File name: Pandora247s1_WhittierCA_20230813_L2Fit_fout2c6d20230505p1-8.txt File generation date: 20241125T171044.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Peter Peterson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 247 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora247_OF_v2d20221027.txt Instrument calibration file used: Pandora247s1_CF_v6d20230505.txt Level 1 file used: Pandora247s1_WhittierCA_20230813_L1_smca1c6d20230505p1-8.txt Full location name: Whittier College SLC Short location name: WhittierCA Country of location: United States Location latitude [deg]: 33.9768 Location longitude [deg]: -118.0299 Location altitude [m]: 130 Local noon date: 20230813 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 5 "based on session 2 trying to improve labcal" First and last pixel inside fitting window: 195 336 Nominal wavelengths inside fitting window [nm]: 305.1400 305.2810 305.4219 305.5629 305.7038 305.8447 305.9856 306.1265 306.2673 306.4082 306.5491 306.6899 306.8307 306.9715 307.1124 307.2531 307.3939 307.5347 307.6755 307.8162 307.9569 308.0977 308.2384 308.3791 308.5198 308.6605 308.8011 308.9418 309.0824 309.2231 309.3637 309.5043 309.6449 309.7855 309.9260 310.0666 310.2072 310.3477 310.4882 310.6287 310.7692 310.9097 311.0502 311.1907 311.3311 311.4716 311.6120 311.7524 311.8929 312.0333 312.1736 312.3140 312.4544 312.5947 312.7351 312.8754 313.0157 313.1560 313.2963 313.4366 313.5769 313.7171 313.8574 313.9976 314.1379 314.2781 314.4183 314.5585 314.6986 314.8388 314.9790 315.1191 315.2592 315.3993 315.5395 315.6796 315.8196 315.9597 316.0998 316.2398 316.3799 316.5199 316.6599 316.7999 316.9399 317.0799 317.2198 317.3598 317.4997 317.6397 317.7796 317.9195 318.0594 318.1993 318.3391 318.4790 318.6188 318.7587 318.8985 319.0383 319.1781 319.3179 319.4577 319.5974 319.7372 319.8769 320.0167 320.1564 320.2961 320.4358 320.5755 320.7151 320.8548 320.9944 321.1341 321.2737 321.4133 321.5529 321.6925 321.8321 321.9716 322.1112 322.2507 322.3902 322.5298 322.6693 322.8087 322.9482 323.0877 323.2271 323.3666 323.5060 323.6454 323.7848 323.9242 324.0636 324.2030 324.3424 324.4817 324.6210 324.7604 324.8997 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230813T141151.0Z 8625.591563 138 1 54.67 2 78.88 79.76 48.52 82.75 0.00 1 0.00 1 0 17 2.325e-01 7.555e-03 7.586e-02 2.085e-03 6.211400e-01 1.139574e-03 6.887090e-03 -6.000000e+00 1.409930e-01 231.01 -2.00 3.36 -2.00 320.33 0.00e+00 8.183704e-04 4.452043e-04 1.561447e-03 -6.000000e+00 6.526876e-03 292.82 -2.00 20.00 -2.00 319.58 0.00e+00 5.000 0.002 302.00 328.00 3 1.5159e+00 3.5410e-03 5.8706e-02 -6.0000e+00 3.5114e-01 6.0801e-02 4.5040e-03 3.2660e-02 -6.0000e+00 3.7856e-01 -7.6360e-02 4.0039e-03 1.5992e-02 -6.0000e+00 2.2600e-01 2.2604e-02 