File name: Pandora247s1_WhittierCA_20231220_L2Fit_fout2c2d20221229p1-8.txt File generation date: 20240123T220155.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Peter Peterson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 247 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora247_OF_v2d20221027.txt Instrument calibration file used: Pandora247s1_CF_v2d20221229.txt Level 1 file used: Pandora247s1_WhittierCA_20231220_L1_smca1c2d20221229p1-8.txt Full location name: Whittier College SLC Short location name: WhittierCA Country of location: United States Location latitude [deg]: 33.9768 Location longitude [deg]: -118.0299 Location altitude [m]: 130 Local noon date: 20231220 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 194 336 Nominal wavelengths inside fitting window [nm]: 305.0208 305.1616 305.3025 305.4433 305.5842 305.7250 305.8658 306.0066 306.1474 306.2881 306.4289 306.5696 306.7104 306.8511 306.9918 307.1325 307.2732 307.4139 307.5546 307.6952 307.8359 307.9765 308.1171 308.2577 308.3983 308.5389 308.6795 308.8201 308.9607 309.1012 309.2417 309.3823 309.5228 309.6633 309.8038 309.9443 310.0847 310.2252 310.3656 310.5061 310.6465 310.7869 310.9273 311.0677 311.2081 311.3484 311.4888 311.6291 311.7695 311.9098 312.0501 312.1904 312.3307 312.4710 312.6112 312.7515 312.8917 313.0320 313.1722 313.3124 313.4526 313.5928 313.7330 313.8731 314.0133 314.1534 314.2936 314.4337 314.5738 314.7139 314.8540 314.9941 315.1341 315.2742 315.4142 315.5542 315.6943 315.8343 315.9743 316.1142 316.2542 316.3942 316.5341 316.6740 316.8140 316.9539 317.0938 317.2337 317.3736 317.5134 317.6533 317.7931 317.9330 318.0728 318.2126 318.3524 318.4922 318.6320 318.7717 318.9115 319.0512 319.1910 319.3307 319.4704 319.6101 319.7498 319.8894 320.0291 320.1687 320.3084 320.4480 320.5876 320.7272 320.8668 321.0064 321.1460 321.2855 321.4251 321.5646 321.7041 321.8436 321.9831 322.1226 322.2621 322.4016 322.5410 322.6804 322.8199 322.9593 323.0987 323.2381 323.3775 323.5168 323.6562 323.7955 323.9349 324.0742 324.2135 324.3528 324.4921 324.6314 324.7706 324.9099 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231220T191216.8Z 8754.800195 180 1 54.47 2 58.09 169.87 106.87 73.99 0.00 1 0.00 1 0 17 3.194e-02 8.954e-03 1.452e-02 3.838e-03 2.838509e-01 1.979892e-03 3.248169e-03 -6.000000e+00 1.901195e-02 223.97 -2.00 3.36 -2.00 317.67 0.00e+00 1.122127e-04 3.237245e-04 2.038657e-04 -6.000000e+00 8.535869e-04 282.00 -2.00 20.00 -2.00 316.97 0.00e+00 1.885 0.000 302.00 328.00 3 6.5397e+00 5.2127e-03 2.3066e-02 -6.0000e+00 4.6788e-02 4.0236e-02 5.8942e-03 1.3672e-02 -6.0000e+00 5.0742e-02 -1.1460e-02 3.6205e-03 6.8076e-03 -6.0000e+00 3.0335e-02 -4.1768e-05 1.8097e-03 1.9541e-03 -6.0000e+00 1.2876e-02 8.2358e-05 4.6340e-04 