File name: Pandora247s1_WhittierCA_20240512_L2Fit_fout2c6d20230505p1-8.txt File generation date: 20241125T190453.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Peter Peterson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 247 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora247_OF_v2d20221027.txt Instrument calibration file used: Pandora247s1_CF_v6d20230505.txt Level 1 file used: Pandora247s1_WhittierCA_20240512_L1_smca1c6d20230505p1-8.txt Full location name: Whittier College SLC Short location name: WhittierCA Country of location: United States Location latitude [deg]: 33.9768 Location longitude [deg]: -118.0299 Location altitude [m]: 130 Local noon date: 20240512 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 5 "based on session 2 trying to improve labcal" First and last pixel inside fitting window: 195 336 Nominal wavelengths inside fitting window [nm]: 305.1400 305.2810 305.4219 305.5629 305.7038 305.8447 305.9856 306.1265 306.2673 306.4082 306.5491 306.6899 306.8307 306.9715 307.1124 307.2531 307.3939 307.5347 307.6755 307.8162 307.9569 308.0977 308.2384 308.3791 308.5198 308.6605 308.8011 308.9418 309.0824 309.2231 309.3637 309.5043 309.6449 309.7855 309.9260 310.0666 310.2072 310.3477 310.4882 310.6287 310.7692 310.9097 311.0502 311.1907 311.3311 311.4716 311.6120 311.7524 311.8929 312.0333 312.1736 312.3140 312.4544 312.5947 312.7351 312.8754 313.0157 313.1560 313.2963 313.4366 313.5769 313.7171 313.8574 313.9976 314.1379 314.2781 314.4183 314.5585 314.6986 314.8388 314.9790 315.1191 315.2592 315.3993 315.5395 315.6796 315.8196 315.9597 316.0998 316.2398 316.3799 316.5199 316.6599 316.7999 316.9399 317.0799 317.2198 317.3598 317.4997 317.6397 317.7796 317.9195 318.0594 318.1993 318.3391 318.4790 318.6188 318.7587 318.8985 319.0383 319.1781 319.3179 319.4577 319.5974 319.7372 319.8769 320.0167 320.1564 320.2961 320.4358 320.5755 320.7151 320.8548 320.9944 321.1341 321.2737 321.4133 321.5529 321.6925 321.8321 321.9716 322.1112 322.2507 322.3902 322.5298 322.6693 322.8087 322.9482 323.0877 323.2271 323.3666 323.5060 323.6454 323.7848 323.9242 324.0636 324.2030 324.3424 324.4817 324.6210 324.7604 324.8997 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240512T171500.2Z 8898.718753 157 1 55.69 2 37.52 104.67 85.03 61.36 0.00 1 0.00 1 0 17 1.276e-02 8.294e-03 4.595e-03 2.536e-03 1.921319e-01 1.352671e-03 2.191269e-03 -6.000000e+00 7.718816e-03 231.08 -2.00 3.36 -2.00 315.85 0.00e+00 4.266814e-04 1.398995e-04 2.731058e-05 -6.000000e+00 3.438154e-04 286.95 -2.00 20.00 -2.00 315.12 0.00e+00 1.260 0.000 302.00 328.00 3 5.9757e+00 3.5196e-03 1.5748e-02 -6.0000e+00 1.9288e-02 9.1284e-03 3.9068e-03 9.5124e-03 -6.0000e+00 2.0809e-02 8.7552e-04 2.2418e-03 4.6107e-03 -6.0000e+00 1.2394e-02 -3.6780e-03 