File name: Pandora247s1_WhittierCA_20240413_L2Fit_fout2c2d20221229p1-8.txt File generation date: 20240414T075551.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Peter Peterson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 247 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora247_OF_v2d20221027.txt Instrument calibration file used: Pandora247s1_CF_v2d20221229.txt Level 1 file used: Pandora247s1_WhittierCA_20240413_L1_smca1c2d20221229p1-8.txt Full location name: Whittier College SLC Short location name: WhittierCA Country of location: United States Location latitude [deg]: 33.9768 Location longitude [deg]: -118.0299 Location altitude [m]: 130 Local noon date: 20240413 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 194 336 Nominal wavelengths inside fitting window [nm]: 305.0208 305.1616 305.3025 305.4433 305.5842 305.7250 305.8658 306.0066 306.1474 306.2881 306.4289 306.5696 306.7104 306.8511 306.9918 307.1325 307.2732 307.4139 307.5546 307.6952 307.8359 307.9765 308.1171 308.2577 308.3983 308.5389 308.6795 308.8201 308.9607 309.1012 309.2417 309.3823 309.5228 309.6633 309.8038 309.9443 310.0847 310.2252 310.3656 310.5061 310.6465 310.7869 310.9273 311.0677 311.2081 311.3484 311.4888 311.6291 311.7695 311.9098 312.0501 312.1904 312.3307 312.4710 312.6112 312.7515 312.8917 313.0320 313.1722 313.3124 313.4526 313.5928 313.7330 313.8731 314.0133 314.1534 314.2936 314.4337 314.5738 314.7139 314.8540 314.9941 315.1341 315.2742 315.4142 315.5542 315.6943 315.8343 315.9743 316.1142 316.2542 316.3942 316.5341 316.6740 316.8140 316.9539 317.0938 317.2337 317.3736 317.5134 317.6533 317.7931 317.9330 318.0728 318.2126 318.3524 318.4922 318.6320 318.7717 318.9115 319.0512 319.1910 319.3307 319.4704 319.6101 319.7498 319.8894 320.0291 320.1687 320.3084 320.4480 320.5876 320.7272 320.8668 321.0064 321.1460 321.2855 321.4251 321.5646 321.7041 321.8436 321.9831 322.1226 322.2621 322.4016 322.5410 322.6804 322.8199 322.9593 323.0987 323.2381 323.3775 323.5168 323.6562 323.7955 323.9349 324.0742 324.2135 324.3528 324.4921 324.6314 324.7706 324.9099 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240413T173412.3Z 8869.732087 159 1 3.29 2 40.09 119.63 84.30 59.89 0.00 1 0.00 1 0 17 1.218e-02 8.033e-03 9.194e-03 5.548e-03 2.244230e-01 2.964678e-03 2.594688e-03 -6.000000e+00 7.390932e-03 229.17 -2.00 3.36 -2.00 315.45 0.00e+00 6.662862e-04 2.838363e-04 5.585405e-05 -6.000000e+00 3.286859e-04 284.32 -2.00 20.00 -2.00 314.80 0.00e+00 1.306 0.000 302.00 328.00 3 5.0093e+00 7.6415e-03 1.7096e-02 -6.0000e+00 1.8395e-02 1.1431e-02 8.4764e-03 1.1048e-02 -6.0000e+00 1.9871e-02 -8.4002e-03 4.8530e-03 5.4081e-03 -6.0000e+00 1.1847e-02 -4.3990e-04 2.1568e-03 1.5982e-03 -6.0000e+00 4.9862e-03 7.3571e-04 1.1083e-04 