1.2183e-04 2.4454e-05 -6.0000e+00 9.8847e-04 -8.2109e-03 1.5189e-04 11 8 0 10 0 0 99.99 25.45 0.65 -0.00821 -0.00473 77 8 1 5 0 707.299 33.25 19.99 25.45 24.05 19.7 998.98 355 -7359 -111 793 -8373 -17704 16494 -16169 5004 1646 -4259 4995 717 -2373 -2141 8112 -5088 2733 2993 1141 450 1926 -214 836 489 122 -1741 -1949 4074 1106 -985 1532 -1624 611 -2001 -259 2218 -680 690 2545 -557 -1356 682 -9998 268 2204 -534 176 195 -2210 1113 182 1192 794 1142 1200 2255 2193 865 -550 1693 1728 2020 -237 1431 -328 -902 13 764 1520 -323 454 326 -487 -86 -890 262 -1196 265 -496 -829 -1354 -1621 -1219 -1117 -403 369 -403 134 10 185 520 133 694 669 137 -37 524 303 33 -645 -1007 -590 -336 28 -1266 -1316 -100 -392 243 573 625 103 107 605 -20 -1153 440 565 265 -247 28 867 410 171 334 502 545 1132 -384 86 -186 63 -315 -323 -425 -154 480 530 30 -43 -582 -722 29 -733 -11 74 -793 -1729 1160 -1725 479 174 -491 540 88 -342 -352 1339 -1026 534 607 244 99 422 -49 195 121 32 -462 -500 935 254 -237 387 -457 175 -580 -72 629 -226 268 1131 -259 -679 347 -5749 139 1121 -276 88 106 -1124 624 100 689 486 724 781 1479 1442 569 -364 1113 1199 1509 -193 1171 -262 -679 9 564 1224 -291 430 314 -460 -76 -725 192 -834 184 -381 -716 -1303 -1693 -1231 -1196 -458 440 -503 167 13 213 548 141 699 692 142 -42 661 412 46 -857 -1244 -683 -387 34 -1657 -1811 -142 -543 356 884 990 162 159 896 -28 -1583 610 826 381 -369 42 1252 622 248 460 659 705 1521 -560 133 -275 95 -495 -534 -740 -276 876 975 54 -75 -994 -1201 SS 20231220T191637.6Z 8754.803213 183 1 15.23 2 57.95 171.03 106.03 74.63 0.00 1 0.00 1 0 25 1.030e-02 6.370e-03 3.350e-03 1.525e-03 2.798575e-01 7.984853e-04 3.253616e-03 -6.000000e+00 6.133345e-03 223.97 -2.00 3.36 -2.00 316.34 0.00e+00 1.780420e-04 9.376822e-05 5.632399e-05 -6.000000e+00 2.753780e-04 282.00 -2.00 20.00 -2.00 315.68 0.00e+00 1.877 0.000 302.00 328.00 3 4.0343e+00 2.0580e-03 2.2889e-02 -6.0000e+00 1.5094e-02 2.9530e-04 2.3000e-03 1.3469e-02 -6.0000e+00 1.6370e-02 -4.2447e-03 1.3375e-03 6.7010e-03 -6.0000e+00 9.7863e-03 -1.1363e-03 6.2590e-04 1.9164e-03 -6.0000e+00 4.1537e-03 1.0402e-03 8.0453e-05 4.7620e-05 2.6394e-05 -6.0000e+00 3.1890e-04 -7.5126e-03 1.6873e-04 12 1 1 12 1 1 99.98 25.46 0.24 -0.00751 -0.00691 28 10 1 5 0 525.092 33.50 20.00 25.46 24.40 19.6 999.10 -424 -3801 -2731 -2633 -4040 -2875 -442 -1870 156 -1771 -2231 -1733 -970 360 405 1213 -109 513 1197 1566 1006 880 1204 1225 707 1044 -501 -275 -519 597 1105 1232 1345 150 -2770 -632 -922 -1039 162 42 -870 -1285 -340 -1700 -418 803 -825 -738 -50 -260 733 641 408 1200 475 872 1121 784 367 91 774 1465 1200 1021 449 -628 19 -101 728 1376 74 -82 -362 77 90 16 -35 -264 -32 31 -1211 -1463 -1800 -2148 -857 -970 -453 74 -95 160 220 605 349 586 845 690 354 354 309 -578 -589 -712 -395 