2.0193e-03 4.3835e-03 -6.0000e+00 9.6292e-02 4.4320e-04 1.6647e-05 6.0501e-05 5.8308e-05 -6.0000e+00 7.0421e-03 -3.4324e-03 -1.5335e-04 11 8 0 10 0 0 99.98 26.08 0.40 -0.00343 -0.00331 130 13 1 5 0 420.511 33.75 19.99 26.08 27.29 10.5 1000.33 -79886 -16824 -109072 -119993 900000 -88664 -37576 -40885 -59779 -48026 -70314 -61664 -65131 -27058 -45276 -67665 4959 11932 -19446 -20363 9522 -2845 -16969 -6942 -4331 9867 -4655 1666 1385 -2852 -10839 -4084 499 -8250 -1331 -3100 -5806 -801 3091 -3340 -4341 4256 -16377 1398 2636 53 1773 -686 -3417 2131 1007 1628 4027 1427 2394 2642 3315 786 -285 1327 2394 1476 3694 3942 986 -957 245 321 3150 1459 1246 666 624 594 14 -159 -1265 -2410 -1801 -1363 -759 -866 -2195 -1045 -558 -245 771 724 536 281 641 -6 -63 -315 238 -511 312 596 -342 -401 -1013 -1253 -25 -181 -1360 -1270 -718 -404 458 643 314 302 54 94 179 -294 491 375 390 -276 -81 259 539 224 620 -147 262 595 322 265 -396 -299 -426 31 -79 -91 240 384 -196 -9 -65 -583 -576 -79 -1308 -1537 900000 -847 -244 -316 -620 -478 -972 -940 -1298 -462 -1123 -2421 96 235 -561 -621 221 -78 -576 -234 -153 313 -169 56 49 -118 -577 -237 30 -555 -83 -210 -471 -76 339 -450 -650 620 -3040 221 420 9 299 -124 -672 435 232 375 990 386 677 774 976 234 -85 394 755 526 1441 1646 427 -415 107 151 1493 786 717 390 352 312 7 -77 -607 -1257 -989 -872 -511 -649 -1795 -902 -512 -220 713 675 489 262 557 -5 -52 -285 226 -565 363 763 -427 -514 -1198 -1365 -28 -200 -1620 -1599 -897 -546 678 988 518 478 89 147 267 -434 744 600 618 -445 -135 416 833 334 941 -218 392 910 522 475 -725 -576 -825 64 -165 -196 522 840 -420 -19 -132 -1140 SS 20230813T141707.6Z 8625.595227 141 1 7.63 2 77.80 80.46 47.46 83.35 0.00 1 0.00 1 0 17 3.070e-01 2.028e-02 2.673e-01 1.513e-02 5.685430e-01 8.235010e-03 6.349938e-03 -6.000000e+00 1.870366e-01 231.01 -2.00 3.36 -2.00 320.08 0.00e+00 3.226535e-03 2.918458e-03 1.305420e-03 -6.000000e+00 8.841083e-03 292.82 -2.00 20.00 -2.00 319.30 0.00e+00 4.592 0.001 302.00 328.00 3 2.5284e+00 2.4816e-02 5.3655e-02 -6.0000e+00 4.6692e-01 9.1710e-02 3.0325e-02 2.9032e-02 -6.0000e+00 5.0376e-01 -1.3937e-01 2.4707e-02 1.4749e-02 -6.0000e+00 2.9970e-01 6.0866e-02 1.2731e-02 4.7981e-03 -6.0000e+00 1.2767e-01 2.4571e-04 -1.7553e-04 4.4865e-04 6.3267e-05 -6.0000e+00 9.4559e-03 -4.6822e-03 -9.8749e-05 12 9 9 12 1 1 999.00 26.08 0.20 -0.00468 -0.00600 1 3 1 5 0 1893.836 33.75 20.00 26.08 27.64 10.5 1000.18 -145801 -21873 -56438 -115032 -93151 -163796 900000 118100 -67960 -92791 900000 -37100 9180 14235 -15557 -31079 -37647 -20030 -23656 -31318 22102 -10008 -63423 57430 47817 -9094 -17915 -9291 25168 -23527 12580 -24797 -13139 6205 -2480 -7182 6856 -1495 46674 -18479 28340 11879 -8349 5072 23397 -2894 3974 4944 -12556 -5728 9472 11672 11851 11344 -1764 4125 4199 6066 6332 1609 -402 