1.7332e-04 2.2107e-05 -6.0000e+00 3.7759e-04 -7.1248e-03 1.2497e-04 12 9 1 12 1 1 999.00 25.47 0.41 -0.00712 -0.00629 1 3 1 5 0 1640.388 33.50 20.00 25.47 24.89 35.4 1004.50 -1212 1311 -3514 -3162 -5082 -1720 2905 550 -1547 -83 1248 -2038 -1278 2093 270 1321 175 3010 1644 -1260 2792 1884 1132 78 -580 1473 995 -1212 -2004 1695 1231 2298 472 -399 -3172 643 -265 537 -279 -277 -1788 -1454 44 -1765 -789 -491 -1832 -1578 -135 -130 252 267 794 975 1048 120 1418 274 802 1110 533 1423 530 489 355 -958 389 468 636 2099 -361 -494 69 535 777 -301 295 -210 1024 173 -1558 -1449 -1269 -2059 -1898 -989 -434 -577 783 282 -405 -135 753 378 980 1039 596 1091 435 -256 -229 -1326 -131 769 492 -957 -950 -680 -960 541 288 253 -299 612 76 -282 940 84 -225 301 -479 388 -79 72 111 1176 224 618 1011 100 -28 -119 -465 169 -517 -311 -352 201 267 -216 -16 67 -481 -311 362 -971 -912 -1377 -420 681 143 -453 -25 382 -604 -402 713 98 522 74 1282 733 -556 1208 827 504 36 -284 731 496 -595 -936 786 581 1062 237 -209 -1668 316 -137 293 -170 -185 -1274 -1098 33 -1400 -621 -383 -1427 -1194 -98 -94 186 208 618 794 882 104 1233 241 695 952 468 1245 479 468 345 -899 350 401 558 1987 -351 -510 72 542 776 -278 257 -180 867 152 -1486 -1458 -1372 -2273 -2131 -1175 -523 -724 979 346 -490 -155 821 392 1025 1122 684 1315 543 -326 -289 -1578 -152 882 599 -1213 -1218 -909 -1298 761 412 368 -428 847 101 -364 1168 107 -296 405 -676 545 -110 96 146 1511 276 776 1260 128 -39 -161 -644 240 -747 -457 -536 311 405 -337 -25 98 -711 SS 20240413T173806.9Z 8869.734802 162 1 11.26 2 39.39 120.66 83.62 60.37 0.00 1 0.00 1 0 17 8.113e-03 6.426e-03 1.244e-03 8.300e-04 2.191051e-01 4.466930e-04 2.538914e-03 -6.000000e+00 4.923222e-03 229.17 -2.00 3.36 -2.00 315.06 0.00e+00 2.069705e-04 3.941218e-05 2.686498e-05 -6.000000e+00 2.189083e-04 284.32 -2.00 20.00 -2.00 314.44 0.00e+00 1.293 0.000 302.00 328.00 3 3.2121e+00 1.1468e-03 1.6808e-02 -6.0000e+00 1.2253e-02 -5.9519e-03 1.2706e-03 1.0733e-02 -6.0000e+00 1.3235e-02 -5.2660e-03 7.2681e-04 5.2659e-03 -6.0000e+00 7.8914e-03 -3.4065e-04 3.1732e-04 1.4707e-03 -6.0000e+00 3.3218e-03 4.5789e-03 1.2590e-04 2.5876e-05 2.1769e-05 -6.0000e+00 2.5146e-04 -7.1146e-03 1.6556e-04 12 9 1 12 1 1 99.35 25.47 0.26 -0.00711 -0.00617 43 21 1 5 0 255.817 33.25 20.00 25.47 25.17 35.3 1004.59 664 -1241 -1375 -2180 -2558 -622 64 1105 1087 -42 -1464 -1229 421 -84 296 10 -529 303 1005 473 1061 134 872 1162 794 1065 -124 -860 24 753 1206 1497 1327 450 -2286 -1399 -856 -972 102 -578 -1485 -1215 -762 -843 -629 -303 -497 -362 -558 -77 788 1063 491 1160 533 627 959 531 415 718 951 1357 1349 962 339 -794 -222 60 398 1525 135 -108 6 -70 161 -176 47 -208 -255 135 -1196 -1441 -1770 -2065 -954 -899 -548 -85 -12 66 148 519 241 568 905 710 406 353 194 -395 -476 -507 -524 