6.349e-03 2.832e-04 1.670e-04 2.485824e-01 9.027762e-05 2.843898e-03 -6.000000e+00 5.193150e-03 232.08 -2.00 3.36 -2.00 315.63 0.00e+00 2.413296e-04 9.052705e-06 3.743190e-05 -6.000000e+00 2.351789e-04 291.11 -2.00 20.00 -2.00 314.85 0.00e+00 1.797 0.000 302.00 328.00 3 1.0541e+00 2.3421e-04 2.1698e-02 -6.0000e+00 1.2987e-02 -3.0372e-03 2.5965e-04 1.2364e-02 -6.0000e+00 1.3984e-02 -4.5144e-03 1.4830e-04 5.9806e-03 -6.0000e+00 8.3523e-03 -8.6131e-04 6.5841e-05 1.6407e-03 -6.0000e+00 3.5175e-03 2.3273e-02 9.1299e-05 5.2009e-06 2.3148e-05 -6.0000e+00 2.6294e-04 -3.3574e-03 1.0385e-04 10 0 0 10 0 0 99.29 25.02 0.29 -0.00336 -0.00267 1466 145 1 5 0 37.233 33.00 20.00 25.02 28.25 10.3 1000.42 175 -1252 -1765 -2679 -3187 -952 -380 606 565 -513 -1722 -779 484 123 356 358 -552 505 832 825 1131 557 1181 1277 841 681 72 -840 138 874 1668 1323 1179 135 -2487 -1388 -628 -685 124 -438 -1291 -1243 -702 -936 -797 -215 -761 -650 -302 -233 733 967 543 993 506 548 971 430 254 627 891 1414 1311 1014 310 -757 90 81 705 1570 75 -53 -110 -146 93 -204 2 -81 -51 25 -1096 -1453 -1824 -2001 -949 -736 -487 -20 -62 132 214 613 320 667 1056 747 358 373 102 -572 -514 -619 -391 291 118 -1229 -856 -635 -538 243 230 111 -13 171 269 465 755 530 380 129 -349 -209 80 313 327 855 240 791 1012 256 127 -263 -300 -42 169 -128 -251 96 -38 -271 -119 -246 -600 44 -329 -483 -717 -793 -233 -94 151 156 -152 -496 -227 150 41 133 140 -219 206 352 360 504 239 510 572 399 320 34 -407 63 381 736 626 570 68 -1268 -684 -322 -382 74 -284 -904 -894 -520 -681 -581 -161 -564 -470 -213 -170 528 738 427 789 419 450 809 361 211 517 747 1208 1170 935 292 -689 80 70 620 1461 73 -53 -112 -146 90 -193 2 -69 -44 23 -1059 -1471 -1948 -2208 -1073 -844 -578 -24 -75 159 249 686 347 705 1107 828 418 458 128 -732 -644 -756 -462 343 144 -1546 -1102 -835 -725 337 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