1504 5462 9595 -1577 -5631 970 1551 6326 679 4111 834 588 2551 -1313 1441 20 -1734 -464 1542 -329 -825 -2414 -5032 -3527 -5227 -908 -471 -947 2595 -98 -3196 -452 -125 -672 -200 -1458 1258 1949 -1494 -448 294 455 925 -876 -3273 722 1084 -455 1151 -419 1378 843 323 -1411 -827 312 -1148 -402 2589 852 -962 1627 941 -324 -1393 1235 1699 -374 1651 1111 -403 -870 -334 -1395 43 834 1302 207 -840 -908 -1015 -4299 -322 -832 -2621 -1785 -5928 900000 1741 -1403 -2599 900000 -766 149 273 -482 -1283 -1832 -886 -1151 -1708 717 -457 -5236 1524 1480 -509 -1083 -507 1002 -1700 742 -2450 -1259 494 -212 -678 647 -185 4266 -3705 3886 2032 -1645 980 3829 -627 820 1042 -3012 -1390 2184 2894 3177 3254 -603 1371 1407 1968 2020 548 -150 613 2379 4282 -788 -2615 462 784 3148 399 2485 528 361 1429 -695 744 10 -876 -265 1006 -231 -644 -2056 -4691 -3213 -5130 -887 -463 -914 2467 -89 -2835 -387 -115 -650 -221 -1731 1599 2536 -1936 -528 339 512 1017 -1046 -4227 953 1441 -675 1737 -684 2241 1340 490 -2068 -1262 457 -1801 -658 4183 1376 -1528 2432 1446 -484 -2031 1767 2617 -617 2761 1993 -729 -1668 -675 -2870 89 1768 2761 435 -1699 -1829 -1970 SS 20230813T150730.3Z 8625.630212 156 1 35.38 2 67.43 87.17 37.30 89.55 0.00 1 0.00 1 0 17 1.750e-02 6.621e-03 7.164e-03 1.896e-03 3.384228e-01 1.004926e-03 3.836548e-03 -6.000000e+00 1.058000e-02 231.01 -2.00 3.36 -2.00 317.55 0.00e+00 5.793691e-04 1.611783e-04 1.915212e-04 -6.000000e+00 4.834287e-04 292.82 -2.00 20.00 -2.00 316.64 0.00e+00 2.584 0.000 302.00 328.00 3 3.5121e+00 2.6789e-03 3.0617e-02 -6.0000e+00 2.6376e-02 2.4217e-02 3.0162e-03 1.6922e-02 -6.0000e+00 2.8431e-02 -1.0544e-02 1.8320e-03 8.1878e-03 -6.0000e+00 1.6998e-02 1.2097e-03 9.1522e-04 2.2726e-03 -6.0000e+00 7.2514e-03 8.1206e-04 3.1971e-04 5.8115e-05 2.7492e-05 -6.0000e+00 5.2951e-04 -4.4122e-03 -1.3795e-04 12 9 1 12 1 1 99.88 26.11 0.14 -0.00441 -0.00201 20 4 1 5 0 1535.996 33.75 20.00 26.11 29.04 10.5 1001.16 -3201 1514 -9102 -5690 -4744 -6987 -1501 -1817 -5337 -2852 -6465 -2836 -209 166 1785 -3481 -1035 1397 -416 1895 1970 481 -81 267 2775 629 -773 67 778 758 745 119 1244 -1816 -3509 -84 -1878 -728 1151 -712 -956 -212 -3669 -208 574 68 -13 -145 -611 1248 770 495 1700 455 685 1362 626 78 1342 516 1215 1098 1506 1518 -352 -331 -451 -90 1331 569 232 353 268 589 -397 -250 -1334 -873 -470 -1213 -1082 -1258 -2150 -1218 -794 -455 21 157 642 157 731 -176 -121 631 488 -92 317 546 -107 -512 -1186 -843 -147 111 -1186 -527 -786 -695 560 565 540 196 308 213 208 -52 179 284 337 -237 -41 278 464 430 734 -115 242 1022 550 34 -267 -274 -365 349 69 -35 67 211 -354 17 -366 -787 -272 130 -855 -480 -373 -572 -128 -175 -574 -309 -753 -352 -29 25 296 -660 -203 281 -89 409 429 108 -19 67 715 168 -203 17 188 191 207 36 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