1.0154e-03 1.3023e-03 -6.0000e+00 5.2560e-03 3.1412e-04 6.9074e-04 7.8341e-05 1.7107e-05 -6.0000e+00 3.8606e-04 -4.0820e-03 -3.7840e-05 11 9 0 11 8 0 99.93 25.58 0.47 -0.00408 0.00111 17 2 1 5 0 3275.502 33.50 20.00 25.58 28.33 35.4 1000.23 477 -279 -2395 -6068 -2034 697 3630 -641 -235 327 2861 -1575 1021 1548 258 400 373 2070 176 333 1176 803 -104 2529 3784 -1200 -1064 -529 133 -1019 1496 268 1976 -887 -4014 336 -2078 -872 457 -1269 -2193 -447 -4684 -33 1362 -458 -989 1035 -1296 -507 83 489 984 702 714 1750 1634 339 1495 520 782 1574 -493 1819 -241 145 -550 -526 1227 -275 1712 626 373 574 -69 -105 -296 -1438 -295 -1563 -412 -1425 -1879 -1047 -658 -424 -69 884 906 -108 767 -455 -611 299 414 16 333 467 549 -262 -866 -724 -269 -158 -1009 -711 -313 -448 420 793 483 34 125 -224 -796 -985 369 234 482 -240 -93 361 393 386 526 -361 331 665 756 139 -139 -216 -205 214 285 77 326 507 25 -149 -612 -1216 116 -71 -599 -1436 -427 142 782 -160 -62 86 737 -448 315 484 89 145 139 782 70 134 472 325 -44 1084 1660 -554 -471 -218 52 -403 608 117 876 -394 -1771 147 -1056 -517 285 -894 -1653 -341 -3778 -26 1027 -346 -727 722 -912 -361 62 384 803 594 568 1399 1310 272 1275 420 665 1424 -481 1755 -225 124 -484 -436 1098 -275 1778 620 390 569 -63 -93 -244 -1195 -262 -1444 -415 -1447 -2019 -1184 -793 -505 -86 1095 1097 -134 858 -505 -637 313 431 18 420 586 696 -320 -1059 -836 -311 -194 -1244 -917 -420 -627 614 1133 704 48 178 -295 -1048 -1263 479 302 663 -347 -136 512 538 503 696 -458 407 845 1017 184 -190 -301 -293 319 421 118 511 803 40 -229 -912 -1780 SS 20240512T173134.9Z 8898.730265 169 1 2.32 2 34.22 108.33 82.10 63.42 0.00 1 0.00 1 0 17 8.419e-03 6.817e-03 2.171e-03 1.604e-03 1.831397e-01 8.663627e-04 2.112096e-03 -6.000000e+00 5.089508e-03 231.08 -2.00 3.36 -2.00 314.63 0.00e+00 2.469262e-04 6.985393e-05 1.823590e-05 -6.000000e+00 2.268657e-04 286.95 -2.00 20.00 -2.00 314.00 0.00e+00 1.209 0.000 302.00 328.00 3 2.2478e+00 2.2243e-03 1.5063e-02 -6.0000e+00 1.2717e-02 -1.5397e-02 2.4548e-03 9.0434e-03 -6.0000e+00 1.3723e-02 -2.7644e-03 1.4059e-03 4.3946e-03 -6.0000e+00 8.1732e-03 -1.3974e-03 6.0952e-04 1.2155e-03 -6.0000e+00 3.4644e-03 1.4151e-02 1.7180e-04 4.9132e-05 1.8012e-05 -6.0000e+00 2.5468e-04 -3.9818e-03 -1.5881e-04 12 9 1 12 1 1 82.04 25.63 0.32 -0.00398 -0.00269 11 28 1 5 0 192.785 33.50 20.00 25.63 29.62 35.3 1001.62 -195 -969 -1667 -2608 -824 -611 940 -3 754 -1447 -1453 731 22 191 479 -394 368 900 629 1828 409 940 1018 765 1195 344 -493 -172 -485 504 1301 1515 1050 -2666 -2149 -1222 -1665 -49 -120 -1078 -1234 -562 -758 -697 63 -698 -629 -29 -524 689 1288 794 1072 772 542 1255 825 198 447 400 1245 1259 1305 649 -462 -488 -690 -110 1347 135 161 195 31 568 102 -358 -938 -800 -261 -1121 -1531 -1778 -2128 -1004 -687 -485 92 -41 377 478 657 29 -133 444 592 483 368 536 -181 -52 -761 -824 -235 439 -964 -833 -648 -544 283 503 423 379 90 -118 246 363 22 574 339 11 -49 207 275 484 701 224 345 901 422 144 -164 -536 -77 132 9 -441 206 208 -192 -48 -394 -889 -76 -390 -650 -990 -284 -210 346 -1 308 -609 -611 301 10 93 241 -200 191 476 342 1005 228 524 559 441 710 207 -286 -97 -261 269 725 853 612 -1568 -1212 -709 -1052 -33 -88 -853 -1002 -467 -639 -586 52 -573 -516 -23 -409 542 1061 670 913 680 473 1104 730 175 390 355 1155 1214 1289 633 -444 -457 -612 -99 1272 134 164 203 32 562 98 -322 -811 -710 -241 -1089 -1551 -1887 -2325 -1121 -798 -583 112 -50 451 566 729 32 -137 462 642 546 435 659 -227 -64 -896 -942 -269 518 -1171 -1062 -839 -716 381 689 591 515 121 -149 302 444 28 725 438 15 -66 277 364 623 876 274 412 1107 524 184 -217 -704 -103 182 12 -639 303 304 -279 -70 -565 -1252 SS 20240512T173622.2Z 8898.733591 172 1 45.64 2 33.28 109.48 81.25 64.00 0.00 1 0.00 1 0 17 7.991e-03 6.539e-03 5.210e-04 3.825e-04 1.818599e-01 2.067106e-04 2.100693e-03 -6.000000e+00 4.831466e-03 231.08 -2.00 3.36 -2.00 314.66 0.00e+00 3.117536e-04 1.684824e-05 1.686765e-05 -6.000000e+00 2.153053e-04 286.95 -2.00 20.00 -2.00 314.04 0.00e+00 1.195 0.000 302.00 328.00 3 2.4452e+00 5.3064e-04 1.4932e-02 -6.0000e+00 1.2073e-02 -1.1184e-02 5.8562e-04 8.9991e-03 -6.0000e+00 1.3027e-02 -3.0936e-03 3.3542e-04 4.3732e-03 -6.0000e+00 7.7587e-03 -2.0664e-03 1.4556e-04 1.2189e-03 -6.0000e+00 3.2889e-03 1.1776e-02 3.3602e-04 1.1707e-05 1.7789e-05 -6.0000e+00 2.4173e-04 -3.3343e-03 -1.0348e-04 12 9 1 12 1 1 99.99 25.66 0.32 -0.00333 -0.00081 293 35 1 5 0 155.211 33.50 20.00 25.66 30.19 35.3 1001.77 -537 -665 -1271 -2663 -791 -492 888 1263 409 -1318 -1213 -76 -437 234 443 -496 179 889 841 1251 503 856 980 635 797 416 -418 40 434 1096 1306 1516 922 -2187 -1976 -1553 -1494 -250 -178 -1158 -1136 -640 -833 -726 -24 -555 -508 -463 -457 427 861 620 1086 708 650 1021 676 283 430 610 1151 1270 1237 849 -565 -300 -600 -80 1322 377 173 212 204 506 -71 -345 -742 -717 -198 -1118 -1422 -1670 -2139 -1154 -776 -438 110 161 382 349 583 -50 81 692 557 292 508 629 -126 -289 -724 -788 -52 235 -1020 -775 -621 -639 268 430 388 162 216 51 -20 277 310 365 440 -11 -71 137 380 239 802 -13 420 968 413 283 -175 -385 -212 168 4 -221 133 117 -210 -122 -296 -852 -208 -266 -492 -952 -273 -169 327 481 166 -518 -505 -31 -198 111 218 -257 95 480 443 671 272 463 544 370 458 240 -245 22 236 592 703 862 543 -1292 -1123 -912 -945 -168 -133 -897 -932 -518 -684 -595 -20 -459 -407 -373 -362 342 694 529 928 627 566 899 598 249 374 540 1066 1216 1210 842 -538 -280 -531 -72 1238 379 179 222 210 509 -68 -309 -641 -615 -182 -1077 -1461 -1789 -2351 -1292 -900 -522 136 196 466 412 648 -55 85 728 610 332 612 785 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