File name: Pandora247s1_WhittierCA_20240415_L2Fit_fout2c2d20221229p1-8.txt File generation date: 20240416T075707.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Peter Peterson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 247 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora247_OF_v2d20221027.txt Instrument calibration file used: Pandora247s1_CF_v2d20221229.txt Level 1 file used: Pandora247s1_WhittierCA_20240415_L1_smca1c2d20221229p1-8.txt Full location name: Whittier College SLC Short location name: WhittierCA Country of location: United States Location latitude [deg]: 33.9768 Location longitude [deg]: -118.0299 Location altitude [m]: 130 Local noon date: 20240415 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 194 336 Nominal wavelengths inside fitting window [nm]: 305.0208 305.1616 305.3025 305.4433 305.5842 305.7250 305.8658 306.0066 306.1474 306.2881 306.4289 306.5696 306.7104 306.8511 306.9918 307.1325 307.2732 307.4139 307.5546 307.6952 307.8359 307.9765 308.1171 308.2577 308.3983 308.5389 308.6795 308.8201 308.9607 309.1012 309.2417 309.3823 309.5228 309.6633 309.8038 309.9443 310.0847 310.2252 310.3656 310.5061 310.6465 310.7869 310.9273 311.0677 311.2081 311.3484 311.4888 311.6291 311.7695 311.9098 312.0501 312.1904 312.3307 312.4710 312.6112 312.7515 312.8917 313.0320 313.1722 313.3124 313.4526 313.5928 313.7330 313.8731 314.0133 314.1534 314.2936 314.4337 314.5738 314.7139 314.8540 314.9941 315.1341 315.2742 315.4142 315.5542 315.6943 315.8343 315.9743 316.1142 316.2542 316.3942 316.5341 316.6740 316.8140 316.9539 317.0938 317.2337 317.3736 317.5134 317.6533 317.7931 317.9330 318.0728 318.2126 318.3524 318.4922 318.6320 318.7717 318.9115 319.0512 319.1910 319.3307 319.4704 319.6101 319.7498 319.8894 320.0291 320.1687 320.3084 320.4480 320.5876 320.7272 320.8668 321.0064 321.1460 321.2855 321.4251 321.5646 321.7041 321.8436 321.9831 322.1226 322.2621 322.4016 322.5410 322.6804 322.8199 322.9593 323.0987 323.2381 323.3775 323.5168 323.6562 323.7955 323.9349 324.0742 324.2135 324.3528 324.4921 324.6314 324.7706 324.9099 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240415T142032.1Z 8871.597594 105 1 40.65 2 78.52 85.50 120.16 4.80 0.00 1 0.00 1 0 25 5.383e-01 1.301e-02 2.293e-01 4.819e-03 8.127369e-01 2.734746e-03 8.799352e-03 -6.000000e+00 3.291540e-01 229.30 -2.00 3.36 -2.00 321.16 0.00e+00 5.620284e-03 1.350302e-03 8.483216e-04 -6.000000e+00 1.465519e-02 284.48 -2.00 20.00 -2.00 320.61 0.00e+00 4.858 0.002 302.00 328.00 3 3.3259e+00 9.2948e-03 6.3806e-02 -6.0000e+00 8.1954e-01 2.5078e-01 1.2931e-02 4.2728e-02 -6.0000e+00 8.8701e-01 -3.2356e-01 1.3084e-02 2.3828e-02 -6.0000e+00 5.2684e-01 1.2306e-01 6.1888e-03 1.1020e-02 -6.0000e+00 2.2135e-01 6.1702e-05 -1.8707e-03 