321 71 -1233 -830 -615 -435 254 213 221 73 313 225 112 871 374 434 89 -142 -111 -158 392 287 830 87 852 1165 401 93 -403 -312 79 191 -189 -139 45 -19 -397 -108 -186 -640 -67 -696 -517 -486 -702 -464 -70 -331 30 -372 -483 -352 -212 89 114 348 -34 167 402 543 360 318 439 464 264 407 -200 -106 -190 226 427 474 559 66 -1233 -269 -411 -492 84 24 -561 -841 -229 -1180 -288 544 -563 -493 -33 -171 494 460 297 912 359 675 883 622 289 71 612 1215 1025 933 403 -574 16 -87 610 1261 73 -81 -365 76 87 15 -29 -219 -27 27 -1146 -1474 -1888 -2301 -962 -1120 -551 89 -116 191 257 675 374 623 880 751 412 438 397 -759 -741 -863 -466 375 88 -1588 -1080 -837 -600 357 306 327 106 447 308 148 1117 493 585 128 -206 -161 -223 550 399 1093 114 1094 1556 558 134 -580 -460 116 295 -300 -221 74 -32 -644 -175 -290 -1007 SS 20231220T201611.9Z 8754.844582 205 1 15.38 2 57.75 187.17 94.18 82.87 0.00 1 0.00 1 0 17 1.270e-02 6.521e-03 5.967e-03 2.393e-03 2.798566e-01 1.247300e-03 3.253235e-03 -6.000000e+00 7.558043e-03 223.97 -2.00 3.36 -2.00 316.64 0.00e+00 4.609386e-04 1.562747e-04 5.094794e-05 -6.000000e+00 3.393553e-04 282.00 -2.00 20.00 -2.00 315.95 0.00e+00 1.867 0.000 302.00 328.00 3 4.8419e+00 3.2304e-03 2.2827e-02 -6.0000e+00 1.8600e-02 -1.3811e-02 3.6204e-03 1.3514e-02 -6.0000e+00 2.0172e-02 -1.4784e-03 2.1233e-03 6.7231e-03 -6.0000e+00 1.2060e-02 -2.8364e-03 1.0108e-03 1.9591e-03 -6.0000e+00 5.1185e-03 4.7072e-04 7.9971e-05 7.4826e-05 2.6336e-05 -6.0000e+00 3.9299e-04 -7.8938e-03 1.4834e-04 12 9 1 12 1 1 98.42 25.53 0.27 -0.00789 -0.00729 9 4 1 5 0 1537.769 33.50 19.99 25.53 25.52 19.6 996.85 777 -1747 -246 -4288 -6587 -6219 -387 2573 355 -4375 -1499 -610 -120 1530 532 778 342 1190 -175 1121 1397 -770 1580 173 1470 539 -579 -1036 695 -5 2046 1075 1715 -271 -2180 -1880 -281 -898 153 126 -1033 -1288 -466 -2664 -717 -217 37 -903 -154 717 294 1239 203 1043 892 733 907 371 413 536 1075 1559 1402 889 206 -745 -374 -74 633 1602 102 226 -251 476 505 142 144 -350 -304 -273 -1271 -1755 -1554 -2214 -991 -679 -443 -39 -86 540 -288 424 343 426 893 461 705 408 245 -261 -585 -476 -523 385 -69 -966 -952 -559 -511 425 436 270 -127 335 351 240 343 91 55 152 -307 -573 74 559 412 779 -60 581 1054 416 253 55 -455 -106 189 59 -181 -189 317 -224 -135 -104 -808 99 -256 -37 -658 -961 -934 -56 392 56 -770 -263 -109 -23 333 134 200 95 343 -53 349 445 -253 513 59 525 203 -222 -386 242 -2 702 401 634 -107 -863 -725 -111 -407 75 68 -629 -841 -294 -1746 -463 -139 24 -567 -101 467 187 831 146 742 661 559 704 291 320 411 834 1272 1169 796 180 -668 -312 -63 521 1436 96 227 -245 473 473 129 119 -288 -253 -235 -1174 -1717 -1644 -2381 -1118 -779 -537 -47 -104 666 -338 476 373 441 943 506 818 502 324 -338 -758 -599 -619 450 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