216 230 -1067 -923 -532 -502 96 281 169 61 278 110 386 706 502 308 227 -202 -187 266 293 298 671 211 691 1134 359 147 -196 -365 -116 149 -46 -231 120 17 -284 -227 -255 -714 205 -404 -463 -715 -776 -184 19 351 357 -15 -501 -425 153 -32 127 5 -240 141 479 233 532 68 444 580 417 579 -68 -459 12 375 604 753 712 251 -1286 -759 -481 -565 66 -405 -1124 -941 -607 -658 -490 -242 -392 -277 -432 -59 612 839 398 979 453 544 843 470 363 622 838 1214 1254 921 331 -747 -205 52 356 1432 133 -110 6 -73 158 -169 42 -179 -220 121 -1175 -1473 -1901 -2286 -1079 -1057 -664 -104 -15 80 173 582 262 599 964 771 474 430 241 -498 -590 -600 -602 253 271 -1326 -1175 -688 -664 130 389 239 87 379 145 486 882 629 400 307 -279 -260 360 392 390 851 263 839 1419 457 194 -267 -496 -161 213 -68 -345 180 25 -426 -338 -376 -1030 SS 20240413T174207.5Z 8869.737587 165 1 54.85 2 38.68 121.75 82.92 60.85 0.00 1 0.00 1 0 17 8.031e-03 6.236e-03 1.277e-03 7.832e-04 2.157991e-01 4.185015e-04 2.493821e-03 -6.000000e+00 4.873517e-03 229.17 -2.00 3.36 -2.00 315.38 0.00e+00 1.717229e-04 3.946677e-05 2.961251e-05 -6.000000e+00 2.166866e-04 284.32 -2.00 20.00 -2.00 314.73 0.00e+00 1.280 0.000 302.00 328.00 3 4.6510e+00 1.0778e-03 1.6605e-02 -6.0000e+00 1.2130e-02 -5.0751e-03 1.1955e-03 1.0579e-02 -6.0000e+00 1.3102e-02 -2.1205e-03 6.8414e-04 5.1912e-03 -6.0000e+00 7.8117e-03 -2.3662e-03 3.0325e-04 1.4479e-03 -6.0000e+00 3.2884e-03 1.1057e-03 2.3538e-04 2.4454e-05 2.1088e-05 -6.0000e+00 2.4890e-04 -7.3701e-03 1.6856e-04 10 0 0 10 0 0 99.99 25.48 0.35 -0.00737 -0.00560 98 10 1 5 0 559.576 33.50 20.00 25.48 25.43 35.4 1004.89 79 -1664 -1168 -2412 -2582 -486 642 590 797 -263 -1545 -775 631 411 502 695 -819 89 878 621 1008 384 1131 1033 774 537 -255 -692 315 920 1542 1115 863 345 -2418 -1417 -352 -946 190 -408 -1254 -1279 -757 -1300 -736 11 -655 -545 -283 -407 701 860 574 884 488 772 950 562 283 843 935 1241 1372 865 570 -826 -98 -6 363 1601 161 22 67 -254 227 -267 -22 -98 -265 -48 -1180 -1306 -1718 -1987 -946 -709 -525 38 12 206 57 603 232 553 1008 686 376 407 208 -339 -559 -486 -367 232 76 -1108 -829 -610 -589 288 316 145 34 126 142 283 598 444 296 271 -281 -225 66 360 365 797 140 661 988 316 169 -199 -508 -57 217 -84 -217 196 128 -287 -76 -276 -751 21 -456 -329 -665 -712 -122 161 160 239 -78 -472 -238 204 148 189 286 -361 40 379 277 457 176 519 490 386 279 -134 -350 149 413 695 533 440 182 -1288 -727 -186 -534 118 -279 -908 -985 -599 -996 -562 9 -514 -415 -209 -298 521 674 454 729 418 674 801 477 238 736 790 1102 1246 834 559 -783 -89 -5 321 1464 157 23 71 -262 230 -249 -19 -85 -229 -43 -1127 -1317 -1796 -2203 -1058 -845 -637 48 14 255 66 696 245 574 1058 745 433 495 261 -432 -711 -574 -426 268 93 -1412 -1065 -818 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