1.3284e-04 1.3377e-04 -6.0000e+00 1.6907e-02 -1.2102e-03 -1.7907e-04 12 9 9 12 1 1 99.96 25.20 0.50 -0.00121 -0.01527 28 4 1 5 0 1401.526 33.25 20.00 25.20 19.31 34.7 1004.97 900000 -227299 -135526 -168498 -193822 -141220 900000 10291 -205944 -164934 -115606 -224169 -156409 -32890 -66615 900000 -107533 -60967 -56742 -65473 -26077 -55982 -7650 -83213 -11377 28446 -90540 -49176 -26873 -64913 -31841 -25851 -63581 18486 -36140 -27557 66787 -22685 2446 11389 -13104 -283 2773 6754 3023 14090 14592 14021 22004 -7207 4215 1213 5997 4940 14319 5877 18715 10335 4118 1060 10810 -3830 7858 -11490 11568 7262 7864 4134 1934 4570 613 5540 1844 115 -399 -3382 -1217 3310 1092 2123 -1679 600 -1068 -1003 -1548 -580 -770 -466 456 -287 -1233 777 -1091 -429 -147 373 -343 -1277 -120 12 -709 -760 -445 43 -315 -1590 -625 -1128 -960 -358 418 488 -283 -519 385 -152 -921 578 1351 415 -306 240 704 1019 906 130 817 712 1186 255 -5 -756 6 -362 -168 -274 77 331 791 -168 -78 -244 -1150 900000 -2621 -694 -1223 -1738 -724 900000 48 -2550 -1479 -691 -4595 -2070 -185 -688 900000 -2475 -1002 -986 -1322 -367 -1078 -93 -2306 -166 294 -3147 -1132 -505 -1951 -823 -777 -3315 469 -1613 -1126 1129 -1087 110 562 -948 -20 201 489 233 999 1069 1087 1685 -806 469 157 828 756 2146 1008 2910 1753 727 189 1782 -793 1646 -3325 2907 1965 2135 1212 635 1508 234 2129 736 44 -142 -1233 -405 1062 397 823 -804 326 -660 -670 -1107 -399 -558 -348 338 -208 -933 543 -753 -303 -105 311 -338 -1352 -139 15 -826 -806 -462 42 -325 -1758 -669 -1303 -1220 -475 618 784 -474 -864 613 -235 -1423 909 2209 709 -490 394 1097 1524 1308 182 1112 999 1844 426 -9 -1465 13 -797 -372 -639 184 801 1899 -395 -171 -532 -2415 SS 20240415T143406.6Z 8871.607021 114 1 54.86 2 75.71 87.35 119.88 8.14 0.00 1 0.00 1 0 17 2.638e-01 7.444e-03 9.928e-02 2.141e-03 6.751020e-01 1.168808e-03 7.397575e-03 -6.000000e+00 1.600115e-01 229.30 -2.00 3.36 -2.00 320.28 0.00e+00 2.802176e-03 4.394513e-04 9.970600e-04 -6.000000e+00 7.122315e-03 284.48 -2.00 20.00 -2.00 319.65 0.00e+00 3.964 0.001 302.00 328.00 3 3.2503e+00 3.5135e-03 5.2080e-02 -6.0000e+00 3.9835e-01 8.6064e-02 4.4470e-03 3.4253e-02 -6.0000e+00 4.3037e-01 -1.1690e-01 4.1402e-03 1.8157e-02 -6.0000e+00 2.5657e-01 3.9536e-02 2.0792e-03 6.5255e-03 -6.0000e+00 1.0789e-01 1.8297e-04 -8.1714e-04 6.0694e-05 8.0264e-05 -6.0000e+00 8.1799e-03 -4.4967e-03 3.2096e-07 11 8 0 10 0 0 99.99 25.21 0.21 -0.00450 -0.01064 90 9 1 5 0 609.460 33.25 19.99 25.21 19.45 34.5 1004.73 -20381 -85023 -100784 -78004 -128094 -39957 -31398 -108433 -88915 -65274 -92392 -77082 -55199 -44828 -37106 4611 -44453 -16497 -29412 -15519 -899 -13579 -7106 -28043 -12571 829 -26590 -5977 -5702 -14808 -12458 -10085 -18417 569 -3576 -2661 10013 -9600 2909 3758 -4116 -1559 2686 -18145 1898 2779 