File name: Pandora247s1_WhittierCA_20240503_L2Fit_fwvt1c2d20221229p1-8.txt File generation date: 20240504T081020.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Peter Peterson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 247 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora247_OF_v2d20221027.txt Instrument calibration file used: Pandora247s1_CF_v2d20221229.txt Level 1 file used: Pandora247s1_WhittierCA_20240503_L1_smca1c2d20221229p1-8.txt Full location name: Whittier College SLC Short location name: WhittierCA Country of location: United States Location latitude [deg]: 33.9768 Location longitude [deg]: -118.0299 Location altitude [m]: 130 Local noon date: 20240503 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 1616 1766 Nominal wavelengths inside fitting window [nm]: 492.0013 492.1221 492.2429 492.3636 492.4844 492.6051 492.7258 492.8465 492.9672 493.0878 493.2084 493.3291 493.4497 493.5703 493.6908 493.8114 493.9319 494.0524 494.1729 494.2934 494.4139 494.5344 494.6548 494.7752 494.8956 495.0160 495.1364 495.2567 495.3771 495.4974 495.6177 495.7380 495.8582 495.9785 496.0987 496.2189 496.3391 496.4593 496.5795 496.6996 496.8198 496.9399 497.0600 497.1801 497.3001 497.4202 497.5402 497.6602 497.7802 497.9002 498.0202 498.1401 498.2601 498.3800 498.4999 498.6197 498.7396 498.8594 498.9793 499.0991 499.2189 499.3387 499.4584 499.5782 499.6979 499.8176 499.9373 500.0570 500.1766 500.2963 500.4159 500.5355 500.6551 500.7747 500.8942 501.0138 501.1333 501.2528 501.3723 501.4917 501.6112 501.7306 501.8501 501.9695 502.0888 502.2082 502.3276 502.4469 502.5662 502.6855 502.8048 502.9241 503.0433 503.1625 503.2818 503.4010 503.5201 503.6393 503.7584 503.8776 503.9967 504.1158 504.2349 504.3539 504.4730 504.5920 504.7110 504.8300 504.9490 505.0679 505.1869 505.3058 505.4247 505.5436 505.6625 505.7813 505.9002 506.0190 506.1378 506.2566 506.3753 506.4941 506.6128 506.7315 506.8502 506.9689 507.0876 507.2062 507.3249 507.4435 507.5621 507.6807 507.7992 507.9178 508.0363 508.1548 508.2733 508.3918 508.5102 508.6287 508.7471 508.8655 508.9839 509.1023 509.2206 509.3390 509.4573 509.5756 509.6939 509.8121 509.9304 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240503T193803.0Z 8889.818091 300 1 9.67 2 18.15 171.56 65.62 239.08 0.00 1 0.00 1 0 15 3.381e-03 3.355e-03 1.675e-03 1.672e-03 1.022081e+03 9.244622e+01 8.053042e+01 -6.000000e+00 1.816928e+02 286.14 -2.00 20.00 -2.00 505.25 0.00e+00 5.864026e-04 4.531589e-05 3.487864e-05 -6.000000e+00 9.383526e-05 286.14 -2.00 20.00 -2.00 500.40 0.00e+00 8.575363e-02 3.214936e-02 7.848362e-03 -6.000000e+00 6.533422e-02 230.50 -2.00 3.36 -2.00 502.00 0.00e+00 1.052 0.000 489.00 513.00 1 7.0927e+00 2.4624e-03 1.8208e-03 -6.0000e+00 5.0045e-03 8.4222e-03 6.4478e-04 1.8627e-04 -6.0000e+00 1.3092e-03 1.3836e-03 1.0187e-03 1.3821e-04 1.3551e-05 -6.0000e+00 2.8625e-04 -5.6803e-04 2.7534e-04 12 1 1 12 1 1 -24.85 25.81 1.99 -0.00057 0.00650 3 2 1 4 0 2415.123 33.50 20.00 25.81 30.69 35.5 998.77 -638 -841 -87 205 223 529 615 736 362 134 103 20 -227 -203 -317 -5 52 -2 199 54 232 -107 49 428 98 137 557 246 -251 -61 -92 -594 -414 108 315 -81 345 21 -166 -147 -80 -206 73 148 224 258 350 166 363 -215 -247 -814 -822 -407 -549 -269 -370 -82 22 23 208 218 -237 397 335 16 -128 -224 -50 -336 -355 -111 164 186 197 202 -63 51 -354 -554 -478 -75 -333 -79 -74 3 156 -370 -196 -336 53 65 107 30 282 443 210 -1 -272 -458 -835 -692 -294 -164 -78 105 265 -354 -249 -664 -316 -117 9 194 557 492 480 602 430 676 313 -29 131 19 25 109 186 -164 799 512 250 -126 -78 21 -427 77 -141 53 73 475 166 -239 78 380 366 273 152 -511 -482 -609 -350 -622 -832 -87 209 233 551 653 775 382 142 108 21 -235 -207 -320 -5 54 -2 207 57 245 -114 52 452 104 146 589 259 -258 -62 -92 -600 -415 112 333 -85 364 22 -172 -150 -81 -211 75 154 233 269 362 173 371 -220 -244 -800 -796 -393 -546 -271 -377 -85 22 23 212 223 -241 408 343 16 -128 -224 -50 -327 -348 -109 159 183 196 201 -62 49 -343 -535 -463 -72 -322 -76 -72 3 153 -363 -192 -331 52 65 107 30 281 443 207 -1 -260 -436 -790 -661 -283 -161 -78 105 260 -350 -242 -647 -312 -115 9 193 555 492 483 607 431 665 309 -29 126 19 25 107 182 -160 770 496 242 -120 -74 20 -399 72 -136 52 71 460 162 -236 77 376 364 270 148 -496 -454 -580 -328 SQ 20240503T194236.9Z 8889.821260 303 1 4.91 2 18.04 175.08 66.40 239.92 0.00 1 0.00 1 0 15 2.791e-03 2.775e-03 2.943e-04 2.938e-04 8.720744e+02 1.612181e+01 6.514138e+01 -6.000000e+00 1.499641e+02 286.14 -2.00 20.00 -2.00 505.25 0.00e+00 5.424244e-04 7.969967e-06 3.243667e-05 -6.000000e+00 7.745102e-05 286.14 -2.00 20.00 -2.00 500.42 0.00e+00 7.382343e-02 5.639781e-03 7.435438e-03 -6.000000e+00 5.393723e-02 230.50 -2.00 3.36 -2.00 502.02 0.00e+00 1.052 0.000 489.00 513.00 1 3.2572e+00 4.3190e-04 1.7801e-03 -6.0000e+00 4.1314e-03 6.0148e-03 1.1310e-04 1.7139e-04 -6.0000e+00 1.0810e-03 6.4210e-02 1.6215e-03 2.4370e-05 1.1747e-05 -6.0000e+00 2.3625e-04 -6.4580e-03 2.9445e-04 12 1 1 12 1 1 97.46 25.83 1.96 -0.00646 0.00479 93 54 1 4 0 52.134 33.50 20.00 25.83 31.00 35.6 999.53 -655 -631 -134 36 201 463 484 516 378 171 258 43 -218 -314 -377 -279 -147 -11 6 22 211 137 126 214 245 335 455 313 -214 -261 -263 -390 -240 157 104 249 276 -27 -81 -102 -58 -57 139 172 352 317 266 314 223 -202 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121 169 47 98 201 178 253 114 -51 -366 -345 -448 -413 SQ 20240503T194612.1Z 8889.823751 306 1 19.38 2 17.99 177.86 67.02 240.58 0.00 1 0.00 1 0 15 2.854e-03 2.837e-03 1.380e-04 1.377e-04 8.861111e+02 7.568599e+00 6.627069e+01 -6.000000e+00 1.533638e+02 286.14 -2.00 20.00 -2.00 505.25 0.00e+00 5.650293e-04 3.734902e-06 3.368369e-05 -6.000000e+00 7.920711e-05 286.14 -2.00 20.00 -2.00 500.42 0.00e+00 8.512231e-02 2.644969e-03 7.608235e-03 -6.000000e+00 5.516202e-02 230.50 -2.00 3.36 -2.00 502.01 0.00e+00 1.051 0.000 489.00 513.00 1 3.1269e+00 2.0257e-04 1.7974e-03 -6.0000e+00 4.2251e-03 4.1366e-03 5.3036e-05 1.7373e-04 -6.0000e+00 1.1056e-03 7.3060e-02 1.6427e-03 1.1425e-05 1.2080e-05 -6.0000e+00 2.4160e-04 -6.1122e-03 2.8972e-04 10 0 0 10 0 0 99.75 25.85 1.95 -0.00611 0.00528 552 55 1 4 0 35.094 33.75 20.00 25.85 31.58 35.6 1000.22 -657 -638 -168 34 244 486 442 528 368 202 257 63 -197 -338 -379 -285 -194 16 24 10 219 140 98 286 209 332 439 327 -270 -260 -293 -367 -236 197 89 293 247 53 -92 -122 -67 -68 140 184 332 314 319 292 203 -181 -397 -642 -788 -561 -442 -308 -98 39 21 62 51 120 78 175 170 85 85 30 -168 -419 -291 -175 -76 127 33 45 37 34 -212 -387 -247 -200 -240 -70 -60 -67 -74 -127 -136 -133 -140 84 121 121 254 333 189 -1 -369 -514 -627 -559 -391 -124 -224 9 -37 -278 -291 -254 -229 -77 198 282 384 540 581 477 303 367 197 70 192 212 72 297 296 182 347 457 67 120 39 -221 -296 -101 -205 -110 155 158 62 140 172 184 233 173 -98 -362 -343 -487 -463 -641 -630 -167 34 253 506 466 555 388 212 268 66 -203 -342 -386 -288 -198 17 25 11 231 147 103 301 220 349 459 344 -281 -262 -292 -368 -237 203 94 310 258 56 -95 -126 -69 -70 144 191 347 326 332 301 208 -184 -395 -628 -769 -548 -438 -309 -100 40 21 63 52 122 79 179 172 86 85 29 -167 -410 -284 -171 -74 125 33 45 36 33 -205 -372 -238 -193 -233 -68 -58 -65 -72 -125 -133 -131 -139 83 121 123 254 331 185 -1 -356 -490 -593 -528 -375 -122 -224 9 -37 -273 -284 -248 -225 -76 196 283 387 540 583 482 304 366 193 68 188 206 71 291 290 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