733 4274 5379 -790 3496 2454 4090 1863 1684 1849 3937 2746 466 -307 4230 2214 3208 -1573 3532 239 854 268 756 2733 911 1249 423 -648 -454 -775 -447 -210 -580 -820 -1187 -913 -1128 -1469 -1206 -995 -439 -338 781 308 450 411 -97 369 309 452 268 447 -134 -160 -982 -650 -461 246 99 -1061 -523 -795 -658 180 165 -119 -113 3 65 -1 404 979 711 487 -67 -142 455 452 248 368 35 235 659 116 -196 -503 -283 -259 31 -151 -274 46 494 11 162 -167 -472 -62 -597 -1010 -635 -1658 -209 -157 -1313 -1002 -641 -1292 -1046 -738 -693 -674 67 -1234 -389 -866 -424 -22 -388 -197 -1030 -430 26 -1149 -210 -200 -603 -570 -539 -1250 35 -234 -172 608 -824 267 410 -559 -227 398 -3432 300 446 123 717 938 -157 731 527 959 487 473 545 1174 835 143 -93 1250 720 1158 -668 1534 109 383 124 344 1379 520 754 260 -385 -249 -387 -206 -96 -287 -472 -804 -653 -900 -1266 -1026 -898 -415 -330 759 293 404 346 -85 323 274 457 293 521 -173 -214 -1268 -765 -528 272 113 -1230 -637 -1036 -876 265 252 -196 -190 5 103 -2 599 1486 1136 812 -114 -233 714 684 382 545 50 344 992 197 -352 -923 -547 -504 63 -315 -591 101 1075 23 342 -331 -948 SS 20240415T151647.5Z 8871.636661 123 1 54.59 2 66.86 93.34 118.00 18.37 0.00 1 0.00 1 0 17 3.056e-02 6.376e-03 1.358e-03 2.681e-04 4.369647e-01 1.422100e-04 4.922491e-03 -6.000000e+00 1.854345e-02 229.30 -2.00 3.36 -2.00 317.92 0.00e+00 8.397984e-04 2.477188e-05 2.088982e-04 -6.000000e+00 8.250346e-04 284.49 -2.00 20.00 -2.00 317.16 0.00e+00 2.524 0.000 302.00 328.00 3 1.0197e+00 3.8001e-04 3.3163e-02 -6.0000e+00 4.6164e-02 -6.3002e-03 4.2838e-04 2.1513e-02 -6.0000e+00 4.9866e-02 -2.9704e-02 2.7083e-04 1.0573e-02 -6.0000e+00 2.9730e-02 9.2360e-03 1.3761e-04 3.0376e-03 -6.0000e+00 1.2507e-02 8.9930e-03 -2.7533e-04 8.1319e-06 3.6780e-05 -6.0000e+00 9.4735e-04 -5.3963e-03 1.0287e-04 10 0 0 10 0 0 91.57 25.23 0.27 -0.00540 -0.00747 1248 123 1 5 0 43.737 33.25 20.00 25.23 22.24 34.8 1007.41 -10210 -8934 -8152 -9536 -13084 -12785 -11272 -8122 -7957 -8646 -9070 -7649 -4735 -3327 -1347 -852 -844 570 1137 1267 1587 552 1257 1005 65 144 -794 -2023 -1109 -152 881 907 703 -110 -2710 -2294 -1391 -1146 350 123 -634 -719 -130 -471 -51 546 62 86 253 195 1104 1508 1088 1522 1013 890 1231 499 227 624 1080 1760 1758 1390 792 -444 190 14 431 1477 146 -54 -134 -294 -2 -371 -127 -333 -510 -286 -1303 -1538 -1881 -2196 -1231 -909 -587 -83 -41 165 225 656 271 345 713 561 235 350 137 -469 -542 -751 -589 189 148 -1260 -891 -638 -503 287 279 167 1 230 289 400 762 655 478 263 -214 -8 238 425 351 793 104 640 1013 230 59 -298 -337 -109 96 -142 -243 131 50 -230 -99 -230 -671 -546 -545 -529 -624 -838 -780 -698 -540 -593 -704 -780 -630 -431 -356 -169 -123 -135 89 188 219 283 101 234 199 14 32 -184 -464 -245 -33 205 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